MOF-derived Porous Carbon Nanofiber Assembly as High Efficiency ORR Electrocatalysts for Zinc-air Batteries

Jin-Liang Ma; Long-Long Liu; Ren-Hai Zhao; Ding Yuan; Xin Ning

doi:10.1007/s10118-023-3006-3

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MOF-derived Porous Carbon Nanofiber Assembly as High Efficiency ORR Electrocatalysts for Zinc-air Batteries

RESEARCH ARTICLE | Updated：2023-11-27

- MOF-derived Porous Carbon Nanofiber Assembly as High Efficiency ORR Electrocatalysts for Zinc-air Batteries
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- MOF-derived Porous Carbon Nanofiber Assembly as High Efficiency ORR Electrocatalysts for Zinc-air Batteries
- 高分子科学（英文版） 2023年41卷第12期页码：1889-1901
- Affiliations：
  
  1.Industrial Research Institute of Nonwovens & Technical Textiles, Shandong Center for Engineered Nonwovens, College of Textiles & Clothing, Qingdao University, Qingdao 266071, China
- Author bio：
  
  yuanding@qdu.edu.cn (D.Y.)
  xning@qdu.edu.cn (X.N.)
- Funds：
  
  This work was financially supported by a key project of the State Key Laboratory of Bio-Fibers and Eco-Textiles of Qingdao University (No. RZ2000003348) and Major Scientific and Technological Innovation Projects of Shandong Province (No. RZ2000001594).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-3006-3.
- DOI：10.1007/s10118-023-3006-3
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Ma, J. L.; Liu, L. L.; Zhao, R. H.; Yuan, D.; Ning, X. MOF-derived porous carbon nanofiber assembly as high efficiency ORR electrocatalysts for zinc-air batteries. Chinese J. Polym. Sci. 2023, 41, 1889–1901

Jin-Liang Ma, Long-Long Liu, Ren-Hai Zhao, et al. MOF-derived Porous Carbon Nanofiber Assembly as High Efficiency ORR Electrocatalysts for Zinc-air Batteries[J]. Chinese Journal of Polymer Science, 2023,41(12):1889-1901.
Ma, J. L.; Liu, L. L.; Zhao, R. H.; Yuan, D.; Ning, X. MOF-derived porous carbon nanofiber assembly as high efficiency ORR electrocatalysts for zinc-air batteries. Chinese J. Polym. Sci. 2023, 41, 1889–1901 DOI： 10.1007/s10118-023-3006-3.

Jin-Liang Ma, Long-Long Liu, Ren-Hai Zhao, et al. MOF-derived Porous Carbon Nanofiber Assembly as High Efficiency ORR Electrocatalysts for Zinc-air Batteries[J]. Chinese Journal of Polymer Science, 2023,41(12):1889-1901. DOI： 10.1007/s10118-023-3006-3.

摘要

Carbon nanofiber materials with special core-shell structure were developed by using bimetallic MOF as precursor, electrospinning, electrodeposition and high temperature carbonization. High performance ORR catalyst containing Fe-N,X,C active sites, Co-N,X,C active sites and Co nanoparticles co-exists in hollow porous carbon fibers.

Abstract

Reasonable construction of high activity and low cost non-noble metal oxygen reduction reaction (ORR) catalyst is of great importance for the wide application of zinc-air batteries (ZABs). Using bimetallic MOF as a precursor combined with electrospinning, high-temperature carbonization and electrodeposition, we successfully developed a porous carbon nanofiber (Co@Fe-CNFs-1000) with bimetallic active center as an efficient catalyst for ORR. The successful construction of this special core-shell structure directly explores the synergy between different active centers. The results showed that the synthesized Co@Fe-CNFs-1000 catalyst exhibited ORR performance comparable to that of Pt/C in 0.1 mol/L KOH electrolyte, high half-wave potential (,E,1/2,=0.81 V) and limiting current density (,J,L,=5.4 mA·cm,−2,). In addition, homemade liquid ZABs with Co@Fe-CNFs-1000 as the air cathode showed excellent power density (155.8 mW·cm,−2,), specific capacity (780.6 mAh·g,Zn,−1,) and long-term stability (over 100 h at 2 mA·cm,−2,), surpassing even Pt/C-based batteries. In addition, the flexible solid-state ZABs assembled based on Co@Fe-CNFs-1000 demonstrates excellent flexibility and durability. This work provides a new idea for constructing ORR catalysts with high activity centers.

