Highly Transparent Fire-resistant Coatings with Intumescent Three-source Integration

Xiao-Liang Zeng; Xin-Sheng Lan; Yan Wang; Lin Zhang; De-Ming Guo; Hai-Bo Zhao

doi:10.1007/s10118-024-3100-1

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Highly Transparent Fire-resistant Coatings with Intumescent Three-source Integration

RESEARCH ARTICLE | Updated：2024-06-26

- Highly Transparent Fire-resistant Coatings with Intumescent Three-source Integration
- Highly Transparent Fire-resistant Coatings with Intumescent Three-source Integration
- 高分子科学（英文版） 2024年42卷第7期页码：907-915
- Affiliations：
  
  a.State Grid Sichuan Electric Power Research Institute, Chengdu 610041, China
  b.The Collaborative Innovation Center for Eco-Friendly and Fire-Safety Polymeric Materials (Ministry of Education), National Engineering Laboratory of Eco-Friendly Polymeric Materials (Sichuan), State Key Laboratory of Polymer Materials Engineering, College of Chemistry, Sichuan University,Chengdu 610064, China
- Author bio：
  
  2022322030100@stu.scu.edu.cn (L.Z.)
  haibor7@163.com (H.B.Z.)
- Funds：
  
  This work was financially supported by State Grid Corporation of China Science and Technology Project Funding (No. 52199723000M), the National Natural Science Foundation of China (No. 52122302) and Sichuan Science and Technology Program (No. 2023NSFSC1943).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3100-1.
- DOI：10.1007/s10118-024-3100-1
  中图分类号：
- 收稿：2023-12-31，
  
  修回：2024-02-22，
  
  录用：2024-02-26，
  
  网络首发：2024-03-29，
  
  纸质出版：2024-07-01
- Accepted：
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Zeng, X. L.; Lan, X. S.; Wang, Y.; Zhang, L.; Guo, D. M.; Zhao, H. B. Highly transparent fire-resistant coatings with intumescent three-source integration. Chinese J. Polym. Sci. 2024, 42, 907–915

Xiao-Liang Zeng, Xin-Sheng Lan, Yan Wang, et al. Highly Transparent Fire-resistant Coatings with Intumescent Three-source Integration[J]. Chinese Journal of Polymer Science, 2024, 42(7): 907-915.
Zeng, X. L.; Lan, X. S.; Wang, Y.; Zhang, L.; Guo, D. M.; Zhao, H. B. Highly transparent fire-resistant coatings with intumescent three-source integration. Chinese J. Polym. Sci. 2024, 42, 907–915 DOI： 10.1007/s10118-024-3100-1.

Xiao-Liang Zeng, Xin-Sheng Lan, Yan Wang, et al. Highly Transparent Fire-resistant Coatings with Intumescent Three-source Integration[J]. Chinese Journal of Polymer Science, 2024, 42(7): 907-915. DOI： 10.1007/s10118-024-3100-1.

摘要

A new eco-friendly strategy to develop highly transparent fire-resistant coatings with intumescent three-source integration is proposed. Once exposed to fire

this coating can respond quickly and puff to form a stable foam-like insulation layer

making it a potential application for protecting wooden materials

particularly on ancient buildings and precious furniture.

Abstract

Wood

a readily available and sustainable natural resource

has found widespread use in construction and furniture. However

its inherent flammability poses a potential fire risk. Although intumescent fire-retardant coatings effectively mitigate this risk

achieving high transparency in such coatings presents a significant challenge. In our approach

we employed a cross-linked network of phytic acid anion and

-[3-(trimethoxysilyl) propyl

]

-trimethylammonium cation to create a transparent "three-in-one" intumescent coating. The collaborative P/N/Si flame-retardant effect markedly improved the intumescent char-forming capability

preventing the wood from rapid decomposition. This resulted in a substantial reduction in heat release (13.9% decrease in THR) and an increased limiting oxygen index (LOI) value of 35.5%. Crucially

the high transparency of the coating ensured minimal impact on the wood's appearance

allowing the natural wood grains to remain clearly visible. This innovative approach provides a straightforward method for developing transparent intumescent flame-retardant coatings suitable for wooden substrates. The potential applications extend to preserving ancient buildings and heritage conservation efforts.

关键词

Keywords

references

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