Ion-conducting Membranes Based on Bacterial Cellulose Nanofibers Modified by Poly(sodium acrylate-<italic style="font-style: italic">co</italic>-2-acrylamido-2-methylpropanesulfonic acid)

Elizaveta V. Batishcheva; Nikolay N. Smirnov; Natalya V. Bobrova; Maria P. Sokolova; Michael A. Smirnov

doi:10.1007/s10118-023-3054-8

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Ion-conducting Membranes Based on Bacterial Cellulose Nanofibers Modified by Poly(sodium acrylate-co-2-acrylamido-2-methylpropanesulfonic acid)

RESEARCH ARTICLE | Updated：2024-02-20

- Ion-conducting Membranes Based on Bacterial Cellulose Nanofibers Modified by Poly(sodium acrylate-co-2-acrylamido-2-methylpropanesulfonic acid)
- Ion-conducting Membranes Based on Bacterial Cellulose Nanofibers Modified by Poly(sodium acrylate-co-2-acrylamido-2-methylpropanesulfonic acid)
- 高分子科学（英文版） 2024年42卷第3期页码：333-343
- Affiliations：
  
  Institute of Macromolecular Compounds, Russian Academy of Sciences, Bolshoy pr. 31, Saint Petersburg 199004, Russia
- Author bio：
  
  batischevaelisaveta@gmail.com (E.V.B.)
  smirnov_michael@mail.ru (M.A.S.)
- Funds：
  
  The work was carried out as part of a State Assignment 122012100170-1. Authors acknowledge shared facilities VTAN NSU for the usage of experimental equipment. The experimental work was also in part facilitated with equipment of the Engineering Center of St. Petersburg State Technological Institute (Technical University). Authors acknowledge Dr. N.N.Saprykina with the help in the scanning electron microscopy.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-3054-8.
- DOI：10.1007/s10118-023-3054-8
  中图分类号：
- 收稿：2023-07-22，
  
  修回：2023-9-11，
  
  录用：2023-9-12，
  
  网络首发：2023-11-03，
  
  纸质出版：2024-03-01
- Accepted：
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Batishcheva, E. V.; Smirnov, N. N.; Bobrova, N. V.; Sokolova, M. P.; Smirnov, M. A. Ion-conducting membranes based on bacterial cellulose nanofibers modified by poly(sodium acrylate-co-2-acrylamido-2-methylpropanesulfonic acid). Chinese J. Polym. Sci. 2024, 42, 333–343

Elizaveta V. Batishcheva, Nikolay N. Smirnov, Natalya V. Bobrova, et al. Ion-conducting Membranes Based on Bacterial Cellulose Nanofibers Modified by Poly(sodium acrylate-co-2-acrylamido-2-methylpropanesulfonic acid)[J]. Chinese Journal of Polymer Science, 2024, 42(3): 333-343. DOI: 10.1007/s10118-023-3054-8.
Batishcheva, E. V.; Smirnov, N. N.; Bobrova, N. V.; Sokolova, M. P.; Smirnov, M. A. Ion-conducting membranes based on bacterial cellulose nanofibers modified by poly(sodium acrylate-co-2-acrylamido-2-methylpropanesulfonic acid). Chinese J. Polym. Sci. 2024, 42, 333–343 DOI： 10.1007/s10118-023-3054-8.

Elizaveta V. Batishcheva, Nikolay N. Smirnov, Natalya V. Bobrova, et al. Ion-conducting Membranes Based on Bacterial Cellulose Nanofibers Modified by Poly(sodium acrylate-co-2-acrylamido-2-methylpropanesulfonic acid)[J]. Chinese Journal of Polymer Science, 2024, 42(3): 333-343. DOI: 10.1007/s10118-023-3054-8. DOI：

摘要

Green ion-conducting membranes based on bacterial cellulose nanofibers with grafted acrylic copolymer was elaborated. High ion mobility and low activation energy of conductivity of prepared membrane allow supercapacitor cell to operate at an ultra-high current density.