关键词

Keywords

ElectrospinningPorous structureORRBimetallic MOFsZinc-air battery

references

Wang,H.;Su,S.;Yu,T.;Meng,C.;Zhou,H.;Zhao,W.;Yan,S.;Bian,T.;Yuan,A.FeNi/NiFe2O4hybridsconfinedinN-dopedcarbonspongederivedfromHofmann-typeMOFsforoxygenelectrocatalysis.Appl. Surf. Sci.2022,596,153522..

Ao,K.;Shi,J.;Zhang,X.;Daoud,W.A.Tuningoxygenvacanciesinspinelnanosheetsforbinder-freeoxygencathodeswithsuperiorcatalyticactivityinzinc-airbatteries.J. Power Sources2022,521,230918..

Harish,K.;Balamurugan,J.;Nguyen,T.T.;Kim,N.H.;Lee,J.H.Advancedinterfacialengineeringofoxygen-enrichedFexSn1−xOSenanostructuresforefficientoverallwatersplittingandflexiblezinc-airbatteries.Appl. Catal. B Environ.2022,305,120924..

Zuo,H.;Zhao,Z.;He,Y.;Li,S.;Li,X.;Cheng,Z.;Cheng,C.;Thomas,A.;Liao,Y.Regulatingsingle-atomdistanceincarbonelectrocatalystsforefficientoxygenreductionreactionviaconjugatedmicroporouspolymerprecursorsstrategy.Carbon2023,201,984−990..

Subjalearndee,N.;He,N.;Cheng,H.;Tesatchabut,P.;Eiamlamai,P.;Limthongkul,P.;Intasanta,V.;Gao,W.;Zhang,X.Gamma(γ)-MnO2/rGOfiberedcathodefabricationfromwetspinninganddipcoatingtechniquesforcable-shapedZn-ionbatteries.Adv. Fiber Mater.2022,4,457−474..

Liu,Y.;Chen,Z.;Zhao,N.;Tong,G.;Li,Z.;Wang,B.;Du,Y.;Pan,Q.;Li,Z.;Xie,Y.;Yang,Y.Ultra-smallcobaltnanoparticlesembeddedintoN-dopedhierarchicalporouscarbonderivedfromion-exchangeMOFsashigh-efficientbifunctionalcatalystsforrechargeableZn-airbattery.Chem. Eng. J.2022,433,134469..

Zhu,Y.;Ning,S.;Yu,X.;Niu,X.;Chen,M.;Zhou,W.;Zhao,D.;Li,Z.;Wang,N.;Li,N.;Li,L.Cobaltnanoparticlesencapsulatedinironandnitrogenco-dopedurchin-likeporouscarbonsasanefficientbifunctionaloxygenreversiblecatalystforZn-airbatteries.Chem. Eng. J.2022,436,135191..

Najam,T.;ShoaibAhmadShah,S.;SufyanJaved,M.;Chen,P.-T.;Chuang,C.;Saad,A.;Song,Z.;Liu,W.;Cai,X.ModulatingtheelectronicstructureofzincsingleatomcatalystbyP/NcoordinationandCo2PsupportsforefficientoxygenreductioninZn-airbattery.Chem. Eng. J.2022,440,135928..

Yu,P.;Wang,L.;Sun,F.;Xie,Y.;Liu,X.;Ma,J.;Wang,X.;Tian,C.;Li,J.;Fu,H.ConanoislandsrootedonCo-N-CnanosheetsasefficientoxygenelectrocatalystforZn-airbatteries.Adv. Mater.2019,31,1901666..

Pan,Z.;Chen,H.;Yang,J.;Ma,Y.;Zhang,Q.;Kou,Z.;Ding,X.;Pang,Y.;Zhang,L.;Gu,Q.;Yan,C.;Wang,J.CuCo2S4nanosheets@N-dopedcarbonnanofibersbysulfurizationatroomtemperatureasbifunctionalelectrocatalystsinflexiblequasi-solid-stateZn-airbatteries.Adv. Sci.2019,6,1900628..

