A Low Cost, Green Sustainable and Biodegradable Biomass-based Fluorine-free Water and Oil Repellent

Zhi-Wei Shen; Shu-Feng Hu; Chen Zeng; Wei-Qing Kong; Mei-Fang Zhu

doi:10.1007/s10118-024-3067-y

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A Low Cost, Green Sustainable and Biodegradable Biomass-based Fluorine-free Water and Oil Repellent

RESEARCH ARTICLE | Updated：2024-03-14

- A Low Cost, Green Sustainable and Biodegradable Biomass-based Fluorine-free Water and Oil Repellent
- A Low Cost, Green Sustainable and Biodegradable Biomass-based Fluorine-free Water and Oil Repellent
- 高分子科学（英文版） 2024年42卷第4期页码：480-491
- Affiliations：
  
  a.State Key Laboratory for Modification of Chemical Fibers & Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
  b.State Key Laboratory of Pulp and Paper Engineering, School of Light Industry and Engineering, South China University of Technology, Guangzhou 510630, China
- Author bio：
  
  kongweiqing@dhu.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 22108031) and Shanghai Sailing Program (No. 21YF1400800). Z. W. Shen and S. F. Hu contributed equally to this work. C. Zeng created the 3D illustrations. All authors commented on the final manuscript.
- DOI：10.1007/s10118-024-3067-y
  中图分类号：
- 收稿：2023-10-01，
  
  修回：2023-11-8，
  
  录用：2023-11-9，
  
  网络首发：2023-12-07，
  
  纸质出版：2024-04-01
- Accepted：
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Shen, Z. W.; Hu, S. F.; Zeng, C.; Kong, W. Q.; Zhu, M. F. A low cost, green sustainable and biodegradable biomass-based fluorine-free water and oil repellent. Chinese J. Polym. Sci. 2024, 42, 480–491

Zhi-Wei Shen, Shu-Feng Hu, Chen Zeng, et al. A Low Cost, Green Sustainable and Biodegradable Biomass-based Fluorine-free Water and Oil Repellent[J]. Chinese Journal of Polymer Science, 2024, 42(4): 480-491.
Shen, Z. W.; Hu, S. F.; Zeng, C.; Kong, W. Q.; Zhu, M. F. A low cost, green sustainable and biodegradable biomass-based fluorine-free water and oil repellent. Chinese J. Polym. Sci. 2024, 42, 480–491 DOI： 10.1007/s10118-024-3067-y.

Zhi-Wei Shen, Shu-Feng Hu, Chen Zeng, et al. A Low Cost, Green Sustainable and Biodegradable Biomass-based Fluorine-free Water and Oil Repellent[J]. Chinese Journal of Polymer Science, 2024, 42(4): 480-491. DOI： 10.1007/s10118-024-3067-y.

摘要

Low cost

green sustainable and biodegradable biomass-based fluorine-free water and oil repellent. The prepared product did not exhibit any leakage after being soaked in hot water and hot oil at 95±5℃ for 30 minutes.

Abstract

With the global ban on plastics intensifying

the substitution of plastic with paper has garnered increasing attention. However

the inadequate water and oil repellency of pulp molding hinders its practical applications. Currently

the common method to enhance the oil and water repellency of pulp molding is by adding fluorinated water and oil repellents. Nevertheless

fluorinated compounds are environmentally and physiologically harmful. Therefore

the development of fluorine-free

water and oil repellent alternatives is crucial. In this study

chitosan and stearic acid were utilized as the first and second layers of the oil and water repellent coatings

respectively. The coated samples exhibited favorable water repellency

with a water contact angle of 116.4°

and excellent oil repellency

achieving a 12/12 rating on the kit scale. Importantly

the samples did not exhibit any leakage after being soaked in hot water and hot oil at 95±5 °C for 30 min

demonstrating remarkable performance as a barrier against hot water and oil. Moreover

the coated samples displayed outstanding mechanical properties

thermal stability

biodegradability

and recyclability. The approach presented in this study is simple

cost-effective

environmentally friendly

and represents a promising technique for producing fluoride-free

oil- and water-resistant pulp molding products.

关键词

Keywords

references

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