Abstract

Green method for preparation of ion-conducting membranes (ICM) based on bacterial cellulose nanofibers (CNF) modified by a copolymer of sodium acrylate and 2-acrylamido-2-methylpropanesulfonic acid was elaborated. FTIR and NMR data confirmed grafting of polyacrylate onto cellulose surface. Formation of porous structure of the ICM was controlled by SEM and AFM. The maximal ionic conductivity of the membranes reaches 1.5 and 3.1 mS·cm

−1

(60 °C and 98% relative humidity) when they are saturated with water or H

(1 mol·L

−1

) electrolyte

respectively. Prepared ICM was tested as a separator in a symmetrical supercapacitor with electrodes based on polyaniline hydrogel. The assembled cell demonstrate ability to operate at high current density up to 100 A·g

−1

maintaining specific capacitance 165 F·g

−1

. Maximal specific capacitance of 289 F·g

−1

was achieved at current density 1 A·g

−1

. Retaining of 90% of initial capacitance after 10000 of charge-discharge cycles proves high electrochemical stability of prepared ICM.

关键词

Keywords

references

deOliveira,C.C.N.;Angelkorte,G.;Rochedo,P.R.R.;Szklo,A.Theroleofbiomaterialsfortheenergytransitionfromthelensofanationalintegratedassessmentmodel. Clim. Change 2021 , 167 ,57..

Jian,M.;Zhang,Y.;Liu,Z.Naturalbiopolymersforflexiblesensingandenergydevices. Chinese J. Polym. Sci. 2020 , 38 ,459−490..

Wang,Y.;RuizDiaz,D.F.;Chen,K.S.;Wang,Z.;Adroher,X.C.Materials,technologicalstatus,andfundamentalsofPEMfuelcells—areview. Mater. Today 2020 , 32 ,178−203..

Lizundia,E.;Kundu,D.Advancesinnaturalbiopolymer-basedelectrolytesandseparatorsforbatteryapplications. Adv. Funct. Mater. 2021 , 31 ,1−29..

Wang,S.;Zhang,L.;Zeng,Q.;Liu,X.;Lai,W.Y.;Zhang,L.Cellulosemicrocrystalswithbrush-likearchitecturesasflexibleall-solid-statepolymerelectrolyteforlithium-ionbattery. ACS Sustainable Chem. Eng. 2020 , 8 ,3200−3207..

Wang,S.;He,J.;Li,Q.;Wang,Y.;Liu,C.;Cheng,T.;Lai,W.Y.Highlyelasticenergystoragedevicebasedonintrinsicallysuper-stretchablepolymerlithium-ionconductorwithhighconductivity. Fundam. Res 2022 ,DOI:10.1016/j.fmre.2022.06.003.

Wang,S.;Bai,M.;Liu,C.;Li,G.;Lu,X.;Cai,H.;Liu,C.;Lai,W.Y.Highlystretchablemultifunctionalpolymerionicconductorwithhighconductivitybasedonorganic-inorganicdualnetworks. Chem. Eng. J. 2022 , 440 ,135824..

Okonkwo,P.C.;Collins,E.;Okonkwo,E.ApplicationofBiopolymerCompositesinSuperCapacitor,in Biopolymer Composites in Electronics ,Elsevier, 2017 :bll487–503..

Musa,M.T.;Shaari,N.;Kamarudin,S.K.;Wong,W.Y.Recentbiopolymersusedformembranefuelcells:characterizationanalysisperspectives. Int. J. Energy Res. 2022 , 46 ,16178−16207..

Palanisamy,G.;Oh,T.H.;Thangarasu,S.Modifiedcelluloseproton-exchangemembranesfordirectmethanolfuelcells. Polymers 2023 , 15 ,639..

Winter,M.;Brodd,R.J.Whatarebatteries,fuelcells,andsupercapacitors. Chem. Rev. 2004 , 104 ,4245−4269..

Ng,W.W.;Thiam,H.S.;Pang,Y.L.;Chong,K.C.;Lai,S.O.Astate-of-artonthedevelopmentofnafion-basedmembraneforperformanceimprovementindirectmethanolfuelcells. Membranes 2022 , 12 ,S06..

Xu,T.C.;Wang,C.S.;Hu,Z.Y.;Zheng,J.J.;Jiang,S.H.;He,S.J.;Hou,H.Q.Highstrengthandstableprotonexchangemembranebasedonperfluorosulfonicacid/polybenzimidazole. Chinese J. Polym. Sci. 2022 , 40 ,764−771..