Liu,Q.;Liu,X.;Xie,Y.;Sun,F.;Liang,Z.;Wang,L.;Fu,H.N-DopedcarboncoatingenhancesthebifunctionaloxygenreactionactivityofCoFenanoparticlesforahighlystableZn-airbattery.J. Mater. Chem. A2020,8,21189−21198..

Guo,W.;Zhang,Z.;Chen,P.;Luan,X.;Dou,J.;Bai,J.;Fang,H.;Shi,W.;Zhou,B.CMP-on-MOFbimetallichybridsderivedsheet-on-rodheterostructureasbifunctionaloxygenelectrocatalystforrechargeableZn-airbatteries.Microporous Mesoporous Mater.2022,331,111639..

Thangasamy,P.;Oh,S.;Randriamahazaka,H.;Nam,S.;Oh,I.-K.MechanisticinsightintocollectivelyexhaustiveCoPi-NPCnanosheetsforoxygenreductionreactionandZn-airbattery.Appl. Catal. B Environ.2022,316,121656..

Ma,L.;Hu,X.;Min,Y.;Zhang,X.;Liu,W.;Lam,P.K.S.;Li,M.M.J.;Zeng,R.J.;Ye,R.Microalgae-derivedsingle-atomoxygenreductioncatalystsforzinc-airbatteries.Carbon2023,203,827−834..

Wang,F.;Xiao,Z.;Liu,X.;Ren,J.;Xing,T.;Li,Z.;Li,X.;Chen,Y.Strategicdesignofcellulosenanofibers@zeoliticimidazolateframeworksderivedmesoporouscarbon-supportednanoscaleCoFe2O4/CoFehybridcompositionastrifunctionalelectrocatalystforZn-airbatteryandself-poweredoverallwater-splitting.J. Power Sources2022,521,230925..

Yang,H.;Xie,A.;Tang,Y.;Wang,Z.;Zhang,J.;Kong,L.;Song,P.;Sun,Y.;Yang,X.;Wan,P.Fe-ZIF8coatingcufoilderivedcarbonasapH-universalelectrocatalystforefficientoxygenreductionreaction.Chem. Eur. J.2022,28,e202103275..

Zhai,W.;Huang,S.;Lu,C.;Tang,X.;Li,L.;Huang,B.;Hu,T.;Yuan,K.;Zhuang,X.;Chen,Y.Simultaneouslyintegrateironsingleatomandnanoclustertriggeredtandemeffectforboostingoxygenelectroreduction.Small2022,18,2107225..

Liu,M.;Lee,J.;Yang,T.C.;Zheng,F.;Zhao,J.;Yang,C.M.;Lee,L.Y.S.SynergiesofFesingleatomsandclustersonN-dopedcarbonelectrocatalystforpH-universaloxygenreduction.Small Methods2021,5,2001165..

Liu,Y.;He,S.;Huang,B.;Kong,Z.;Guan,L.InfluenceofdifferentFedopingstrategiesonmodulatingactivesitesandoxygenreductionreactionperformanceofFe,N-dopedcarbonaceouscatalysts.J. Energy Chem.2022,70,511−520..

Hu,Y.;Shen,T.;Zhao,X.;Zhang,J.;Lu,Y.;Shen,J.;Lu,S.;Tu,Z.;Xin,H.L.;Wang,D.CombiningstructurallyorderedintermetallicswithN-dopedcarbonconfinementforefficientandanti-poisoningelectrocatalysis.Appl. Catal. B Environ.2020,279,119370..

Li,D.;Liang,J.;Robertson,S.J.;Chen,Y.;Wang,N.;Shao,M.;Shi,Z.Heterogeneousbimetallicorganiccoordinationpolymer-derivedCo/Fe@NCbifunctionalcatalystsforrechargeableLi-O2batteries.ACS Appl. Mater. Interfaces2022,14,5459−5467..

