High Impact Polylactide Based on Organosilicon Nucleation Agent

Daria Pakuła; Bogna Sztorch; Eliza Romańczuk-Ruszuk; Bogdan Marciniec; Robert E. Przekop

doi:10.1007/s10118-024-3095-7

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High Impact Polylactide Based on Organosilicon Nucleation Agent

RESEARCH ARTICLE | Updated：2024-05-11

- High Impact Polylactide Based on Organosilicon Nucleation Agent
- High Impact Polylactide Based on Organosilicon Nucleation Agent
- 高分子科学（英文版） 2024年42卷第6期页码：787-797
- Affiliations：
  
  a.Adam Mickiewicz University in Poznań, Faculty of Chemistry, Uniwersytetu Poznańskiego 8, 61-614 Poznań, Poland
  b.Adam Mickiewicz University in Poznań, Centre for Advanced Technologies, Uniwersytetu Poznańskiego 10, 61-614 Poznań, Poland
  c.Institute of Biomedical Engineering, Faculty of Mechanical Engineering, Bialystok University of Technology, Wiejska 45C, 15-351 Bialystok, Poland
- Author bio：
  
  bogdan.marciniec@amu.edu.pl (B.M.)
  robert.przekop@amu.edu.pl (R.E.P.)
- Funds：
  
  This work was financially supported by the Smart Growth Operational Programme (No. POIR.04.02.00-00-D003/20-00); European Funds (No. RPWP.01.01.00-30-0004/18) and Ministry of Science and Higher Education (No. 21/529535/SPUB/SP/2022).
- DOI：10.1007/s10118-024-3095-7
  中图分类号：
- 纸质出版日期：2024-6-1，
  
  网络出版日期：2024-3-7，
  
  收稿日期：2023-12-11，
  
  修回日期：2024-1-7，
  
  录用日期：2024-1-15
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Pakuła, D.; Sztorch, B.; Romańczuk-Ruszuk, E.; Marciniec, B.; Przekop, R. E. High impact polylactide based on organosilicon nucleation agent. Chinese J. Polym. Sci. 2024, 42, 787–797

Daria Pakuła, Bogna Sztorch, Eliza Romańczuk-Ruszuk, et al. High Impact Polylactide Based on Organosilicon Nucleation Agent[J]. Chinese Journal of Polymer Science, 2024,42(6):787-797.
Pakuła, D.; Sztorch, B.; Romańczuk-Ruszuk, E.; Marciniec, B.; Przekop, R. E. High impact polylactide based on organosilicon nucleation agent. Chinese J. Polym. Sci. 2024, 42, 787–797 DOI： 10.1007/s10118-024-3095-7.

Daria Pakuła, Bogna Sztorch, Eliza Romańczuk-Ruszuk, et al. High Impact Polylactide Based on Organosilicon Nucleation Agent[J]. Chinese Journal of Polymer Science, 2024,42(6):787-797. DOI： 10.1007/s10118-024-3095-7.

摘要

In the present work

(3-thiopropyl)polysilsesquioxane SSQ-SH was introduced into a polylactide. Thermal and mechanical characterization was carried out

as well as a rheology test. The formation of spherulite structures was observed. Particularly noteworthy is the fact that SSQ-SH significantly improves the impact strength of the composite.

Abstract

Vario

us sectors of the industry are searching for new materials with specific requirements

providing improved properties. The study presents novel composite materials based on polylactide that have been modified with the organosilicon compound

(3-thiopropyl)polysilsesquioxane (SSQ-SH). The SSQ-SH compound is a mixture of cage structures and not fully condensed random structures. The composite materials were obtained through injection moulding. The study includes a comprehensive characterization of the new materials that analyze their functional properties

such as rheology (MFR)

mechanical strength (tensile strength

Charpy impact strength)

and thermal properties. SEM microscopic photos were also taken to analyze the microstructure of the samples. The addition of a 5% by-weight organosilicon compound to polylactide resulted in a significant increase in MFR by 73.8% compared to the neat polymer. The greatest improvement in impact strength was achieved for the 5% SSQ-SH/PLA composite

increasing it by 32.0 kJ/m

compared to PLA

which represents an increase of up to 187%. The conducted research confirms the possibility of modifying the properties of the polymer by employing organosilicon compounds.

关键词

Keywords

Octa(3-thiopropyl)silsesquioxane8SH-POSSPolylactide (PLA)Injection mouldingComposites

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