Walkowiak-Kulikowska,J.;Wolska,J.;Koroniak,H.Biopolymermembranesinfuelcellapplications,in Biopolymer Membranes and Films ,Elsevier, 2020 :bll423–476..

Bayer,T.;Cunning,B.V.;Šmíd,B.;Selyanchyn,R.;Fujikawa,S.;Sasaki,K.;Lyth,S.M.Spraydepositionofsulfonatedcellulosenanofibersaselectrolytemembranesinfuelcells. Cellulose 2021 , 28 ,1355−1367..

Reddy,M.S.B.;Ponnamma,D.;Choudhary,R.;Sadasivuni,K.K.Acomparativereviewofnaturalandsyntheticbiopolymercompositescaffolds. Polymers 2021 , 13 ,1105..

Selyanchyn,O.;Selyanchyn,R.;Lyth,S.M.Areviewofprotonconductivityincellulosicmaterials. Front. Energy Res. 2020 , 8 ,1−17..

Smirnov,M.A.;Sokolova,M.P.;Bobrova,N.V.;Toikka,A.M.;Morganti,P.;Lahderanta,E.Synergisticeffectofchitinnanofibersandpolyacrylamideonelectrochemicalperformanceoftheirternarycompositewithpolypyrrole. J. Energy Chem. 2018 , 27 ,843−853..

Vijayakumar,V.;Nam,S.Y.Areviewofrecentchitosananionexchangemembranesforpolymerelectrolytemembranefuelcells. Membranes 2022 , 12 ,1−12..

Vorobiov,V.K.;Smirnov,M.A.;Bobrova,N.V.;Sokolova,M.P.Chitosan-supporteddeepeutecticsolventasbio-basedelectrolyteforflexiblesupercapacitor. Mater. Lett. 2021 , 283 ,128889..

Wang,B.;Han,X.;Wang,Y.;Kang,L.;Yang,Y.;Cui,L.;Zhong,S.;Cui,X.Fabricationofalginate-basedmulti-crosslinkedbiomembranesfordirectmethanolfuelcellapplication. Carbohydr. Polym. 2023 , 300 ,120261..

Tiwari,T.;Srivastava,N.Exploringthepossibilityofstarch-basedelectrolytemembraneinMFCapplication. Macromol. Symp. 2019 , 388 ,1−8..

Mohanapriya,S.;Rambabu,G.;Bhat,S.D.;Raj,V.Pectinbasednanocompositemembranesasgreenelectrolytesfordirectmethanolfuelcells. Arab. J. Chem. 2020 , 13 ,2024−2040..

Hernández-Flores,G.;Andrio,A.;Compañ,V.;Solorza-Feria,O.;Poggi-Varaldo,H.M.Synthesisandcharacterizationoforganicagar-basedmembranesformicrobialfuelcells. J. Power Sources 2019 , 435 ,.

KumarGupta,P.;SaiRaghunath,S.;VenkateshPrasanna,D.;Venkat,P.;Shree,V.;Chithananthan,C.;Choudhary,S.;Surender,K.;Geetha,K.Anupdateonoverviewofcellulose,itsstructureandapplications,in Cellulose ,IntechOpen, 2019 :bll1–21.

Heinze,T.;ElSeoud,O.A.;Koschella,A.Productionandcharacteristicsofcellulosefromdifferentsources, 2018 .

Gadim,T.D.O.;Loureiro,F.J.A.;Vilela,C.;Rosero-Navarro,N.;Silvestre,A.J.D.;Freire,C.S.R.;Figueiredo,F.M.L.Protonicconductivityandfuelcelltestsofnanocompositemembranesbasedonbacterialcellulose. Electrochim. Acta 2017 , 233 ,52−61..

Batishcheva,E.V.;Sokolova,D.N.;Fedotova,V.S.;Sokolova,M.P.;Nikolaeva,A.L.;Vakulyuk,A.Y.;Shakhbazova,C.Y.;Ribeiro,M.C.C.;Karttunen,M.;Smirnov,M.A.Strengtheningcellulosenanopaper via deepeutecticsolventandultrasound-inducedsurfacedisorderingofnanofibers. Polymers 2022 , 14 ,78..

Wang,Y.R.;Yin,C.C.;Zhang,J.M.;Wu,J.;Yu,J.;Zhang,J.Functionalcellulosematerialsfabricatedbyusingionicliquidsasthesolvent. Chinese J. Polym. Sci. 2023 , 41 ,483−499..