Zhong,B.;Zhang,L.;Yu,J.;Fan,K.Ultrafineiron-cobaltnanoparticlesembeddedinnitrogen-dopedporouscarbonmatrixforoxygenreductionreactionandzinc-airbatteries.J. Colloid Interface Sci.2019,546,113−121..

Li,J.;Liu,P.;Yan,J.;Huang,H.;Song,W.Fully-conjugatedcovalentorganicframeworkswithtwometalsitesforoxygenelectrocatalysisandZn-airbattery.Adv. Sci.2023,10,2206165..

Zhu,X.;Zhang,J.;Wang,Y.;Yang,M.;Yu,H.;Li,T.;Hu,M.;Yang,J.Achievinghigh-performanceoxygenreductioncatalystandZn-airbatterythroughasynergisticnitrogendopingstrategy.Energy Technol.2022,10,2200602..

Liu,Y.;Tu,F.;Zhang,Z.;Zhao,Z.;Guo,P.;Shen,L.;Zhang,Y.;Zhao,L.;Shao,G.;Wang,Z.MolecularscissortailoringhierarchicalarchitectureofZIF-derivedFe/N/Ccatalystsforacidicoxygenreductionreaction.Appl. Catal. B Environ.2023,324,122209..

Wang,T.;Gao,S.;Wei,T.;Qin,Y.;Zhang,S.;Ding,J.;Liu,Q.;Luo,J.;Liu,X.ConanoparticlesconfinedinmesoporousMo/Nco-dopedpolyhedralcarbonframeworkstowardshigh-efficiencyoxygenreduction.Chem. Eur. J.2023,29,e202204034.

Gao,H.;Zhu,S.;Kang,Y.;Dinh,D.A.;Hui,K.S.;Bin,F.;Fan,X.;Chen,F.;Mahmood,A.;Geng,J.;Cheong,W.C.M.;Hui,K.N.Zeoliticimidazolateframework-derivedCo-Fe@NCforrechargeablehybridsodium-airbatterywithalowvoltagegapandlongcyclelife.ACS Appl. Energy Mater.2022,5,1662−1671..

Song,K.;Feng,Y.;Zhou,X.;Qin,T.;Zou,X.;Qi,Y.;Chen,Z.;Rao,J.;Wang,Z.;Yue,N.;Ge,X.;Zhang,W.;Zheng,W.Exploitingthetrade-offsofelectrontransferinMOF-derivedsingleZn/Coatomiccouplesforperformance-enhancedzinc-airbattery.Appl. Catal. B Environ.2022,316,121591..

Yu,K.;Shi,P.H.;Fan,J.C.;Min,Y.L.;Xu,Q.J.PorousFe,Co,andN-co-dopedcarbonnanofibersashigh-efficiencyoxygenreductioncatalysts.J Nanopart Res2019,21,230..

Zhang,Y.;He,Q.;Chen,Z.;Chi,Y.;Sun,J.;Yuan,D.;Zhang,L.HierarchicallyporousCo@N-dopedcarbonfiberassembledbyMOF-derivedhollowpolyhedronsenableseffectiveelectronic/masstransport:anadvanced1DoxygenreductioncatalystforZn-airbattery.J. Energy Chem.2023,76,117−126..

Niu,Q.;Chen,B.;Guo,J.;Nie,J.;Guo,X.;Ma,G.Flexible,porous,andmetal-heteroatom-dopedcarbonnanofibersasefficientORRelectrocatalystsforZn-airbattery.Nanomicro Lett.2019,11,8..

Liu,X.;Zhang,Y.;Zhao,Z.;Gao,H.;Kang,J.;Wang,R.;Ge,G.;Jia,X.HighlyexposeddiscreteCoatomsanchoredinultrathinporousN,P-codopedcarbonnanosheetsforefficientoxygenelectrocatalysisandrechargeableaqueous/solid-stateZn-airbatteries.J. Mater. Chem. A2021,9,22643−22652..

