Improving Thermal-oxidative Aging Resistance of Styrene-butadiene Rubber by Antioxidant Loaded Silica Aerogel

Xue-Fei Ping; Yu Wang; Lu Liu; Fu-Yong Liu; Hong-Wei He; Pi Wang; Wen-Wen Yu; Qiang Zheng

doi:10.1007/s10118-024-3125-5

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Improving Thermal-oxidative Aging Resistance of Styrene-butadiene Rubber by Antioxidant Loaded Silica Aerogel

RESEARCH ARTICLE | Updated：2024-08-06

- Improving Thermal-oxidative Aging Resistance of Styrene-butadiene Rubber by Antioxidant Loaded Silica Aerogel
- Improving Thermal-oxidative Aging Resistance of Styrene-butadiene Rubber by Antioxidant Loaded Silica Aerogel
- 高分子科学（英文版） 2024年42卷第8期页码：1198-1209
- Affiliations：
  
  a.College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
  b.Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering, Taiyuan 030032, China
  c.Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310058, China
- Author bio：
  
  liufuyong@tyut.edu.cn (F.Y.L.)
  zhengqiang@zju.edu.cn (Q.Z.)
- Funds：
  
  This work was financially supported by Natural Science Foundation of Shanxi Province (No. 202303021211075), Shanxi Province Science and Technology Key Research and Development Project (No. 201903D321065) and Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering (No. 2021SX-TD011).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3125-5.
- DOI：10.1007/s10118-024-3125-5
  中图分类号：
- 纸质出版日期：2024-08-01，
  
  网络出版日期：2024-04-25，
  
  收稿日期：2023-12-04，
  
  修回日期：2024-02-28，
  
  录用日期：2024-03-11
- Accepted：
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Ping, X. F.; Wang, Y.; Liu, L.; Liu, F. Y.; He, H. W.; Wang, P.; Yu, W. W.; Zheng, Q. Improving thermal-oxidative aging resistance of styrene-butadiene rubber by antioxidant loaded silica aerogel. Chinese J. Polym. Sci. 2024, 42, 1198–1209

Xue-Fei Ping, Yu Wang, Lu Liu, et al. Improving Thermal-oxidative Aging Resistance of Styrene-butadiene Rubber by Antioxidant Loaded Silica Aerogel[J]. Chinese Journal of Polymer Science, 2024,42(8):1198-1209.
Ping, X. F.; Wang, Y.; Liu, L.; Liu, F. Y.; He, H. W.; Wang, P.; Yu, W. W.; Zheng, Q. Improving thermal-oxidative aging resistance of styrene-butadiene rubber by antioxidant loaded silica aerogel. Chinese J. Polym. Sci. 2024, 42, 1198–1209 DOI： 10.1007/s10118-024-3125-5.

Xue-Fei Ping, Yu Wang, Lu Liu, et al. Improving Thermal-oxidative Aging Resistance of Styrene-butadiene Rubber by Antioxidant Loaded Silica Aerogel[J]. Chinese Journal of Polymer Science, 2024,42(8):1198-1209. DOI： 10.1007/s10118-024-3125-5.

摘要

In this study

composite particles (A-N) with both slow-release and reinforcing functions were obtained by loading the antioxidant into the pores of silica aerogel powders. Thermo-oxidative aging of vulcanized rubber was inhibited by continuous release of antioxidant from A-N.

Abstract

The antioxidant

-isopropyl-

'-phenyl-

-phenylenediamine (4010NA) was dissolved in ethanol and impregnated into silica aerogel (SAG)

via

vacuum-pressure cycles

yielding composite particles (A-N) with enhanced sustained-release and reinforcing capabilities. The effect of A-N on the mechanical properties and thermal-oxidative aging resistance of styrene-butadiene rubber (SBR) vulcanizates was investigated. TGA and BET assessments indicated that the loading efficiency of 4010NA in SAG reached 14.26% within ethanol's solubility limit. Incorporating A-N into SBR vulcanizates significantly elevated tensile strength by 17.5% and elongation at break by 41.9% over those with fumed silica and free 4010NA. Furthermore

A-N notably enhanced the thermal-oxidative aging resistance of SBR. After aging for 96 h at 100 °C

the tensile strength and elongation at break of SBR with A-N sustained 70.09% and 58.61% of their initial values

respectively

with the retention rate of elongation at break being 62.8% higher

than that of SBR with fumed silica and free antioxidant. The study revealed that A-N composite particles significantly inhibited the crosslinking in SBR's molecular chains

reducing hardening and embrittlement during later thermal-oxidative aging stages.