Lin,D.;Liu,Z.;Shen,R.;Chen,S.;Yang,X.Bacterialcelluloseinfoodindustry:currentresearchandfutureprospects. Int. J. Biol. Macromol. 2020 , 158 ,1007−1019..

Smirnov,M.A.;Fedotova,V.S.;Sokolova,M.P.;Nikolaeva,A.L.;Elokhovsky,V.Y.;Karttunen,M.Polymerizablecholine-andimidazolium-basedionicliquidsreinforcedwithbacterialcellulosefor3D-printing. Polymers 2021 , 13 ,3044..

Sathish,S.K.;Vitta,S. Bacterial Cellulose Based Nanocomposites for Electronic and Energy Applications .Elsevier. 2020 ..

Ramírez-Carmona,M.;Gálvez-Gómez,M.P.;González-Perez,L.;Pinedo-Rangel,V.;Pineda-Vasquez,T.;Hotza,D.Productionofbacterialcellulosehydrogelanditsevaluationasaprotonexchangemembrane. J. Polym. Environ . 2023 , 31 ,2462−2472..

Smirnov,M.A.;Vorobiov,V.K.;Sokolova,M.P.;Bobrova,N.V.;Lahderanta,E.;Hiltunen,S.;Yakimansky,A.V.Electrochemicalpropertiesofsupercapacitorelectrodesbasedonpolypyrroleandenzymaticallypreparedcellulosenanofibers. Polym. Sci. - Ser. C. 2018 , 60 ,228−239..

Shu,Y.;Bai,Q.;Fu,G.;Xiong,Q.;Li,C.;Ding,H.;Shen,Y.;Uyama,H.Hierarchicalporouscarbonsfrompolysaccharidescarboxymethylcellulose,bacterialcellulose,andcitricacidforsupercapacitor. Carbohydr. Polym. 2020 , 227 ,115346..

Lahiri,D.;Nag,M.;Dutta,B.;Dey,A.;Sarkar,T.;Pati,S.;Edinur,H.A.;Kari,Z.A.;Noor,N.H.M.;Ray,R.R.Bacterialcellulose:production,characterizationandapplicationasantimicrobialagent. Int. J. Mol. Sci. 2021 , 22 ,1−18..

Mishra,S.;Singh,P.K.;Pattnaik,R.;Kumar,S.;Ojha,S.K.;Srichandan,H.;Parhi,P.K.;Jyothi,R.K.;Sarangi,P.K.Biochemistry,synthesis,andapplicationsofbacterialcellulose:areview. Front. Bioeng. Biotechnol. 2022 , 10 ,1−12..

Jiang,G.;Zhang,J.;Qiao,J.;Jiang,Y.;Zarrin,H.;Chen,Z.;Hong,F.Bacterialnanocellulose/Nafioncompositemembranesforlowtemperaturepolymerelectrolytefuelcells. J. Power Sources 2015 , 273 ,697−706..

Gadim,T.D.O.;Vilela,C.;Loureiro,F.J.A.;Silvestre,A.J.D.;Freire,C.S.R.;Figueiredo,F.M.L.Nafion®andnanocellulose:apartnershipforgreenerpolymerelectrolytemembranes. Ind. Crops Prod. 2016 , 93 ,212−218..

Samaniego,A.J.;Espiritu,R.Prospectsonutilizationofbiopolymermaterialsforionexchangemembranesinfuelcells. Green Chem. Lett. Rev. 2022 , 15 ,253−275..

Dahlström,C.;LópezDurán,V.;Keene,S.T.;Salleo,A.;Norgren,M.;Wågberg,L.IonconductivitythroughTEMPO-mediatedoxidatedandperiodateoxidatedcellulosemembranes. Carbohydr. Polym. 2020 , 233 ,115829..

Rana,H.H.;Park,J.H.;Gund,G.S.;Park,H.S.Highlyconducting,extremelydurable,phosphorylatedcellulose-basedionogelsforrenewableflexiblesupercapacitors. Energy Storage Mater. 2020 , 25 ,70−75..

Yue,L.;Zheng,Y.;Xie,Y.;Liu,S.;Guo,S.;Yang,B.;Tang,T.Preparationofacarboxymethylatedbacterialcellulose/polyanilinecompositegelmembraneanditscharacterization. RSC Adv. 2016 , 6 ,68599−68605..

