Thermally Conductive, Healable Glass Fiber Cloth Reinforced Polymer Composite based on <italic style="font-style: italic">β</italic>-Hydroxyester Bonds Crosslinked Epoxy with Improved Heat Resistance

Fang Chen; Xiao-Yan Pang; Ze-Ping Zhang; Min-Zhi Rong; Ming-Qiu Zhang

doi:10.1007/s10118-024-3076-x

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Thermally Conductive, Healable Glass Fiber Cloth Reinforced Polymer Composite based on β-Hydroxyester Bonds Crosslinked Epoxy with Improved Heat Resistance

RESEARCH ARTICLE | Updated：2024-04-12

- Thermally Conductive, Healable Glass Fiber Cloth Reinforced Polymer Composite based on β-Hydroxyester Bonds Crosslinked Epoxy with Improved Heat Resistance
- Thermally Conductive, Healable Glass Fiber Cloth Reinforced Polymer Composite based on β-Hydroxyester Bonds Crosslinked Epoxy with Improved Heat Resistance
- 高分子科学（英文版） 2024年42卷第5期页码：643-654
- Affiliations：
  
  a.Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education, GD HPPC Lab, IGCME, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China
  b.Guangdong Provincial Laboratory of Chemistry and Fine Chemical Engineering Jieyang Center, Jieyang 515200, China
- Author bio：
  
  zhangzp8@mail.sysu.edu.cn (Z.P.Z.)
  ceszmq@mail.sysu.edu.cn (M.Q.Z.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 52033011, 51973237 and 52373095), Natural Science Foundation of Guangdong Province, China (Nos. 2019B1515120038 and 2021A1515010417), Science and Technology Planning Project of Guangdong Province (No. 2020B010179001), Science and Technology Planning Project of Guangzhou City (No. 202201011568), GBRCE for Functional Molecular Engineering, and Fundamental Research Funds for the Central Universities, Sun Yat-sen University (No. 23yxqntd002).
- DOI：10.1007/s10118-024-3076-x
  中图分类号：
- 收稿：2023-10-30，
  
  修回：2023-11-29，
  
  录用：2023-12-4，
  
  网络首发：2024-01-26，
  
  纸质出版：2024-05-01
- Accepted：
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Chen, F.; Pang, X. Y.; Zhang, Z. P.; Rong, M. Z.; Zhang, M. Q. Thermally conductive, healable glass fiber cloth reinforced polymer composite based on β-hydroxyester bonds crosslinked epoxy with improved heat resistance. Chinese J. Polym. Sci. 2024, 42, 643–654

Fang Chen, Xiao-Yan Pang, Ze-Ping Zhang, et al. Thermally Conductive, Healable Glass Fiber Cloth Reinforced Polymer Composite based on β-Hydroxyester Bonds Crosslinked Epoxy with Improved Heat Resistance[J]. Chinese Journal of Polymer Science, 2024, 42(5): 643-654. DOI: 10.1007/s10118-024-3076-x.
Chen, F.; Pang, X. Y.; Zhang, Z. P.; Rong, M. Z.; Zhang, M. Q. Thermally conductive, healable glass fiber cloth reinforced polymer composite based on β-hydroxyester bonds crosslinked epoxy with improved heat resistance. Chinese J. Polym. Sci. 2024, 42, 643–654 DOI： 10.1007/s10118-024-3076-x.

Fang Chen, Xiao-Yan Pang, Ze-Ping Zhang, et al. Thermally Conductive, Healable Glass Fiber Cloth Reinforced Polymer Composite based on β-Hydroxyester Bonds Crosslinked Epoxy with Improved Heat Resistance[J]. Chinese Journal of Polymer Science, 2024, 42(5): 643-654. DOI: 10.1007/s10118-024-3076-x. DOI：

摘要

A high-temperature resistant

thermally conductive glass fiber cloth reinforced polymer composite based on β-hydroxyester bonds crosslinked cycloaliphatic epoxy is developed. As a result of the topological network reshuffling and the accompanying physical recontact of BN fillers

restorations of mechanical

thermally conductive and electrical insulation properties are enabled after interlaminar damage.

Abstract

To simultaneously endow thermal conductivity

high glass transition temperature (

) and healing capability to glass fiber/epoxy (GFREP) composite

dynamic crosslinked epoxy resin bearing reversible

-hydroxyl ester bonds was reinforced with boron nitride nanosheets modified glass fiber cloth (GFC@BNNSs). The in-plane heat conduction paths were constructed by electrostatic self-assembly of polyacrylic acid treated GFC and polyethyleneimine decorated BNNSs. Then

the GFC@BNNSs were impregnated with the mixture of lower concentration (3-glycidyloxypropyl) trimethoxysilane grafted BN micron sheets

4-epoxycyclohexylmethyl 3

4-epoxycyclohexanecarboxylate and hexahydro-4-methylphthalic anhydride

which accounted for establishing the through-plane heat transport pathways and avoiding serious deterioration of mechanical performances. The resultant GFREP composite containing less boron nitride particles (17.6 wt%) exhibited superior in-plane (3.29 W·m

−1

·K

−1

) and through-plane (1.16 W·m

−1

·K

−1

) thermal conductivities

as well as high

of 204 °C (

of the unfilled epoxy=177 °C). The reversible transesterification reaction enabled closure of interlaminar cracks within the composite

achieving decent healing efficiencies estimated by means of tensile strength (71.2%)

electrical breakdown strength (83.6%) and thermal conductivity (69.1%). The present work overcame the disadvantages of conventional thermally conductive composites

and provided an efficient approach to prolong the life span of thermally conductive GFREP laminate for high-temperature resistant integrated circuit application.

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Keywords

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Thermally Conductive, Healable Glass Fiber Cloth Reinforced Polymer Composite based on β-Hydroxyester Bonds Crosslinked Epoxy with Improved Heat Resistance

DOI：10.1007/s10118-024-3076-x

摘要

Abstract

关键词

Keywords

references