Self-healable and Robust Film Based on Electroactive Polymer Brush as Electrode for Flexible Supercapacitor

Maria P. Sokolova; Vitaly K. Vorobiov; Nikolay N. Smirnov; Ivan S. Kuryndin; Natalya V. Bobrova; Michael A. Smirnov

doi:10.1007/s10118-024-3113-9

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Self-healable and Robust Film Based on Electroactive Polymer Brush as Electrode for Flexible Supercapacitor

RESEARCH ARTICLE | Updated：2024-08-06

- Self-healable and Robust Film Based on Electroactive Polymer Brush as Electrode for Flexible Supercapacitor
- Self-healable and Robust Film Based on Electroactive Polymer Brush as Electrode for Flexible Supercapacitor
- 高分子科学（英文版） 2024年42卷第8期页码：1049-1059
- Affiliations：
  
  Institute of Macromolecular Compounds, Russian Academy of Sciences, Bolshoy pr. 31, Saint Petersburg 199004, Russia
- Author bio：
  
  pmarip@mail.ru (M.P.S.)
  smirnov_michael@mail.ru (M.A.S.)
- Funds：
  
  The work was carried out within the state assignment №124013000728-0. The experimental work was also in part facilitated with equipment of the Engineering Center of St. Petersburg State Technological Institute (Technical University).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3113-9.
- DOI：10.1007/s10118-024-3113-9
  中图分类号：
- 纸质出版日期：2024-08-01，
  
  网络出版日期：2024-05-10，
  
  收稿日期：2023-12-10，
  
  修回日期：2024-03-05，
  
  录用日期：2024-03-27
- Accepted：
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Sokolova, M. P.; Vorobiov, V. K.; Smirnov, N. N.; Kuryndin, I. S.; Bobrova, N. V.; Smirnov, M. A. Self-healable and robust film based on electroactive polymer brush as electrode for flexible supercapacitor. Chinese J. Polym. Sci. 2024, 42, 1049–1059

Maria P. Sokolova, Vitaly K. Vorobiov, Nikolay N. Smirnov, et al. Self-healable and Robust Film Based on Electroactive Polymer Brush as Electrode for Flexible Supercapacitor[J]. Chinese Journal of Polymer Science, 2024,42(8):1049-1059.
Sokolova, M. P.; Vorobiov, V. K.; Smirnov, N. N.; Kuryndin, I. S.; Bobrova, N. V.; Smirnov, M. A. Self-healable and robust film based on electroactive polymer brush as electrode for flexible supercapacitor. Chinese J. Polym. Sci. 2024, 42, 1049–1059 DOI： 10.1007/s10118-024-3113-9.

Maria P. Sokolova, Vitaly K. Vorobiov, Nikolay N. Smirnov, et al. Self-healable and Robust Film Based on Electroactive Polymer Brush as Electrode for Flexible Supercapacitor[J]. Chinese Journal of Polymer Science, 2024,42(8):1049-1059. DOI： 10.1007/s10118-024-3113-9.

摘要

A novel polyimide-Cu complex material predicated on side-chain-type pyridine-Cu coordination achieves superior dielectric performance

which endows an elevated degree of freedom with suppressed relaxation activation energy and long-range electron delocalization

enhancing molecular dipole moment with more flexibility.

Abstract

The aim of this study was to develop self-healable and robust electroconductive film based on polyaniline copolymer for application as electrode in flexible supercapacitor. For this purpose

the electroconductive polymer brushes (EPB) was elaborated. The synt

hesis of EPB is based on graft polymerizations of acrylamide (AAm) on poly(vinyl alcohol) (PVA) with formation of PVA-PAAm polymer brush and subsequent graft copolymerization of aniline and

-phenylenediamine on PVA-PAAm resulting in formation of EPB with electroconducting copoly(aniline-

-phenylenediamine) (PAPhDA). It was found that the ratio between PVA and PAAm at the first stage greatly influence the electrochemical performance of the EPBs. Electroconducting films were prepared by casting of EPB solution with subsequent drying. Investigation of electrical current distribution through the film with AFM reveal more uniform distribution of PAPhDA in EPB in comparison with reference PVA-PAPhDA and PAAm-PAPhDA samples. It was demonstrated that mechanical characteristics and electrical conductivity values of films restore at large extent after curring and self-healing under optimal relative humidity level (58%). The flexile supercapacitor cell with EPB film electrodes demonstrate specific capacitance 602 mF·cm

–2

at the current density of 1 mA·cm

–2

and retention 94% of initial capacitance after 5000 charge/discharge cycles.

关键词

Keywords

Polymer brushPolyanilineFlexible supercapacitorSelf-healingElectroconducting film

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