Electrostatic Encapsulation of Cobalt Ions into Crystalline Framework Derived Polymer Aerogel: Ultra-light, Pressure Resistant, Hydrophobic, Photothermal Conversion, Heat Insulation and Infrared Stealth

Yi-Fan Kang; Jin-Lu Tang; Ming Song; Wei Wang; Jia-Cheng Ma; Zhan-You Ji; Tong Liu; Wen-Huan Huang

doi:10.1007/s10118-024-3111-y

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Electrostatic Encapsulation of Cobalt Ions into Crystalline Framework Derived Polymer Aerogel: Ultra-light, Pressure Resistant, Hydrophobic, Photothermal Conversion, Heat Insulation and Infrared Stealth

RESEARCH ARTICLE | Updated：2024-06-26

- Electrostatic Encapsulation of Cobalt Ions into Crystalline Framework Derived Polymer Aerogel: Ultra-light, Pressure Resistant, Hydrophobic, Photothermal Conversion, Heat Insulation and Infrared Stealth
  Enhanced Publication
- Electrostatic Encapsulation of Cobalt Ions into Crystalline Framework Derived Polymer Aerogel: Ultra-light, Pressure Resistant, Hydrophobic, Photothermal Conversion, Heat Insulation and Infrared Stealth
- 高分子科学（英文版） 2024年42卷第7期页码：946-957
- Affiliations：
  
  a.China Key Laboratory of Chemical Additives for China National Light Industry, College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi’an 710021, China
  b.College of New Energy, Xi’an Shiyou University, Xi’an 710065, China
  c.Xi’an Key Laboratory of Functional Supramolecular Structure and Materials, College of Chemistry and Materials Science, Northwest University, Xi’an 710127, China
- Author bio：
  
  huangwenhuan@sust.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 22001156 and 22301239), the Youth Talent Fund of University Association for Science and Technology in Shaanxi, China (No. 20210602), International Cooperation Key Project of Science and Technology Department of Shaanxi, China (No. 2022KWZ-06), the research project of Science and Technology Department of Shaanxi Province (No. 2021JQ-533), the Research Program of the Shaanxi Provincial Department of Education (No. 23JK0596), the open Foundation of Xi’an Key Laboratory of Functional Supramolecular Structure and Materials (No. CFZKFKT23003) and Shaanxi Provincial Department of Education service local special project, industrialization cultivation project (No. 23JC007).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3111-y.
- DOI：10.1007/s10118-024-3111-y
  中图分类号：
- 收稿：2024-01-19，
  
  修回：2024-02-07，
  
  录用：2024-02-27，
  
  网络首发：2024-04-16，
  
  纸质出版：2024-07-01
- Accepted：
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Kang, Y. F.; Tang, J. L.; Song, M.; Wang, W.; Ma, J. C.; Ji, Z. Y.; Liu, T.; Huang, W. H. Electrostatic encapsulation of cobalt ions into crystalline framework derived polymer aerogel: ultra-light, pressure resistant, hydrophobic, photothermal conversion, heat insulation and infrared stealth. Chinese J. Polym. Sci. 2024, 42, 946–957

Yi-Fan Kang, Jin-Lu Tang, Ming Song, et al. Electrostatic Encapsulation of Cobalt Ions into Crystalline Framework Derived Polymer Aerogel: Ultra-light, Pressure Resistant, Hydrophobic, Photothermal Conversion, Heat Insulation and Infrared Stealth[J]. Chinese Journal of Polymer Science, 2024, 42(7): 946-957.
Kang, Y. F.; Tang, J. L.; Song, M.; Wang, W.; Ma, J. C.; Ji, Z. Y.; Liu, T.; Huang, W. H. Electrostatic encapsulation of cobalt ions into crystalline framework derived polymer aerogel: ultra-light, pressure resistant, hydrophobic, photothermal conversion, heat insulation and infrared stealth. Chinese J. Polym. Sci. 2024, 42, 946–957 DOI： 10.1007/s10118-024-3111-y.

Yi-Fan Kang, Jin-Lu Tang, Ming Song, et al. Electrostatic Encapsulation of Cobalt Ions into Crystalline Framework Derived Polymer Aerogel: Ultra-light, Pressure Resistant, Hydrophobic, Photothermal Conversion, Heat Insulation and Infrared Stealth[J]. Chinese Journal of Polymer Science, 2024, 42(7): 946-957. DOI： 10.1007/s10118-024-3111-y.

摘要

An outstanding electromagnetic wave absorbing material wi

th multiple loss mechanisms was synthesized by incorporating magnetic metal into the anionic crystal framework through electrostatic incorporation. The superior RLmin at a thickness of 2.5 mm is -40.49 dB

and the EAB is 5.36 GHz (RL

-10 dB

10.4~15.76GHz). The optimal radar cross section (RCS) reduction of the sample was 34.9 dB·m

. Furthermore

Co@CN-4 is embedded into CMC as the precursor of self-assembly to form Co@CN-4 hybrid aerogel (CCHA aerogel)

which integrates various functionalities including ultra-light

pressure resistance

hydrophobicity

photothermal conversion capability

heat insulation performance and infrared stealthiness to cater for practical applications.

Abstract

A variety of electromagnetic wave absorption materials (EMWAs) have been reported

but the integration of powder materials and multifunctional devices should be investigated in-depth to adapt to practical demands. Herein

carbon-coated cobalt composites were prepared by adsorbing magnetic metal cations into an anionic crystalline framework through an electrostatic encapsulate process. Excellent reflection loss (RL

min

) of −40.49 dB and effective absorption bandwidth (EAB) of 5.36 GHz (RL

−10 dB

10.4−15.76 GHz) was achieved with an optimal radar cross section (RCS) reduction of 34.9 dB·m

for the sample tested. For commercial applications

Co@CN-4 was integrated into sodium carboxymethyl cellulose (CMC) aerogel to create an ultra-lightweight composite aerogel that is compressive resistant and heat-holding while also having photothermal conversion capabilities.The hydrophobic modification makes it more widely useful. This study provides a new strategy for EWAMs to integrate versatility and improve their application prospects.

关键词

Keywords

references

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