The Role of Renewable Protocatechol Acid in Epoxy Coating Modification: Significantly Improved Antibacterial and Adhesive Properties

Ming-Xuan Chen; Jin-Yue Dai; Li-Yue Zhang; Shuai-Peng Wang; Jing-Kai Liu; Yong-Gang Wu; Xin-Wu Ba; Xiao-Qing Liu

doi:10.1007/s10118-023-3029-9

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The Role of Renewable Protocatechol Acid in Epoxy Coating Modification: Significantly Improved Antibacterial and Adhesive Properties

RESEARCH ARTICLE | Updated：2023-12-26

- The Role of Renewable Protocatechol Acid in Epoxy Coating Modification: Significantly Improved Antibacterial and Adhesive Properties
- The Role of Renewable Protocatechol Acid in Epoxy Coating Modification: Significantly Improved Antibacterial and Adhesive Properties
- 高分子科学（英文版） 2024年42卷第1期页码：63-72
- Affiliations：
  
  a.School of Chemistry and Materials Science, Hebei University, Baoding 071000, China
  b.Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
  c.Key Laboratory of Marine Materials and Related Technologies, Chinese Academy of Sciences, Ningbo 315201, China
- Author bio：
  
  daijinyue@nimte.ac.cn (J.Y.D.)
  baxw@hbu.edu.cn (X.W.B.)
  liuxq@nimte.ac.cn (X.Q.L.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. U1909220 and 52003283), Science and Technology Innovation 2025 Major Project of Ningbo (Nos. 2021Z092, 2022Z111 and 2022Z160), Defense Industrial Technology Development Program (No. JCKY2021513B001) and the Research Project of Technology Application for Public Welfare of Ningbo City (No. 202002N3122).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-3029-9.
- DOI：10.1007/s10118-023-3029-9
  中图分类号： M
- 收稿：2023-06-08，
  
  修回：2023-7-3，
  
  录用：2023-7-14，
  
  网络首发：2023-08-23，
  
  纸质出版：2024-01-01
- Accepted：
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Chen, M. X.; Dai, J. Y.; Zhang, L. Y.; Wang, S. P.; Liu, J. K.; Wu, Y. G.; Ba, X. W.; Liu, X. Q. The role of renewable protocatechol acid in epoxy coating modification: significantly improved antibacterial and adhesive properties. Chinese J. Polym. Sci. 2024, 42, 63–72

Ming-Xuan Chen, Jin-Yue Dai, Li-Yue Zhang, et al. The Role of Renewable Protocatechol Acid in Epoxy Coating Modification: Significantly Improved Antibacterial and Adhesive Properties[J]. Chinese Journal of Polymer Science, 2024, 42(1): 63-72.
Chen, M. X.; Dai, J. Y.; Zhang, L. Y.; Wang, S. P.; Liu, J. K.; Wu, Y. G.; Ba, X. W.; Liu, X. Q. The role of renewable protocatechol acid in epoxy coating modification: significantly improved antibacterial and adhesive properties. Chinese J. Polym. Sci. 2024, 42, 63–72 DOI： 10.1007/s10118-023-3029-9.

Ming-Xuan Chen, Jin-Yue Dai, Li-Yue Zhang, et al. The Role of Renewable Protocatechol Acid in Epoxy Coating Modification: Significantly Improved Antibacterial and Adhesive Properties[J]. Chinese Journal of Polymer Science, 2024, 42(1): 63-72. DOI： 10.1007/s10118-023-3029-9.

摘要

A multi-functional epoxy coating was prepared by using protocatechinic acid (PCA) as raw material in this paper

reacting with ethylene glycol diglycidyl ether (EGDE) by one-step method and curing with isophorone diamine (IPDA). It demonstrated outstanding adhesion and antibacterial activity

the highest adhesion was 13.60 MPa

and the highest antibacterial rate was 100%.

Abstract

It is of great significance to design epoxy coatings with superior antibacterial properties and high adhesive properties

as well as excellent processing

superior durability

and high transparency. However

it is still a challenge because of the common complex design and synthesis. Herein

the bio-based monomer protocatechuic acid (PCA) was used as raw material

the catechol structure with high bonding and antibacterial properties was introduced into the flexible alkane segment of ethylene glycol diglycidyl ether (EGDE) through an efficient

and green method

and it was cured with isophorone diamine (IPDA) to prepare corresponding thermosets. The cured resins exhibited excellent all-around qualities

particularly in bonding and antibacterial. When 30% PCA was added to pure epoxy resin

the adhesion between substrate and coating increased from 4.40 MPa to 13.60 MPa and the antibacterial rate of coating against

E. coli

and

S. aureus

could approach 100%. All of this is due to the fact that the catechol structure present in PCA has the ability to interact with various substrates and alter the permeability of bacterial cell membranes. The architecture of this method offers a fresh approach to dealing with the issues of challenging raw material selection and complex synthesis techniques.

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