Zhao,H.L.;Wu,S.;Liu,C.Y.;Yan,X.T.;Xu,X.;Fu,S.S.;Wang,Y.B.;Su,Q.;Wang,X.;Yang,Q.L.EncapsulationFe-NxcombinedwithCo@CtoconstructefficientoxygenreductioncatalystswithbimetallicsitesandtheapplicationofZn-airbatteries.Mater. Today Chem.2022,26,101174..

Li,G.;He,X.;Yin,F.;Chen,B.;Yin,H.Co-Fe/MIL-101(Cr)hybridcatalysts:preparationandtheirelectrocatalysisinoxygenreductionreaction.Int. J. Hydrog. Energy2019,44,11754−11764..

Chen,X.L.;Huang,J.W.;Huang,Y.C.;Du,J.;Jiang,Y.F.;Zhao,Y.;Zhu,H.B.EfficientFe-Co-N-CelectrocatalysttowardsoxygenreductionderivedfromacationicCoII-basedmetal-organicframeworkmodifiedbyanion-exchangewithpotassiumferricyanide.Chem. Asian J.2019,14,995−1003..

Zhang,Z.;Jin,H.;Zhu,J.;Li,W.;Zhang,C.;Zhao,J.;Luo,F.;Sun,Z.;Mu,S.3Dflower-likeZnFe-ZIFderivedhierarchicalFe,N-codopedcarbonarchitectureforenhancedoxygenreductioninbothalkalineandacidicmedia,andzinc-airbatteryperformance.Carbon2020,161,502−509..

Xue,Y.;Guo,Y.;Zhang,Q.;Xie,Z.;Wei,J.;Zhou,Z.MOF-derivedCoandFespeciesloadedonN-dopedcarbonnetworksasefficientoxygenelectrocatalystsforZn-airbatteries.Nanomicro Lett.2022,14,162..

Shen,M.;Lin,X.;Xi,W.;Yin,X.;Gao,B.;He,L.;Zheng,Y.;Lin,B.Mesoporouswaffle-likeN-dopedcarbonwithembeddedConanoparticlesforefficientlyelectrocatalyticoxygenreductionandevolution.J. Colloid Interface Sci.2023,633,374−382..

Guo,S.;Wang,J.;Sun,Y.;Peng,L.;Li,C.InterfaceengineeringofCo3O4/CeO2heterostructurein-situembeddedinCo/N-dopedcarbonnanofibersintegratingoxygenvacanciesaseffectiveoxygencathodecatalystforLi-O2battery.Chem. Eng. J.2023,452,139317..

Al-Zoubi,T.;Zhou,Y.;Yin,X.;Janicek,B.;Sun,C.;Schulz,C.E.;Zhang,X.;Gewirth,A.A.;Huang,P.;Zelenay,P.;Yang,H.Preparationofnonpreciousmetalelectrocatalystsforthereductionofoxygenusingalow-temperaturesacrificialmetal.J. Am. Chem. Soc.2020,142,5477−5481..

Peera,S.G.;Balamurugan,J.;Kim,N.H.;Lee,J.H.SustainablesynthesisofCo@NCcoreshellnanostructuresfrommetalorganicframeworksviamechanochemicalcoordinationself-assembly:anefficientelectrocatalystforoxygenreductionreaction.Small2018,14,1800441..

Zheng,Q.;Xiong,Y.;Tang,K.;Wu,M.;Hu,H.;Zhou,T.;Wu,Y.;Cao,Z.;Sun,J.;Yu,X.;Wu,C.Modulationofpore-sizeinN,S-codopedcarbon/Co9S8hybridforastrongerO2affinitytowardrechargablezinc-airbattery.Nano Energy2022,92,106750..

Long,J.;Zhou,D.;Chen,C.;Shen,K.StructuralandinterfaceengineeringofConanocatalystsinduceboostingtheelectrochemicalperformanceforrechargeablezinc-airbattery.Appl. Surf. Sci.2022,602,154304..

Meng,D.;Zhang,C.;Liang,Y.;Qiu,W.;Kong,F.;He,X.;Chen,M.;Liang,P.;Zhang,Z.Electrospuncobaltprussianblueanalogue-derivednanofibersforoxygenreductionreactionandlithium-ionbatteries.J. Colloid Interface Sci.2021,599,280−290..

