Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO<sub>2</sub> Nanoparticles for High-Temperature Application

Qing-Qing Liu; Qiu-Hao Lin; Xiao-Dong Qi; Nan Zhang; Ting Huang; Jing-Hui Yang; Yong Wang

doi:10.1007/s10118-024-3068-x

Your Location：

Home >

Browse articles >

Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO₂ Nanoparticles for High-Temperature Application

RESEARCH ARTICLE | Updated：2024-02-20

- Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO₂ Nanoparticles for High-Temperature Application
- Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO₂ Nanoparticles for High-Temperature Application
- 高分子科学（英文版） 2024年42卷第3期页码：322-332
- Affiliations：
  
  a.School of Chemistry, Southwest Jiaotong University, Chengdu 610031, China
  b.Key Laboratory of Advanced Technologies of Materials, Ministry of Education of China, Southwest Jiaotong University, Chengdu 610031, China
- Author bio：
  
  yangjinghui_84@163.com (J.H.Y.)
  yongwang1976@swjtu.edu.cn (Y.W.)
- Funds：
  
  This work was financially supported by Sichuan Science and Technology Program (No. 2022ZHCG0122), the NSAF project (No. U2230120), Youth Science and Technology Innovation Team of Sichuan Province of Functional Polymer Composites (No. 2021JDTD0009), the Key Researched Development Program of Sichuan Province (No. 2022YFG0271).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3068-x.
- DOI：10.1007/s10118-024-3068-x
  中图分类号：
- 收稿：2023-09-01，
  
  修回：2023-11-2，
  
  录用：2023-11-9，
  
  网络首发：2023-12-07，
  
  纸质出版：2024-03-01
- Accepted：
Scan QR Code
Liu, Q. Q.; Lin, Q. H.; Qi, X. D.; Zhang, N.; Huang, T.; Yang, J. H.; Wang, Y. Significantly enhanced energy storage performances of PEI-based composites utilizing surface functionalized ZrO₂ nanoparticles for high-temperature application. Chinese J. Polym. Sci. 2024, 42, 322–332 DOI: 10.1007/s10118-024-3068-x.

Qing-Qing Liu, Qiu-Hao Lin, Xiao-Dong Qi, et al. Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO₂ Nanoparticles for High-Temperature Application[J]. Chinese Journal of Polymer Science, 2024, 42(3): 322-332. DOI: 10.1007/s10118-024-3068-x.
Liu, Q. Q.; Lin, Q. H.; Qi, X. D.; Zhang, N.; Huang, T.; Yang, J. H.; Wang, Y. Significantly enhanced energy storage performances of PEI-based composites utilizing surface functionalized ZrO₂ nanoparticles for high-temperature application. Chinese J. Polym. Sci. 2024, 42, 322–332 DOI: 10.1007/s10118-024-3068-x. DOI：

Qing-Qing Liu, Qiu-Hao Lin, Xiao-Dong Qi, et al. Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO₂ Nanoparticles for High-Temperature Application[J]. Chinese Journal of Polymer Science, 2024, 42(3): 322-332. DOI: 10.1007/s10118-024-3068-x. DOI：

摘要

The ZrO

particles were decorated with amino group utilizing AMEO

which were applied as dielectric filler to enhance the dielectric property of PEI. The composites containing ZrO

-AMEO exhibit high breakdown strength and improved dielectric constant simultaneously

showing excellent energy storage performance at elevated temperatures.