关键词

Keywords

Styrene-butadiene rubberSilica aerogelLoading modificationThermal-oxidative aging

references

Aprem, A. S.; Joseph, K.; Thomas, S. Recent developments in crosslinking of elastomers.Rubber Chem. Technol.2005,78, 458−488..

Li, G.-Y.; Koenig, J. L. A review of rubber oxidation.Rubber Chem. Technol.2005,78, 355−390..

Zhao, W.; He, J.; Yu, P.; Jiang, X.; Zhang, L. Recent progress in the rubber antioxidants: a review.Polym. Degrad. Stabil.2023,207, 110223..

Ji, Y.; Han, S. D.; Wu, H.; Guo, S. Y.; Zhang, F. S.; Qiu, J. H. Understanding the thermal impedance of silicone rubber/hexagonal boron nitride composites as thermal interface materials.Chinese J. Polym. Sci.2024,42, 352−363..

Tayefi, M.; Eesaee, M.; Hassanipour, M.; Elkoun, S.; David, E.; Nguyen-Tri, P. Recent progress in the accelerated aging and lifetime prediction of elastomers : a review.Polym. Degrad. Stabil.2023,214, 110379−21..

Liu, Q.; Wei, P.; Cong, C.; Meng, X.; Zhou, Q. Synthesis and antioxidation behavior in EPDM of novel macromolecular antioxidants with crosslinking and antioxidation effects.Polym. Degrad. Stabil.2022,205, 110155..

Choi, S. S.; Im, S. H.; Park, J. H.; Kim, J. S. Analysis of wax solubility of rubber vulcanizates using wax solution in toluene and molten wax.Polym. Test.2009,28, 696−701..

Bom, N. M.; Usuda, E. O.; da Silva Gigliotti, M.; de Aguiar, D. J. M.; Imamura, W.; Paixao, L. S.; Carvalho, A. M. G. Waste tire rubber-based refrigerants for solid-state cooling devices.Chinese J. Polym. Sci.2020,38, 769−775..

Choi, S. S.; Chung, H. S.; Joo, Y. T.; Min, B. K.; Lee, S. H. Analysis of the whitening phenomenon of a thermoplastic elastomer article by UV weathering.Polym. Test.2011,30, 415−419..

Choi, S. S.; Chung, H. S.; Joo, Y. T.; Yang, K. M.; Lee, S. H. Analysis of whitening phenomenon of EPDMarticle by humid aging.J. Appl. Polym. Sci.2012,123, 2451−2457..

Fu, Y.; Zhao, D.; Yao, P.; Wang, W.; Zhang, L.; Lvov, Y. Highly aging-resistant elastomers doped with antioxidant-loaded clay nanotubes.ACS Appl. Mater. Interfaces2015,7, 8156−8165..

Dileep, P.; Narayanankutty, S. K. Styrenated phenol modified nanosilica for improved thermo-oxidative and mechanical properties of natural rubber.Polym. Test.2020,82, 106302..

Zhong, B.; Dong, H.; Luo, Y. Antioxidant modified graphene oxide for robust and highly aging resistant rubber composites.Compos. Commun.2023,37, 101443−101446..

Zhang, L.; Li, H.; Lai, X.; Liao, X.; Wang, J.; Su, X.; Liu, H.; Wu, W.; Zeng, X. Functionalized graphene as an effective antioxidant in natural rubber.Compos. Part A-Appl. S2018,107, 47−54..

