Stabilize and Reinforce Hydrogen-Bonded Polymer Complex Elastic Fiber by Catechol Chemistry and Coordination

Ze-Xin Liu; De-Zhong Liu; Cai-Hong Zhang; Wei-Jie Wang; Hao Huang; Shu-Guang Yang

doi:10.1007/s10118-023-2992-5

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Stabilize and Reinforce Hydrogen-Bonded Polymer Complex Elastic Fiber by Catechol Chemistry and Coordination

RESEARCH ARTICLE | Updated：2023-11-27

- Stabilize and Reinforce Hydrogen-Bonded Polymer Complex Elastic Fiber by Catechol Chemistry and Coordination
- Stabilize and Reinforce Hydrogen-Bonded Polymer Complex Elastic Fiber by Catechol Chemistry and Coordination
- 高分子科学（英文版） 2023年41卷第12期页码：1846-1855
- Affiliations：
  
  State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-Dimension Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
- Author bio：
  
  shgyang@dhu.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51973029 and 52273020) and Ministry of Education (No. 8091B022141).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-2992-5.
- DOI：10.1007/s10118-023-2992-5
  中图分类号：
- 收稿：2023-03-01，
  
  修回：2023-4-14，
  
  录用：2023-4-17，
  
  网络首发：2023-06-12，
  
  纸质出版：2023-12-01
- Accepted：
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Liu, Z. X.; Liu, D. Z.; Zhang, C. H.; Wang, W. J.; Huang, H.; Yang, S. G. Stabilize and reinforce hydrogen-bonded polymer complex elastic fiber by catechol chemistry and coordination. Chinese J. Polym. Sci. 2023, 41, 1846–1855

Ze-Xin Liu, De-Zhong Liu, Cai-Hong Zhang, et al. Stabilize and Reinforce Hydrogen-Bonded Polymer Complex Elastic Fiber by Catechol Chemistry and Coordination[J]. Chinese Journal of Polymer Science, 2023, 41(12): 1846-1855.
Liu, Z. X.; Liu, D. Z.; Zhang, C. H.; Wang, W. J.; Huang, H.; Yang, S. G. Stabilize and reinforce hydrogen-bonded polymer complex elastic fiber by catechol chemistry and coordination. Chinese J. Polym. Sci. 2023, 41, 1846–1855 DOI： 10.1007/s10118-023-2992-5.

Ze-Xin Liu, De-Zhong Liu, Cai-Hong Zhang, et al. Stabilize and Reinforce Hydrogen-Bonded Polymer Complex Elastic Fiber by Catechol Chemistry and Coordination[J]. Chinese Journal of Polymer Science, 2023, 41(12): 1846-1855. DOI： 10.1007/s10118-023-2992-5.

摘要

PEO/PAA-Dopa/Metal fibers were constructed by the synergy interactions of hydrogen bonds

coordinate bonds and covalent bonds. Compared with hydrogen-bonded PEO/PAA fibers

PEO/PAA-Dopa/Metal fibers show high stiffness

strength and toughness

and quick recovery.

Abstract

Hydrogen-bonded polymer complex fiber of poly(ethylene oxide) (PEO) and poly(acrylic acid) (PAA) shows rubber elasticity in ambient environment

but the fiber has relatively low strength and weak stability. We apply the catechol chemistry and metal coordination to stabilize and strengthen the PEO/PAA fiber. PAA is grafted with dopamine (Dopa)

and then combines with PEO to prepare fiber. PAA-Dopa in the fiber is cross-linked through oxidation induced dismutation and the metal ions are introduced through coordination. The cross-linking and coordination greatly improve the stability of the fiber against the erosion of alkaline water. Among four different metal coordination fibers

PEO/PAA-Dopa/Cu fiber keeps the excellent extensibility (~1000%) and presents much higher initial modulus (~7 MPa)

ultimate strength (~20 MPa)

and toughness (~60 MJ/m

) than its precursor PEO/PAA fiber. In addition

PEO/PAA-Dopa/Cu fiber shows quick recovery and large energy dissipation ratio compared with the PEO/PAA fiber. The distinct mechanical properties enhancement of the hydrogen-bonded complex fiber is attributed to the synergy of hydrogen bonds

coordination and covalent bond cross-linking.

关键词

Keywords

references

Boretos,J.W.;Pierce,W.S.Segmentedpolyurethane:anewelastomerforbiomedicalapplications. Science 1967 , 158 ,1481−1482..

Chen,Y.;Miller,P.;Ding,X.;Stowell,C.;Kelly,K.;Wang,Y.Chelationcrosslinkingofbiodegradableelastomers. Adv. Mater. 2020 , 32 ,2003761..