Abstract

Polymer dielectrics with a high energy density and an available energy storage capacity have been playing an important role in advanced electronics and power systems. Nevertheless

the use of polymer dielectrics in harsh environments is limited by their low energy density at high temperatures. Herein

zirconium dioxide (ZrO

) nanoparticles were decorated with amino group utilizing 4

4-methylenebis (phenyl isocyanate) (AMEO) and successfully incorporated into polyetherimide (PEI) matrix. The dielectric properties

breakdown strength

and energy storage performances of PEI/ZrO

-AMEO nanocomposites were investigated from 25 °C to 150 °C. It is found that the combination of moderate bandgap ZrO

with modest dielectric constant and polar groups at interface with deep trap can offer an available strategy to simultaneously increase the dielectric constant and breakdown strength of polymer dielectrics. As a result

the composites containing ZrO

-AMEO exhibit excellent energy storage performance at elevated temperatures. Specially

the PEI-based composites with 3 vol% ZrO

-AMEO display a maximum discharged energy density (

) of 3.1 J/cm

at 150 °C

presenting 90% higher than that of neat PEI. This study may help to better develop the polymer-based dielectric composite applied at elevated temperatures.

关键词

Keywords

references

Dang,Z.;Yuan,J.;Yao,S.;Liao,R.Flexiblenanodielectricmaterialswithhighpermittivityforpowerenergystorage. Adv. Mater. 2013 , 25 ,6334−6365..

Hu,P.;Shen,Y.;Guan,Y.;Zhang,X.;Lin,Y.;Zhang,Q.;Nan,C.Topological-structuremodulatedpolymernanocompositesexhibitinghighlyenhanceddielectricstrengthandenergydensity. Adv. Funct. Mater. 2014 , 24 ,3172−3178..

Palit,S.;Varghese,D.;Guo,H.;Krishnan,S.;Alam,M.A.Theroleofdielectricheatingandeffectsofambienthumidityintheelectricalbreakdownofpolymerdielectrics. IEEE Trans. Device Mat. Rel. 2015 , 15 ,308−318..

Feng,S.;Zhou,Y.;Zhang,T.;Zhang,C;Zhang,Y.;Zhang,Y.;Chen,Q.;Chi,Q.Ultrahighdischargeefficiencyandexcellentenergydensityinorientedcore-shellnanofiber-polyetherimidecomposites. Energy Stor. Mater. 2020 , 25 ,180−192..

Luo,S.;Yu,J.;Yu,S.;Sun,R.;Cao,L.;Liao,W.;Wong,C.Significantlyenhancedelectrostaticenergystorageperformanceofflexiblepolymercompositesbyintroducinghighlyinsulating-ferroelectricmicrohybridsasfillers. Adv. Energy Mater. 2019 , 9 ,1803204..

Fan,M.;Hu,P.;Dan,Z.;Jiang,J.;Sun,B.;Shen,Y.SignificantlyincreasedenergydensityanddischargeefficiencyathightemperatureinpolyetherimidenanocompositesbyasmallamountofAl 2 O 3 nanoparticles. J. Mater. Chem. A 2020 , 8 ,24536−24542..

Li,H.;Liu,F.;Fan,B.;Ai,D.;Peng,Z.;Wang,Q.Nanostructuredferroelectric-polymercompositesforcapacitiveenergystorage. Small Methods 2018 , 2 ,1700399..

Dang,Z.;Yuan,J.;Zha,J.;Zhou,T.;Li,S.;Hu,G.Fundamentals,processesandapplicationsofhigh-permittivitypolymer-matrixcomposites. Prog. Mater. Sci. 2012 , 57 ,660−723..

Rajib,M.;Martinez,R.;Shuvo,M.;Karim,H.;Delfin,D.;Afrin,S.;Rodriguez,G.;Chintalapalle,R.;Lin,Y.Enhancedenergystorageofdielectricnanocompositesatelevatedtemperatures. Int. J. Appl. Ceram. Technol. 2016 , 13 ,125−132..

Sarlioglu,B.;Morris,C.T.Moreelectricaircraft:review,challenges,andopportunitiesforcommercialtransportaircraft. IEEE Trans. Transp. Electrification 2015 , 1 ,54−64..

Tan,D.;Zhang,L.;Chen,Q.;Irwin,P.High-temperaturecapacitorpolymerfilms. J. Electron. Mater. 2014 , 43 ,4569−4575..