Lu, Y.; Yang, J.; Yin, D.; Tan, M.; Wang, J. Synthesis and aging properties of reactive antioxidant NAPM in natural rubber vulcanizates.J. Appl. Polym. Sci.2008,108, 576−582..

Wu, W.; Zeng, X.; Li, H.; Lai, X.; Xie, H. Synthesis and antioxidative properties in natural rubber of novel macromolecular hindered phenol antioxidants containing thioether and urethane groups.Polym. Degrad. Stabil.2015,111, 232−238..

Xie, H.; Li, H.; Lai, X.; Wu, W.; Zeng, X. Synthesis and antioxidative properties of a star-shaped macromolecular antioxidant based onβ-cyclodextrin.Mater. Lett.2015,151, 72−74..

Zhong, B.; Lin, J.; Liu, M.; Jia, Z.; Luo, Y.; Jia, D.; Liu, F. Preparation of halloysite nanotubes loaded antioxidant and its antioxidative behaviour in natural rubber.Polym. Degrad. Stabil.2017,141, 19−25..

Luo, Y.; Wang, J.-P.; Cui, X.; Fu, Y.; Li, G. L.; Wang, W. Surface-modified mesoporous silica nanorods for the highly aging resistance rubber through controlled release of antioxidant.Polym. Adv. Technol.2021,32, 3384−3391..

Fu, Y.; Yang, C.; Lvov, Y. M.; Zhang, L.; Wang, W. Antioxidant sustained release from carbon nanotubes for preparation of highly aging resistant rubber.Chem. Eng. J.2017,328, 536−545..

Hu, D.; Luo, Y.; Chen, Y.; Lin, J.; Jia, D. Mesoporous silica as nanocarrier of antioxidant for highly anti-aging elastomer composites.Polym. Degrad. Stabil.2019,169, 108987−108995..

Zhao, S.; Siqueira, G.; Drdova, S.; Norris, D.; Ubert, C.; Bonnin, A.; Galmarini, S.; Ganobjak, M.; Pan, Z.; Brunner, S.; Nyström, G.; Wang, J.; Koebel, M. M.; Malfait, W. J. Additive manufacturing of silica aerogels.Nature2020,584, 387−392..

Linhares, T.; Pessoa de Amorim, M. T.; Durães, L. Silica aerogel composites with embedded fibres: a review on their preparation, properties and applications.J. Mater. Chem. A2019,7, 22768−22802..

Kistler, S. S. Coherent expanded-aerogels.J. Phys. Chem.2002,36, 52−64..

Bheekhun, N.; Abu Talib, A. R.; Hassan, M. R. Aerogels in aerospace: an overview.Adv. Mater. Sci. Eng.2013,2013, 1−18..

Eskandari, N.; Motahari, S.; Atoufi, Z.; Hashemi Motlagh, G.; Najafi, M. Thermal, mechanical, and acoustic properties of silica-aerogel/UPVC composites.J. Appl. Polym. Sci.2017,134, 44685..

Sun, G.; Duan, T.; Liu, C.; Zhang, L.; Chen, R.; Wang, J.; Han, S. Fabrication of flame-retardant and smoke-suppressant isocyanate-based polyimide foam modified by silica aerogel thermal insulation and flame protection layers.Polym. Test.2020,91, 106738..

Fricke, J.; Tillotson, T. Aerogels: production, characterization, and applications.Thin Solid Films1997,297, 212−223..

Zhou, S.; You, T.; Zhang, X.; Xu, F. Superhydrophobic cellulose nanofiber-assembled aerogels for highly efficient water-in-oil emulsions separation.ACS Appl. Nano Mater.2018,1, 2095−2103..

Zheng, X.; Liu, X.; Zha, L. Under-oil superhydrophilic poly(vinyl alcohol)/silica hybrid nanofibrous aerogel for gravity-driven separation of surfactant-stabilized water-in-oil emulsions.Macromol. Mater. Eng.2019,304, 1900125−1900129..

Mazrouei-Sebdani, Z.; Salimian, S.; Khoddami, A.; Shams-Ghahfarokhi, F. Sodium silicate based aerogel for absorbing oil from water: the impact of surface energy on the oil/water separation.Mater. Res. Express2019,6, 085059..

