Porous Shish-Kebab Structure Prepared from Oriented UHMWPE Films by Processing in Supercritical CO<sub>2</sub>

Sergey A. Lermontov; Aleksey V. Maksimkin; Nataliya A. Sipyagina; Tarek Dayyoub; Alena N. Malkova; Evgeniy A. Kolesnikov; Elena A. Straumal; Inna O. Gozhikova; Saidkhodzha G. Nematulloev; Dmitry V. Telyshev

doi:10.1007/s10118-023-3036-x

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Porous Shish-Kebab Structure Prepared from Oriented UHMWPE Films by Processing in Supercritical CO₂

RESEARCH ARTICLE | Updated：2023-12-26

- Porous Shish-Kebab Structure Prepared from Oriented UHMWPE Films by Processing in Supercritical CO₂
- Porous Shish-Kebab Structure Prepared from Oriented UHMWPE Films by Processing in Supercritical CO₂
- 高分子科学（英文版） 2024年42卷第1期页码：97-104
- Affiliations：
  
  a.Institute of Physiologically Active Compounds of the Russian Academy of Sciences, Chernogolovka 142432, Russia
  b.Institute for Bionic Technologies and Engineering, I.M. Sechenov First Moscow State Medical University (Sechenov University), Moscow 119991, Russia
  c.National University of Science and Technology "MISIS", Moscow 119049, Russia
  d.Institute of Biomedical Systems, National Research University of Electronic Technology, Zelenograd, Moscow 124498, Russia
- Author bio：
  
  lermontov52@yandex.ru (S.A.L.)
  tarekzd@windowslive.com (T.D.)
- Funds：
  
  This work was financially supported by the Academic leadership program Priority 2030 proposed by Federal State Autonomous Educational Institution of Higher Education I.M. Sechenov First Moscow State Medical University of the Ministry of Health of the Russian Federation (Sechenov University). The preparation and modification of UHMWPE samples were financially supported by the Russian Science Foundation (No. 18-13-00145), SEM investigation was supported by the State Assignment (No. 0090-2019-0002, IPAC RAS).
- DOI：10.1007/s10118-023-3036-x
  中图分类号：
- 收稿：2023-04-03，
  
  修回：2023-7-17，
  
  录用：2023-7-24，
  
  网络首发：2023-08-31，
  
  纸质出版：2024-01-01
- Accepted：
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Porous Shish-Kebab Structure Prepared from Oriented UHMWPE Films by Processing in Supercritical CO₂[J]. 高分子科学（英文版）, 2024,42(1):97-104. DOI: 10.1007/s10118-023-3036-x.

Sergey A. Lermontov, Aleksey V. Maksimkin, Nataliya A. Sipyagina, et al. Porous Shish-Kebab Structure Prepared from Oriented UHMWPE Films by Processing in Supercritical CO₂[J]. Chinese Journal of Polymer Science, 2024, 42(1): 97-104. DOI: 10.1007/s10118-023-3036-x.
Porous Shish-Kebab Structure Prepared from Oriented UHMWPE Films by Processing in Supercritical CO₂[J]. 高分子科学（英文版）, 2024,42(1):97-104. DOI: 10.1007/s10118-023-3036-x. DOI：

Sergey A. Lermontov, Aleksey V. Maksimkin, Nataliya A. Sipyagina, et al. Porous Shish-Kebab Structure Prepared from Oriented UHMWPE Films by Processing in Supercritical CO₂[J]. Chinese Journal of Polymer Science, 2024, 42(1): 97-104. DOI: 10.1007/s10118-023-3036-x. DOI：

摘要

A highly crystalline porous "shish-kebab" structure with a high degree of crystallinity can be prepared by the treatment of the oriented UHMWPE films using supercritical carbon dioxide (scCO2). The particularity of the prepared porous shish-kebab is the absence of the amorphous phase between kebab crystals. Controlling the conditions for the crystallization of the UHMWPE macromolecules using supercritical CO2 gives the possibility to control the size of both lamellar disks and pores formed.

Abstract

For the first time

a highly crystalline porous shish-kebab structure with a high degree of crystallinity was obtained by using a combination of two methods for the formation of porous polymeric materials. A treatment procedure using supercritical carbon dioxide (scCO

) was carried out for oriented ultrahigh molecular weight polyethylene (UHMWPE) films

which provided special conditions for the crystallization of dissolved UHMWPE macromolecules on the surface of oriented UHMWPE crystals. The prepared porous materials were investigated by scanning electron microscopy (SEM) and differential scanning calorimetry (DSC). The particularity of the obtained porous shish-kebab is the absence of the amorphous phase between lamellar crystals (kebabs). The obtained pores had an oval shape

and they were oriented in the orientation direction of the UHMWPE macromolecules. The pore size ranged from 0.05 μm to 4 μm. Controlling the conditions for the crystallization of the UHMWPE macromolecules using supercritical CO

gives the possibility to control the size of both lamellar disks and pores formed.

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Porous Shish-Kebab Structure Prepared from Oriented UHMWPE Films by Processing in Supercritical CO2

Porous Shish-Kebab Structure Prepared from Oriented UHMWPE Films by Processing in Supercritical CO2

DOI：10.1007/s10118-023-3036-x

摘要

Abstract

关键词

Keywords

references

Porous Shish-Kebab Structure Prepared from Oriented UHMWPE Films by Processing in Supercritical CO₂

Porous Shish-Kebab Structure Prepared from Oriented UHMWPE Films by Processing in Supercritical CO₂