Dong,J.;Hu,R.;Xu,X.;Chen,J.;Niu,Y.;Wang,F.;Hao,J.;Wu,K.;Wang,Q.;Wang,H.Afacile in situ surface-functionalizationapproachtoscalablelaminatedhigh-temperaturepolymerdielectricswithultrahighcapacitiveperformance. Adv. Funct. Mater. 2021 , 31 ,2102644..

Wang,P.;Yao,L.;Pan,Z.;Shi,S.;Yu,J.;Zhou,Y.;Liu,Y.;Liu,J.;Chi,Q.;Zhai,J.;Wang,Q.Ultrahighenergystorageperformanceoflayeredpolymernanocompositesoverabroadtemperaturerange. Adv. Mater. 2021 , 33 ,2103338..

Sun,B.;Hu,P.;Ji,X.;Fan,M.;Zhou,L.;Guo,M.;He,S.;Shen,Y.Excellentstabilityinpolyetherimide/SiO 2 nanocompositeswithultrahighenergydensityanddischargeefficiencyathightemperature. Small 2022 , 18 ,2202421..

Wang,P.;Guo,Y.;Zhou,D.;Li,D.;Pang,L.;Liu,W.;Su,J.;Shi,Z.;Sun,S.High-temperatureflexiblenanocompositeswithultra-highenergystoragedensitybynanostructuredMgOfillers. Adv. Funct. Mater . 2022 , 32 ,2204155..

Li,Q.;Chen,L.;Gadinski,M.R.;Zhang,S.;Zhang,G.;Li,H.U.;Iagodkine,E.;Haque,A.;Chen,L.;Jackson,T.N.;Wang,Q.Correction:Corrigendum:Flexiblehigh-temperaturedielectricmaterialsfrompolymernanocomposites. Nature 2015 , 523 ,576−579..

Li,H.;Ren,L.;Ai,D.;Han,Z.;Liu,Y.;Yao,B.;Wang,Q.Ternarypolymernanocompositeswithconcurrentlyenhanceddielectricconstantandbreakdownstrengthforhigh-temperatureelectrostaticcapacitors. InfoMat. 2020 , 2 ,389−400..

Liu,F.;Li,Q.;Li,Z.;Liu,Y.;Dong,L.;Xiong,C.;Wang,Q.Poly(methylmethacrylate)/boronnitridenanocompositeswithenhancedenergydensityashightemperaturedielectrics. Compos. Sci. Technol. 2017 , 142 ,139−144..

Ai,D.;Li,H.;Zhou,Y.;Ren,L.;Han,Z.;Yao,B.;Zhou,W.;Zhao,L.;Xu,J.;Wang,Q.Tuningnanofillersin in situ preparedpolyimidenanocompositesforhigh-temperaturecapacitiveenergystorage. Adv. Energy Mater. 2020 , 10 ,1903881..

Chen,C.;Xie,Y.;Liu,J.;Li,J.;Wei,X.;Zhang,Z.EnhancedenergystoragecapabilityofP(VDF-HFP)nanodielectricsbyHfO 2 passivationlayer:preparation,performanceandsimulation. Compos. Sci. Technol. 2020 , 188 ,107968..

Zheng,W.;Ren,L.;Zhao,X.;Li,H.;Xie,Z.;Li,Y.;Wang,C.;Yu,L.;Yang,L.;Liao,R.TuninginterfacialrelaxationsinP(VDF-HFP)withAl 2 O 3 @ZrO 2 core-shellnanofillersforenhanceddielectricandenergystorageperformance. Compos. Sci. Technol. 2022 , 222 ,109379..

Ren,L.;Li,H.;Xie,Z.;Ai,D.;Zhou,Y.;Liu,Y.;Zhang,S.;Yang,L.;Zhao,X.;Peng,Z.;Liao,R.;Wang,Q.High-temperaturehigh-energy-densitydielectricpolymernanocompositesutilizinginorganiccore-shellnanostructurednanofillers. Adv. Energy Mater. 2021 , 11 ,2101297..