Wang, Q.; Asoh, T. A.; Uyama, H. Facile fabrication of flexible bacterial cellulose/silica composite aerogel for oil/water separation.Bull. Chem. Soc. Jpn.2018,91, 1138−1140..

Zhang, Y.; Shen, Q.; Li, X.; Xie, H.; Nie, C. Facile synthesis of ternary flexible silica aerogels with coarsened skeleton for oil-water separation.RSC Adv.2020,10, 42297−42304..

Liu, H.; Sha, W.; Cooper, A. T.; Fan, M. Preparation and characterization of a novel silica aerogel as adsorbent for toxic organic compounds.Colloids Surf. Physicochem. Eng. Aspects2009,347, 38−44..

Ganonyan, N.; Bar, G.; Gvishi, R.; Avnir, D. Gradual hydrophobization of silica aerogel for controlled drug release.RSC Adv.2021,11, 7824−7838..

Giray, S.; Bal, T.; Kartal, A. M.; Kızılel, S.; Erkey, C. Controlled drug delivery through a novel PEG hydrogel encapsulated silica aerogel system.J. Biomed. Mater. Res. A2012,100A, 1307−1315..

Magryta, J. Effect of aerogel on the properties of acrylonitrile-butadiene rubber (NBR) vulcanizates.Polimery2012,57, 117−123..

Lay, M.; Azura, A.; Othman, N.; Tezuka, Y.; Chhorda, P. Effect of nanosilica fillers on the cure characteristics and mechanical properties of natural rubber composites.Adv. Mat. Res.2012,626, 818−822..

Guo, W.-J.; Liu, L.; Liu, F. Y.; Yu, W.-W.; Jia, L.; He, H. W.; Zhu, F. B.; Zheng, Q. Mechanical properties and mullins effect of ethylene propylene diene monomer vulcanizes reinforced with silica powders with different micropore structures.Acta Polymerica Sinica(in Chinese)2023,54, 1241−1252..

Song, Y. H.; Zeng, L. B.; Zheng, Q. Understanding the reinforcement and dissipation of natural rubber compounds filled with hybrid filler composed of carbon black and silica.Chinese J. Polym. Sci.2017,35, 1436−1446..

Liu, Y. B.; Li, L.; Wang, Q. Reinforcement of natural rubber with carbon black/nanoclay hybrid filler.Plast. Rubber Compos.2013,39, 370−376..

Hou, F.; Song, Y.; Zheng, Q. Payne effect of thermo-oxidatively aged isoprene rubber vulcanizates.Polymer2020,195, 122432..

Štandeker, S.; Novak, Z.; Knez, Ž. Adsorption of toxic organic compounds from water with hydrophobic silica aerogels.J. Colloid Interface Sci.2007,310, 362−368..

Julve, D.; Ramos, J.; Pérez, J.; Menéndez, M. Analysis of mercury porosimetry curves of precipitated silica, as an example of compressible porous solids.J. Non-Crystalline Solids2011,357, 1319−1327..

Khang, T. H.; Ariff, Z. M. Vulcanization kinetics study of natural rubber compounds having different formulation variables.J. Therm. Anal. Calorim.2011,109, 1545−1553..

Yang, S. Y.; Jia, Z. X.; Liu, L.; Fu, W. W.; Jia, D. M.; Luo, Y. F. Insight into vulcanization mechanism of novel binary accelerators for natural rubber.Chinese J. Polym. Sci.2014,32, 1077−1085..

Yang, C.; Luo, Y.; Peng, Z.; Xu, K.; Zhong, J. Comparison effects of lanthanum stearate and antioxidants in epoxidized natural rubber.J. Rare Earths2015,33, 1236−1240..

Tokoro, T. InEffects of temperature and surface roughness on the evaluation of hydrophobic properties of silicone rubber, 2016 IEEE Conference on Electrical Insulation and Dielectric Phenomena (CEIDP), IEEE: 2016 ; pp. 814−817..