Yang,H.;Hu,S.;Zhao,H.;Luo,X.;Liu,Y.;Deng,C.;Yu,Y.;Hu,T.;Shan,S.;Zhi,Y.;Su,H.;Jiang,L.High-performanceFe-dopedZIF-8adsorbentforcapturingtetracyclinefromaqueoussolution.J. Hazard. Mater.2021,416,126046..

Zhang,Y.;Chen,Z.;Tian,J.;Sun,M.;Yuan,D.;Zhang,L.NitrogendopedCuCo2O4nanoparticlesanchoredonbeaded-likecarbonnanofibersasanefficientbifunctionaloxygencatalysttowardzinc-airbattery.J. Colloid Interface Sci.2022,608,1105−1115..

Bai,Q.;Shen,F.C.;Li,S.L.;Liu,J.;Dong,L.Z.;Wang,Z.M.;Lan,Y.Q.Cobalt@nitrogen-dopedporouscarbonfiberderivedfromtheelectrospunfiberofbimetal-organicframeworkforhighlyactiveoxygenreduction.Small Methods2018,2,1800049..

He,H.;Lei,Y.;Liu,S.;Thummavichai,K.;Zhu,Y.;Wang,N.Tunableactive-sitesofConanoparticlesencapsulatedincarbonnanofiberashighperformancebifunctionalOER/ORRelectrocatalyst.J. Colloid Interface Sci.2023,630,140−149..

Hung,K.Y.;Hosseini,S.;Ko,T.E.;Tseng,C.M.;Li,Y.Y.HighlyefficientrechargeableZn-airbatteriesbasedonhybridCNT-grafted,Co/CoS2-Feembedded,Nitrogen-dopedporouscarbonnano-frameworks.Fuel2022,316,123328..

Du,L.;Gao,X.Y.;Li,Z.;Wang,G.Y.;Wen,Z.;Yang,C.C.;Jiang,Q.Metal-organicframeworksderivedCo/N-dopedcarbonnanonecklacesashigh-efficientoxygenreductionreactionelectrocatalysts.Int. J. Hydrog. Energy2022,47,39133−39145..

Hu,Z.;Dong,S.;He,Q.;Chen,Z.;Yuan,D.Synergeticnanostructureengineeringandelectronicmodulationofa3DhollowheterostructuredNiCo2O4@NiFe-LDHself-supportingelectrodeforrechargeableZn-airbatteries.Inorg. Chem.2023,62,7471−7482..

Jafari,M.;Gharibi,H.;Parnian,M.J.Metalorganicframeworkderivediron-nitrogendopedporouscarbonsupportdecoratedwithcobaltandironasefficientnanocatalysttowardoxygenreductionreaction.J. Power Sources2021,499,229956..

Sun,X.;Wei,P.;Zhang,J.;Gu,S.;Yang,R.;Fang,C.;Li,Q.;Han,J.;Jiang,Z.;He,J.P,N-codopedcarbonnanofibersconfinedultra-smallbimetallicNiCoPforhighlyefficientoverallwatersplitting.Appl. Surf. Sci.2021,570,151247..

Niu,Y.;Teng,X.;Gong,S.;Xu,M.;Sun,S.G.;Chen,Z.Engineeringtwo-phasebifunctionaloxygenelectrocatalystswithtunableandsynergeticcomponentsforflexibleZn-airbatteries.Nanomicro Lett.2021,13,126..

Li,K.;Zhang,Y.;Wang,P.;Long,X.;Zheng,L.;Liu,G.;He,X.;Qiu,J.Core-ShellZIF-67@ZIF-8-derivedmulti-dimensionalcobalt-nitrogendopedhierarchicalcarbonnanomaterialforefficientoxygenreductionreaction.J. Alloy. Compd.2022,903,163701..

Li,G.;Deng,W.;He,L.;Wu,J.;Liu,J.;Wu,T.;Wang,Y.;Wang,X.Zn,Co,andFetridopedN–Ccore-shellnanocagesasthehigh-efficiencyoxygenreductionreactionelectrocatalystinzinc-airbatteries.ACS Appl. Mater. Interfaces2021,13,28324−28333..

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