Zhou,Y.;Yuan,C.;Wang,S.;Zhu,Y.;Cheng,S.;Yang,X.;Yang,Y.;Hu,J.;He,J.;Li,Q.Interface-modulatednanocompositesbasedonpolypropyleneforhigh-temperatureenergystorage. Energy Stor. Mater. 2020 , 28 ,255−263..

Thakur,Y.;Zhang,T.;Yang,T.;Bernholc,J.;Chen,L.Q.;Runt,J.;Zhang,Q.M.Enhancementofthedielectricresponseinpolymernanocompositeswithlowdielectricconstantfillers. Nanoscale 2017 , 9 ,0992−10997..

Zhou,Y.;Wang,Q.Advancedpolymerdielectricsforhightemperaturecapacitiveenergystorage. J. Appl. Phys. 2020 , 127 ,240902..

Chen,H.;Pan,Z.;Wang,W.;Chen,Y.;Xing,S.;Cheng,Y.;Ding,X.;Liu,J.;Zhai,J.;Yu,J.Ultrahighdischargeefficiencyandimprovedenergydensityinpolymer-basednanocompositeforhigh-temperaturecapacitorsapplication. Compos. Part A Appl. Sci. Manuf. 2021 , 142 ,106266..

Majoul,N.;Aouida,S.;Bessaïs,B.ProgressofporoussiliconAPTES-functionalizationbyFTIRinvestigations. Appl. Surf. Sci. 2015 , 331 ,388−391..

Nakonieczny,D.S.;Kern,F.;Dufner,L.;Dubiel,A.;Antonowicz,M.;Matus,K.Effectofcalcinationtemperatureonthephasecomposition,morphology,andthermalpropertiesofZrO 2 andAl 2 O 3 modifiedwithAPTES(3-aminopropyltriethoxysilane). Materials 2021 , 14 ,6651..

Wang,T.;Li,J.;Niu,F.;Zhong,A.;Liu,J.;Liu,W.;Shan,L.;Zhang,G.;Sun,R.;Wong,C.Low-temperaturecurableandlow-dielectricpolyimidenanocompositesusingaminoquinoline-functionalizedgrapheneoxidenanosheets. Compos. B Eng. 2022 , 228 ,109412..

Dai,W.;Yu,J.;Wang,Y.;Song,Y.;Alam,F.E.;Nishimura,K.;Lin,C.;Jiang,N.Enhancedthermalconductivityforpolyimidecompositeswithathree-dimensionalsiliconcarbidenanowire@graphenesheetsfiller. J. Mater. Chem. A 2015 , 3 ,4884−4891..

Li,X.;Tan,D.;Xie,L.;Sun,H.;Sun,S.;Zhong,G.;Ren,P.EffectofsurfacepropertyofhalloysiteonthecrystallizationbehaviorofPBAT. Appl. Clay Sci. 2018 , 157 ,218−226..

Yang,C.;Xie,X.;Lu,Y.;Qi,X.;Lei,Y.;Yang,J.;Wang,Y.Improvingtheperformanceofdielectricnanocompositesbyutilizinghighlyconductiverigidcoreandextremelylowlossshell. J. Phys. Chem. C 2020 , 124 ,12883−12896..

Ren,L.;Yang,L.;Zhang,S.;Li,H.;Zhou,Y.;Ai,D.;Xie,Z.;Zhao,X.;Peng,Z.;Liao,R.;Wang,Q.LargelyenhanceddielectricpropertiesofpolymercompositeswithHfO 2 nanoparticlesforhigh-temperaturefilmcapacitors. Compos. Sci. Technol. 2021 , 201 ,108528..