Yue,L.;Xie,Y.;Zheng,Y.;He,W.;Guo,S.;Sun,Y.;Zhang,T.;Liu,S.Sulfonatedbacterialcellulose/polyanilinecompositemembraneforuseasgelpolymerelectrolyte. Compos. Sci. Technol. 2017 , 145 ,122−131..

Sriruangrungkamol,A.;Chonkaew,W.Modificationofnanocellulosemembranebyimpregnationmethodwithsulfosuccinicacidfordirectmethanolfuelcellapplications. Polym. Bull. 2021 , 78 ,3705−3728..

Hao,Y.;Qu,J.;Tan,L.;Liu,Z.;Wang,Y.;Lin,T.;Yang,H.;Peng,J.;Zhai,M.Synthesisandpropertyofsuperabsorbentpolymerbasedoncellulosegrafted2-acrylamido-2-methyl-1-propanesulfonicacid. Int. J. Biol. Macromol. 2023 , 233 ,123643..

Anirudhan,T.S.;Rejeena,S.R.Poly(acrylicacid- co -acrylamide- co -2-acrylamido-2-methyl-1-propanesulfonicacid)-graftednanocellulose/poly(vinylalcohol)compositeforthe in vitro gastrointestinalreleaseofamoxicillin. J. Appl. Polym. Sci. 2014 , 131 ,8657−8668..

Prosvirnina,A.P.;Bugrov,A.N.;Dobrodumov,A.V.;Vlasova,E.N.;Fedotova,V.S.;Nikolaeva,A.L.;Vorobiov,V.K.;Sokolova,M.P.;Smirnov,M.A.Bacterialcellulosenanofibersmodificationwith3-(trimethoxysilyl)propylmethacrylateasacrosslinkingandreinforcingagentfor3DprintableUV-curableinks. J. Mater. Sci. 2022 , 57 ,20543−20557..

Fager,C.;Gebäck,T.;Hjärtstam,J.;Röding,M.;Olsson,A.;Lorén,N.;vonCorswant,C.;Särkkä,A.;Olsson,E.Correlating3DporousstructureinpolymerfilmswithmasstransportpropertiesusingFIB-SEMtomography. Chem. Eng. Sci. X. 2021 , 12 ,100109..

Tessmar,J.;Holland,T.;Mikos,A.SaltLeachingforPolymerScaffolds,in Scaffolding In Tissue Engineering ,CRCPress, 2005 ,bll111–124.

Laatikainen,M.;Lindstrom,M.Generalsorptionisothermforswellingmaterials. Acta Polytech. Scand. Technol. Ser. 1987 , 178 ,105−116..

Smirnov,M.A.;Sokolova,M.P.;Bobrova,N.V.;Kasatkin,I.A.;Lahderanta,E.;Elyashevich,G.K.Capacitancepropertiesandstructureofelectroconductinghydrogelsbasedoncopoly(aniline-P-phenylenediamine)andpolyacrylamide. J. Power Sources 2016 , 304 ,102−110..

Gaylord,N.Proposednewmechanismforcatalyzedanduncatalyzedgraftpolymerizationontocellulose. J. Polym. Sci., Part C: Polym Symp. 1972 , 172 ,153−172..

Kalia,S.;Sabaa,M.W.in Polysaccharide based graft copolymers ,SpringerLink, 2013 ..

Jacek,P.;Kubiak,K.;Ryngajłło,M.;Rytczak,P.;Paluch,P.;Bielecki,S.ModificationofbacterialnanocellulosepropertiesthroughmutationofmotilityrelatedgenesinKomagataeibacterhanseniiATCC53582. N. Biotechnol. 2019 , 52 ,60−68..

Gelenter,M.D.;Wang,T.;Liao,S.Y.;O’Neill,H.;Hong,M. 2 H- 13 Ccorrelationsolid-stateNMRforinvestigatingdynamicsandwateraccessibilitiesofproteinsandcarbohydrates. J. Biomol. NMR . 2017 , 68 ,257–270..

