Simultaneously Improved Curing, Mechanical, Antioxidative Properties and Reduced ZnO Loading of Silica Filled NR Composites by Incorporation of Low-cost Crude Carbon Dots <italic style="font-style: italic">via</italic> Conventional Melt-milling Method

Chao-Ying Sun; Hai-Jun Ji; Li-Wei Li; Hui Yang; Xiao-Peng An; Yi-Ping Chen; Ming-Jian Han; Can Jiang; Li-Qun Zhang; Peng Yu; Run-Guo Wang

doi:10.1007/s10118-024-3089-5

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Simultaneously Improved Curing, Mechanical, Antioxidative Properties and Reduced ZnO Loading of Silica Filled NR Composites by Incorporation of Low-cost Crude Carbon Dots via Conventional Melt-milling Method

RESEARCH ARTICLE | Updated：2024-05-11

- Simultaneously Improved Curing, Mechanical, Antioxidative Properties and Reduced ZnO Loading of Silica Filled NR Composites by Incorporation of Low-cost Crude Carbon Dots via Conventional Melt-milling Method
- Simultaneously Improved Curing, Mechanical, Antioxidative Properties and Reduced ZnO Loading of Silica Filled NR Composites by Incorporation of Low-cost Crude Carbon Dots via Conventional Melt-milling Method
- 高分子科学（英文版） 2024年42卷第6期页码：815-825
- Affiliations：
  
  a.State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China
  b.School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan 430205, China
- Author bio：
  
  20121202@wit.edu.cn (P.Y.)
  wangrg@mail.buct.edu.cn (R.G.W.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 52103065, 51988102 and 52273003) and the scientific research fund of Wuhan Institute of Technology (No. K2021044).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3089-5.
- DOI：10.1007/s10118-024-3089-5
  中图分类号：
- 收稿：2023-11-30，
  
  修回：2023-12-21，
  
  录用：2024-1-3，
  
  网络首发：2024-02-28，
  
  纸质出版：2024-06-01
- Accepted：
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Sun, C. Y.; Ji, H. J.; Li, L. W.; Yang, H.; An, X. P.; Chen, Y. P.; Han, M. J.; Jiang, C.; Zhang, L. Q.; Yu, P.; Wang, R. G. Simultaneously improved curing, mechanical, antioxidative properties and reduced ZnO loading of silica filled NR composites by incorporation of low-cost crude carbon dots via conventional melt-milling method. Chinese J. Polym. Sci. 2024, 42, 815–825

Chao-Ying Sun, Hai-Jun Ji, Li-Wei Li, et al. Simultaneously Improved Curing, Mechanical, Antioxidative Properties and Reduced ZnO Loading of Silica Filled NR Composites by Incorporation of Low-cost Crude Carbon Dots via Conventional Melt-milling Method[J]. Chinese Journal of Polymer Science, 2024, 42(6): 815-825. DOI: 10.1007/s10118-024-3089-5.
Sun, C. Y.; Ji, H. J.; Li, L. W.; Yang, H.; An, X. P.; Chen, Y. P.; Han, M. J.; Jiang, C.; Zhang, L. Q.; Yu, P.; Wang, R. G. Simultaneously improved curing, mechanical, antioxidative properties and reduced ZnO loading of silica filled NR composites by incorporation of low-cost crude carbon dots via conventional melt-milling method. Chinese J. Polym. Sci. 2024, 42, 815–825 DOI： 10.1007/s10118-024-3089-5.

Chao-Ying Sun, Hai-Jun Ji, Li-Wei Li, et al. Simultaneously Improved Curing, Mechanical, Antioxidative Properties and Reduced ZnO Loading of Silica Filled NR Composites by Incorporation of Low-cost Crude Carbon Dots via Conventional Melt-milling Method[J]. Chinese Journal of Polymer Science, 2024, 42(6): 815-825. DOI: 10.1007/s10118-024-3089-5. DOI：

摘要

In this work

crude carbon dots (CCDs) were used as multifunctional additives for natural rubber/silica system. The results revealed that the CCDs could endow the rubber compound with excellent anti-aging capability

higher curing rate

better mechanical performance

lower rolling resistance and effectively reduce the ZnO dosage by at least 40%.

Abstract

Rubbers or elastomers play an important role in hi-tech technology and civilian daily life because of their unique and strategical properties. Generally

the rubber additives are essential components for rubbers' practical application. Nowadays

developing novel multifunctional additives has attracted increasing research attention. In this work

low-cost crude carbon dots (CCDs) were used as m

ultifunctional additives for natural rubber/silica system (without any additional modification) through industrial compatible melt-mixing method. The results revealed that the CCDs could disperse well in the NR/silica system

and they could not only endow the rubber compound with excellent anti-aging capability due to CCDs' radical scavenging activity because of their plenty of nitrogen-containing species

but also improve the curing rate and mechanical performance of the rubber composite. Also

the CCDs could reduce the rolling resistance of the rubber composites (tan

value at 7% strain of the rubber composite could be decreased by 34%)

which is promising for the application of energy-saving tire industry. Lastly

the addition of CCDs could effectively reduce the ZnO dosage by at least 40% in the rubber composite without deteriorating its performance. Overall

this work provides valuable guidance to develop novel cheap yet effective additives for the elastomer.

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references

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Simultaneously Improved Curing, Mechanical, Antioxidative Properties and Reduced ZnO Loading of Silica Filled NR Composites by Incorporation of Low-cost Crude Carbon Dots via Conventional Melt-milling Method

Simultaneously Improved Curing, Mechanical, Antioxidative Properties and Reduced ZnO Loading of Silica Filled NR Composites by Incorporation of Low-cost Crude Carbon Dots via Conventional Melt-milling Method

DOI：10.1007/s10118-024-3089-5

摘要

Abstract

关键词

Keywords

references