Hu,P.;Sun,W.;Fan,M.;Qian,J.;Jiang,J.;Dan,Z.;Lin,Y.;Nan,C.;Li,M.;Shen,Y.Largeenergydensityathigh-temperatureandexcellentthermalstabilityinpolyimidenanocompositecontainedwithsmallloadingofBaTiO 3 nanofibers. Appl. Surf. Sci. 2018 , 458 ,743−750..

Cheng,S.;Zhou,Y.;Hu,J.;He,J.;Li,Q.Polyimidefilmscoatedbymagnetronsputteredboronnitrideforhigh-temperaturecapacitordielectrics. IEEE Trans. Dielectr. Electr. Insul. 2020 , 27 ,498−503..

Zhou,Y.;Li,Q.;Dang,B.;Yang,Y.;Shao,T.;Li,H.;Hu,J.;Zeng,R.;He,J.;Wang,Q.Ascalable,high-throughput,andenvironmentallybenignapproachtopolymerdielectricsexhibitingsignificantlyimprovedcapacitiveperformanceathightemperatures. Adv. Mater. 2018 , 30 ,1805672..

Azizi,A.;Gadinski,M.R.;Li,Q.;AlSaud,M.;Wang,J.;Wang,Y.;Wang,B.;Liu,F.;Chen,L.;Alem,N.;Wang,Q.High-performancepolymerssandwichedwithchemicalvapordepositedhexagonalboronnitridesasscalablehigh-temperaturedielectricmaterials. Adv. Mater. 2017 , 29 ,1701864..

Sun,W.;Lu,X.;Jiang,J.;Zhang,X.;Hu,P.;Li,M.;Lin,Y.;Nan,C.;Shen,Y.Dielectricandenergystorageperformancesofpolyimide/BaTiO 3 nanocompositesatelevatedtemperatures. J. Appl. Phys. 2017 , 121 ,244101..

Dong,J.;Hu,R.;Niu,Y.;Sun,L.;Li,L.;Li,S.;Pan,D.;Xu,X.;Gong,R.;Cheng,J.;Pan,Z.;Wang,Q.;Wang,H.Enhancinghigh-temperaturecapacitorperformanceofpolymernanocompositesbyadjustingtheenergylevelstructureinthemicro-/meso-scopicinterfaceregion. Nano Energy 2022 , 99 ,107314..

Liu,J.;Li,X.;Ma,S.;Zhang,J.;Jiang,Z.;Zhang,Y.Enhancedhigh-temperaturedielectricpropertiesofpoly(arylethersulfone)/BaTiO 3 nanocomposites via constructingchemicalcrosslinkednetworks. Macromol. Rapid Commun. 2020 , 41 ,2000012..

Wang,Y.;Li,Z.;Wu,C.;Cao,Y.High-temperaturedielectricpolymernanocompositeswithinterposedmontmorillonitenanosheets. Chem. Eng. J. 2020 , 401 ,126093..

浏览量

547

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

One-step Preparation of Brush-type Polystyrene (PS)-SiO2-Poly(2-hydroxyethyl methacrylate) Janus Nanoparticle to Compatibilize PS/Poly(methyl methacrylate) Blends

Janus Particle Sizing Agent for Interfacial Enhancement of Basalt Fiber/Poly(vinyl chloride) Composites

Nucleobase-tackified Thioctic Acid-based Degradable and Recyclable Supramolecular Polymer Adhesives

Enhanced Adhesion Properties of Polymer-Metal Interfaces via Nano-injection Molding: A Study on Molecular Kinematic Mechanisms

Molecular Segregation and Melt Memory in Dilute Polycaprolactone with Reduced Entanglements

Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO2 Nanoparticles for High-Temperature Application

Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO2 Nanoparticles for High-Temperature Application

DOI：10.1007/s10118-024-3068-x

摘要

Abstract

关键词

Keywords

references

Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO₂ Nanoparticles for High-Temperature Application

Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO₂ Nanoparticles for High-Temperature Application