Fedotova,V.S.;Sokolova,M.P.;Vorobiov,V.K.;Sivtsov,E.V.;Lukasheva,N.V.;Smirnov,M.A.Waterinfluenceonthephysico-chemicalpropertiesand3Dprintabilityofcholineacrylate—bacterialcelluloseinks. Polymers 2023 , 15 ,2156..

Porwal,S.;Diwedi,A.;Kamal,M. 13 CNMRandRamanstudiesoffullerene-basedpoly(acrylamides). Int. J. Org. Chem . 2012 , 02 ,377–386..

Devrim,Y.G.;Rzaev,Z.M.O.;Pişkin,E.Synthesisandcharacterizationofpoly[((maleicanhydride)- alt -styrene)- co -(2-acrylamido-2-methyl-1-propanesulfonicacid)]. Macromol. Chem. Phys. 2006 , 207 ,111−121..

Qiao,J.;Hamaya,T.;Okada,T.Newhighlyproton-conductingmembranepoly(vinylpyrrolidone)(PVP)modifiedpoly(vinylalcohol)/2-acrylamido-2-methyl-1-propanesulfonicacid(PVA-PAMPS)forlowtemperaturedirectmethanolfuelcells(DMFCs). Polymer 2005 , 46 ,10809−10816..

Mondal,M.I.H.Mechanismofstructureformationofmicrobialcelluloseduringnascentstage. Cellulose 2013 , 20 ,1073−1088..

Jiang,G.;Qiao,J.;Hong,F.Applicationofphosphoricacidandphyticacid-dopedbacterialcelluloseasnovelproton-conductingmembranestoPEMFC. Int. J. Hydrogen Energy. 2012 , 37 ,9182−9192..

Ni,C.;Wang,H.;Zhao,Q.;Liu,B.;Sun,Z.;Zhang,M.;Hu,W.;Liang,L.Crosslinkingeffectinnanocrystallinecellulosereinforcedsulfonatedpoly(aryletherketone)protonexchangemembranes. Solid State Ionics 2018 , 323 ,5−15..

Selyanchyn,O.;Bayer,T.;Klotz,D.;Selyanchyn,R.;Sasaki,K.;Lyth,S.M.Cellulosenanocrystalscrosslinkedwithsulfosuccinicacidassustainableprotonexchangemembranesforelectrochemicalenergyapplications. Membranes 2022 , 12 ,658..

Gadim,T.D.O.;Figueiredo,A.G.P.R.;Rosero-Navarro,N.C.;Vilela,C.;Gamelas,J.A.F.;Barros-Timmons,A.;Neto,C.P.;Silvestre,A.J.D.;Freire,C.S.R.;Figueiredo,F.M.L.Nanostructuredbacterialcellulose-poly(4-styrenesulfonicacid)compositemembraneswithhighstoragemodulusandprotonicconductivity. ACS Appl. Mater. Interfaces. 2014 , 6 ,7864−7875..

BagusPambudi,A.;Priyangga,A.;Hartanto,D.;Atmaja,L.Fabricationandcharacterizationofmodifiedmicrocrystallinecellulosemembraneasprotonexchangemembranefordirectmethanolfuelcell. Mater. Today Proc. 2020 , 46 ,1855−1859..

Vilela,C.;Silva,A.C.Q.;Domingues,E.M.;Gonçalves,G.;Martins,M.A.;Figueiredo,F.M.L.;Santos,S.A.O.;Freire,C.S.R.Conductivepolysaccharides-basedproton-exchangemembranesforfuelcellapplications:thecaseofbacterialcelluloseandfucoidan. Carbohydr. Polym. 2020 , 230 ,115604..

Guccini,V.;Carlson,A.;Yu,S.;Lindbergh,G.;Lindström,R.W.;Salazar-Alvarez,G.Highlyprotonconductivemembranesbasedoncarboxylatedcellulosenanofibresandtheirperformanceinprotonexchangemembranefuelcells. J. Mater. Chem. A 2019 , 7 ,25032−25039..

Eikerling,M.;Kornyshev,A.A.Protontransferinasingleporeofapolymerelectrolytemembrane. J. Electroanal. Chem. 2001 , 502 ,1−14..

Vayenas,C.G.;Tsampas,M.N.;Katsaounis,A.FirstprinciplesanalyticalpredictionoftheconductivityofNafionmembranes. Electrochim. Acta 2007 , 52 ,2244−2256..