Estaji, S.; Paydayesh, A.; Mousavi, S. R.; Khonakdar, H. A.; Abiyati, M. M. Polycarbonate/poly(methyl methacrylate)/silica aerogel blend composites for advanced transparent thermal insulations: mechanical, thermal, and optical studies.Polym. Compos.2021,42, 5323−5334..

Floess, J. K.; Field, R.; Rouanet, S. The use of vinyl functional aerogels for reinforcement of silicone rubbers.J. Non-Crystalline Solids2001,285, 101−108..

Poh, B. T.; Te, C. S. Cure index and activation energy of vulcanization of natural rubber and epoxidized natural rubber vulcanized in the presence of antioxidants.J. Appl. Polym. Sci.2000,77, 3234−3238..

Sun, Y.; He, J.; Zhong, B.; Zhu, L.; Liu, F. A synthesized multifunctional rubber additive and its improvements on the curing and antioxidative properties of styrene-butadiene rubber/silica composites.Polym. Degrad. Stabil.2019,170, 108999..

Zhong, B.; Shi, Q.; Jia, Z.; Luo, Y.; Chen, Y.; Jia, D. Preparation of silica-supported 2-mercaptobenzimidazole and its antioxidative behavior in styrene-butadiene rubber.Polym. Degrad. Stabil.2014,110, 260−267..

Talma, A. G.; Datta, S.; Huntink, N. M.; Datta, R. N. Rubber vulcanizates degradation and stabilization.Rubber Chem. Technol.2007,80, 436−480..

Smith, L. M.; Aitken, H. M.; Coote, M. L. The fate of the peroxyl radical in autoxidation: how does polymer degradation really occur.Acc. Chem. Res.2018,51, 2006−2013..

Wang, X.; Yang, K.; Zong, C.; Zhang, P. The evolution of microstructure of Styrene-Isoprene-Butadiene Rubber during the thermal-oxidative aging process usingin-situFTIR way.Polym. Degrad. Stabil.2021,188, 109573..

Li, J.; Zhou, C.; Cao, D.; Liu, H. Synergistic effects of amine-containing antioxidants on the aging performances of ethylene propylene diene rubber.ChemistrySelect2020,5, 4961−4966..

Wang, X.; Yang, K.; Zhang, P. Evaluation of the aging coefficient and the aging lifetime of carbon black-filled styrene-isoprene-butadiene rubber after thermal-oxidative aging.Compos. Sci. Technol.2022,220, 109258..

Mostafa, A.; Abouel-Kasem, A.; Bayoumi, M. R.; El-Sebaie, M. G. The influence of CB loading on thermal aging resistance of SBR and NBR rubber compounds under different aging temperature.Mater. Des.2009,30, 791−795..

Ha-Anh, T.; Vu-Khanh, T. Prediction of mechanical properties of polychloroprene during thermo-oxidative aging.Polym. Test.2005,24, 775−780..

Carli, L. N.; Bianchi, O.; Mauler, R. S.; Crespo, J. S. Accelerated aging of elastomeric composites with vulcanized ground scraps.J. Appl. Polym. Sci.2012,123, 280−285..

Tang, M.; Xing, W.; Wu, J.; Huang, G.; Xiang, K.; Guo, L.; Li, G. Graphene as a prominent antioxidant for diolefin elastomers.J. Mater. Chem. A2015,3, 5942−5948..

Bandzierz, K.; Reuvekamp, L.; Dryzek, J.; Dierkes, W.; Blume, A.; Bielinski, D. Influence of network structure on glass transition temperature of elastomers.Materials2016,9, 607..

Bellas, R.; Díez, J.; Rico, M.; Barral, L.; Ramírez, C.; Montero, B. Accelerated ageing of styrene-butadiene rubber nanocomposites stabilized by phenolic antioxidant.Polym. Compos.2014,35, 334−343..

Xiang, K.; Wu, S.; Huang, G.; Zheng, J.; Huang, J.; Li, G. Relaxation behavior and time-temperature superposition (TTS) profiles of thermally aged styrene-butadiene rubber (SBR).Macromol. Res.2014,22, 820−825..

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