Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO<sub>2</sub> Nanoparticles for High-Temperature Application

Qing-Qing Liu; Qiu-Hao Lin; Xiao-Dong Qi; Nan Zhang; Ting Huang; Jing-Hui Yang; Yong Wang

doi:10.1007/s10118-024-3068-x

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Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO₂ Nanoparticles for High-Temperature Application

RESEARCH ARTICLE | Updated：2024-02-20

- Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO₂ Nanoparticles for High-Temperature Application
- Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO₂ Nanoparticles for High-Temperature Application
- 高分子科学（英文版） 2024年42卷第3期页码：322-332
- Affiliations：
  
  a.School of Chemistry, Southwest Jiaotong University, Chengdu 610031, China
  b.Key Laboratory of Advanced Technologies of Materials, Ministry of Education of China, Southwest Jiaotong University, Chengdu 610031, China
- Author bio：
  
  yangjinghui_84@163.com (J.H.Y.)
  yongwang1976@swjtu.edu.cn (Y.W.)
- Funds：
  
  This work was financially supported by Sichuan Science and Technology Program (No. 2022ZHCG0122), the NSAF project (No. U2230120), Youth Science and Technology Innovation Team of Sichuan Province of Functional Polymer Composites (No. 2021JDTD0009), the Key Researched Development Program of Sichuan Province (No. 2022YFG0271).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3068-x.
- DOI：10.1007/s10118-024-3068-x
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Liu, Q. Q.; Lin, Q. H.; Qi, X. D.; Zhang, N.; Huang, T.; Yang, J. H.; Wang, Y. Significantly enhanced energy storage performances of PEI-based composites utilizing surface functionalized ZrO₂ nanoparticles for high-temperature application. Chinese J. Polym. Sci. 2024, 42, 322–332

Qing-Qing Liu, Qiu-Hao Lin, Xiao-Dong Qi, et al. Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO₂ Nanoparticles for High-Temperature Application[J]. Chinese Journal of Polymer Science, 2024,42(3):322-332.
Liu, Q. Q.; Lin, Q. H.; Qi, X. D.; Zhang, N.; Huang, T.; Yang, J. H.; Wang, Y. Significantly enhanced energy storage performances of PEI-based composites utilizing surface functionalized ZrO₂ nanoparticles for high-temperature application. Chinese J. Polym. Sci. 2024, 42, 322–332 DOI： 10.1007/s10118-024-3068-x.

Qing-Qing Liu, Qiu-Hao Lin, Xiao-Dong Qi, et al. Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO₂ Nanoparticles for High-Temperature Application[J]. Chinese Journal of Polymer Science, 2024,42(3):322-332. DOI： 10.1007/s10118-024-3068-x.

摘要

The ZrO,2, particles were decorated with amino group utilizing AMEO, which were applied as dielectric filler to enhance the dielectric property of PEI. The composites containing ZrO,2,-AMEO exhibit high breakdown strength and improved dielectric constant simultaneously, showing excellent energy storage performance at elevated temperatures.

Abstract

Polymer dielectrics with a high energy density and an available energy storage capacity have been playing an important role in advanced electronics and power systems. Nevertheless, the use of polymer dielectrics in harsh environments is limited by their low energy density at high temperatures. Herein, zirconium dioxide (ZrO,2,) nanoparticles were decorated with amino group utilizing 4,4-methylenebis (phenyl isocyanate) (AMEO) and successfully incorporated into polyetherimide (PEI) matrix. The dielectric properties, breakdown strength, and energy storage performances of PEI/ZrO,2,-AMEO nanocomposites were investigated from 25 °C to 150 °C. It is found that the combination of moderate bandgap ZrO,2, with modest dielectric constant and polar groups at interface with deep trap can offer an available strategy to simultaneously increase the dielectric constant and breakdown strength of polymer dielectrics. As a result, the composites containing ZrO,2,-AMEO exhibit excellent energy storage performance at elevated temperatures. Specially, the PEI-based composites with 3 vol% ZrO,2,-AMEO display a maximum discharged energy density (,U,d,) of 3.1 J/cm,3, at 150 °C, presenting 90% higher than that of neat PEI. This study may help to better develop the polymer-based dielectric composite applied at elevated temperatures.

关键词

Keywords

PolyetherimideHigh temperature dielectricZrO2Interface

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Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO2 Nanoparticles for High-Temperature Application

Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO2 Nanoparticles for High-Temperature Application

DOI：10.1007/s10118-024-3068-x

摘要

Abstract

关键词

Keywords

references

Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO₂ Nanoparticles for High-Temperature Application

Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO₂ Nanoparticles for High-Temperature Application