Zhou,J.;Zhang,R.;Xu,R.;Li,Y.;Tian,W.;Gao,M.;Wang,M.;Li,D.;Liang,X.;Xie,L.;Liang,K.;Chen,P.;Kong,B.Super-assembledhierarchicalcelluloseaerogel-gelatinsolidelectrolyteforimplantableandbiodegradablezincionbattery. Adv. Funct. Mater . 2022 , 32 ,2111406..

An,Y.;Yang,Y.;Hu,Z.;Guo,B.;Wang,X.;Yang,X.;Zhang,Q.;Wu,H.High-performancesymmetricsupercapacitorsbasedoncarbonnanosheetsframeworkwithgraphenehydrogelarchitecturederivedfromcelluloseacetate. J. Power Sources 2017 , 337 ,45−53..

Li,H.;Cao,L.;Zhang,H.;Tian,Z.;Zhang,Q.;Yang,F.;Yang,H.;He,S.;Jiang,S.Intertwinedcarbonnetworksderivedfrompolyimide/cellulosecompositeasporouselectrodeforsymmetricalsupercapacitor. J. Colloid Interface Sci. 2022 , 609 ,179−187..

Chen,L.F.;Huang,Z.H.;Liang,H.W.;Guan,Q.F.;Yu,S.H.Bacterial-cellulose-derivedcarbonnanofiber@MnO 2 andnitrogen-dopedcarbonnanofiberelectrodematerials:Anasymmetricsupercapacitorwithhighenergyandpowerdensity. Adv. Mater. 2013 , 25 ,4746−4752..

Li,K.;Li,P.;Sun,Z.;Shi,J.;Huang,M.;Chen,J.;Liu,S.;Shi,Z.;Wang,H.All-cellulose-basedquasi-solid-statesupercapacitorwithnitrogenandborondual-dopedcarbonelectrodesexhibitinghighenergydensityandexcellentcyclicstability. Green Energy Environ . 2022 , 8 ,1091−1101..

Smirnov,M.A.;Tarasova,E.V.;Vorobiov,V.K.;Kasatkin,I.A.;Mikli,V.;Sokolova,M.P.;Bobrova,N.V.;Vassiljeva,V.;Krumme,A.;Yakimanskiy,A.V.Electroconductivefibrousmatpreparedbyelectrospinningofpolyacrylamide- g -polyanilinecopolymersaselectrodematerialforsupercapacitors. J. Mater. Sci. 2019 , 54 ,4859−4873..

Smirnov,M.A.;Vorobiov,V.K.;Kasatkin,I.A.;Vlasova,E.N.;Sokolova,M.P.;Bobrova,N.V.Long-termelectrochemicalstabilityofpolyaniline-andpolypyrrole-basedhydrogels. Chem. Pap. 2021 , 75 ,5103−5112..

Sun,Z.;Thielemans,W.Interconnectedandhighcyclingstabilitypolypyrrolesupercapacitorsusingcellulosenanocrystalsandcommonlyusedinorganicsaltsasdopants. J. Energy Chem. 2023 , 76 ,165−174..

Tanguy,N.R.;Wu,H.;Nair,S.S.;Lian,K.;Yan,N.Lignincellulosenanofibrilsasanelectrochemicallyfunctionalcomponentforhigh-performanceandflexiblesupercapacitorelectrodes. ChemSusChem. 2021 , 14 ,1057−1067..

Sun,Y.;Yang,Y.;Fan,L.;Zheng,W.;Ye,D.;Xu,J.Polypyrrole/SnCl 2 modifiedbacterialcelluloseelectrodeswithhigharealcapacitanceforflexiblesupercapacitors. Carbohydr. Polym. 2022 , 292 ,119679..

Smirnov,M.A.;Sokolova,M.P.;Geydt,P.;Smirnov,N.N.;Bobrova,N.V.;Toikka,A.M.;Lahderanta,E.Dualdopedelectroactivehydrogelicfibrousmatwithhigharealcapacitance. Mater. Lett. 2017 , 199 ,192−195..

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Ion-conducting Membranes Based on Bacterial Cellulose Nanofibers Modified by Poly(sodium acrylate-co-2-acrylamido-2-methylpropanesulfonic acid)

DOI：10.1007/s10118-023-3054-8

摘要

Abstract

关键词

Keywords

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