Understand the Temperature Sensing Behavior of Solid-state Polymerized PEDOT Hybrid Based on X-ray Scattering Studies

Zhen-Hang He; Guang-Feng Liu; Ze-Kun Zhou; Zhen Liu; Yi-Shu Zeng; Peng Zhang

doi:10.1007/s10118-023-3005-4

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Understand the Temperature Sensing Behavior of Solid-state Polymerized PEDOT Hybrid Based on X-ray Scattering Studies

RESEARCH ARTICLE | Updated：2023-12-26

- Understand the Temperature Sensing Behavior of Solid-state Polymerized PEDOT Hybrid Based on X-ray Scattering Studies
- Understand the Temperature Sensing Behavior of Solid-state Polymerized PEDOT Hybrid Based on X-ray Scattering Studies
- 高分子科学（英文版） 2024年42卷第1期页码：105-112
- Affiliations：
  
  a.School of Materials Science and Engineering, Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education, Sun Yat-sen University, Guangzhou 510275, China
  b.Shanghai Advanced Research Institute (Zhangjiang Laboratory), Chinese Academy of Sciences, Shanghai 201204, China
- Author bio：
  
  liuzh287@mail.sysu.edu.cn (Z.L.)
  zhangpeng3@mail.sysu.edu.cn (P.Z.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. U2032101 and 11905306), Fundamental Research Funds for the Central Universities (No. 19lgpy14) and “100 Top Talents Program” of Sun Yat-sen University. Ms. Huiyun Deng is thanked for her help during the sample preparation. This work was carried out with the support of 19U2 beamline at Shanghai Synchrotron Radiation Facility.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-3005-4.
- DOI：10.1007/s10118-023-3005-4
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He, Z. H.; Liu, G. F.; Zhou, Z. K.; Liu, Z.; Zeng, Y. S.; Zhang, P. Understand the temperature sensing behavior of solid-state polymerized PEDOT hybrid based on X-ray scattering studies. Chinese J. Polym. Sci. 2024, 42, 105–112

Zhen-Hang He, Guang-Feng Liu, Ze-Kun Zhou, et al. Understand the Temperature Sensing Behavior of Solid-state Polymerized PEDOT Hybrid Based on X-ray Scattering Studies[J]. Chinese Journal of Polymer Science, 2024,42(1):105-112.
He, Z. H.; Liu, G. F.; Zhou, Z. K.; Liu, Z.; Zeng, Y. S.; Zhang, P. Understand the temperature sensing behavior of solid-state polymerized PEDOT hybrid based on X-ray scattering studies. Chinese J. Polym. Sci. 2024, 42, 105–112 DOI： 10.1007/s10118-023-3005-4.

Zhen-Hang He, Guang-Feng Liu, Ze-Kun Zhou, et al. Understand the Temperature Sensing Behavior of Solid-state Polymerized PEDOT Hybrid Based on X-ray Scattering Studies[J]. Chinese Journal of Polymer Science, 2024,42(1):105-112. DOI： 10.1007/s10118-023-3005-4.

摘要

Authors developed a scalable (1 kg/h) protocol to produce a wearable temperature sensor material with defined composition, without structural transition from solution to solid states, using two-roll milling. X-ray scattering was employed to study its temperature sensing mechanism. The prepared material and device possess good detection capability for body temperature changes.

Abstract

Poly(3,4-ethylenedioxythiophene) (PEDOT) is one of the most successful conductive polymers that recently has been used in wearable sensors for human health monitoring. In this work, we prepared a series of PEDOT hybrids consisting of PEDOT, sodium poly(styrene sulfonate) (PSSNa) and polyethylene oxide (PEO), and their preparation could be scaled-up ,via, an adapted solid-state polymerization process. The resistance of the as-prepared PEDOT:PSS/PEO hybrid shows clear temperature response,i.e., it decreases almost linearly with the temperature increase. To understand this phenomenon, the ,in situ, synchrotron radiation wide- and small-angle X-ray scattering (WAXS/SAXS) characterizations were undertaken to study the temperature-dependent microstructure change of the PEDOT:PSS/PEO hybrid. It demonstrated that PEDOT formed conductive paths in the hybrids, which were not destroyed by the PEO crystallization. As temperature increased, the PEO crystals’ melting and the accompanying reorganization of PEDOT chains endowed the hybrid sample temperature responsiveness. Based on these fundamental knowledges, the hybrid materials were used to fabricate flexible wearable sensor that showing temperature sensing performance with an accuracy of 1 °C. These findings shed lights on the scalable manufacturing of wearable sensors for body temperature monitoring.

关键词

Keywords

Solid-state polymerizationPEDOT hybridStructure-property correlationX-ray scattering

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