Li,Z.Q.;Zhu,Y.L.;Niu,W.W.;Yang,X.;Jiang,Z.Y.;Lu,Z.Y.;Liu,X.K.;Sun,J.Q.Healableandrecyclableelastomerswithrecord-highmechanicalrobustness,unprecedentedcracktolerance,andsuperhighelasticrestorability. Adv. Mater. 2021 , 33 ,2101498..

Lei,W.W.;Zhou,X.X.;Russell,T.P.;Hua,K.C.;Yang,X.P.;Qiao,H.;Wang,W.C.;Li,F.Z.;Wang,R.G.;Zhang,L.Q.Highperformancebio-basedelastomers:energyefficientandsustainablematerialsfortires. J. Mater. Chem. A 2016 , 4 ,13058−13062..

LeFloch,P.;Yao,X.;Liu,Q.H.;Wang,Z.J.;Nian,G.D.;Sun,Y.;Jia,L.;Suo,Z.G.Wearableandwashableconductorsforactivetextiles. ACS Appl. Mater. Interfaces 2017 , 9 ,25542−25552..

Vatankhah-Varnosfaderani,M.;Keith,A.N.;Cong,Y.D.;Liang,H.Y.;Rosenthal,M.;Sztucki,M.;Clair,C.;Magonov,S.;Ivanov,D.A.;Dobrynin,A.V.;Sheiko,S.S.Chameleon-likeelastomerswithmolecularlyencodedstrain-adaptivestiffeningandcoloration. Science 2018 , 359 ,1509−1513..

Ohm,C.;Brehmer,M.;Zentel,R.Liquidcrystallineelastomersasactuatorsandsensors. Adv. Mater. 2010 , 22 ,3366−3387..

Sheiko,S.S.;Dobrynin,A.V.Architecturalcodeforrubberelasticity:fromsupersofttosuperfirmmaterials. Macromolecules 2019 , 52 ,7531−7546..

Cordier,P.;Tournilhac,F.;Soulie-Ziakovic,C.;Leibler,L.Self-healingandthermoreversiblerubberfromsupramolecularassembly. Nature 2008 , 451 ,977−980..

Ducrot,E.;Chen,Y.L.;Bulters,M.;Sijbesma,R.P.;Creton,C.Tougheningelastomerswithsacrificialbondsandwatchingthembreak. Science 2014 , 344 ,186−189..

Jiang,F.;Fang,C.;Zhang,J.;Wang,W.T.;Wang,Z.G.TriblockcopolymerelastomerswithenhancedmechanicalpropertiessynthesizedbyRAFTpolymerizationandsubsequentquaternizationthroughincorporationofacomonomerwithimidazolegroupsofabout2.0masspercentage. Macromolecules 2017 , 50 ,6218−6226..

Wang,W.J.;Zhang,C.H.;Huang,H.;Liu,Z.X.Jian,H.X.;Yang,S.G.Combiningmicrophaseseparationandhydrogen-bondingcomplexationtoconstructelastomer. Acta Polymerica Sinica (inChinese) 2023 , 54 ,478−486..

Yasui,T.;Zheng,Y.;Nakajima,T.;Kamio,E.;Matsuyama,H.;Gong,J.P.Rate-independentself-healingdoublenetworkhydrogelsusingathixotropicsacrificialnetwork. Macromolecules 2022 , 55 ,9547−9557..

Wu,J.R.;Cai,L.H.;Weitz,D.A.Toughself-healingelastomersbymolecularenforcedintegrationofcovalentandreversiblenetworks. Adv. Mater. 2017 , 29 ,1702616..

Guo,H.S.;Han,Y.;Zhao,W.Q.;Yang,J.;Zhang,L.Universallyautonomousself-healingelastomerwithhighstretchability. Nat. Commun. 2020 , 11 ,2037..

Wang,D;Xu,J.H.;Chen,J.Y.;Hu,P.;Wang,Y.;Jiang,W.;Fu,J.J.Transparent,mechanicallystrong,extremelytough,self-recoverable,healablesupramolecularelastomersfacilelyfabricated via dynamicharddomainsdesignformultifunctionalapplications. Adv. Funct. Mater. 2020 , 30 ,1907109..

Wu,X.Z.;Wang,J.Q.;Huang,J.X.;Yang,S.R.Robust,stretchable,andself-healablesupramolecularelastomerssynergisticallycross-linkedbyhydrogenbondsandcoordinationbonds. ACS Appl. Mater. Interfaces 2019 , 11 ,7387−7396..

Wang,Y.;Liu,X.;Li,S.;Li,T.;Song,Y.;Li,Z.;Zhang,W.;Sun,J.Q.Transparent,healableelastomerswithhighmechanicalstrengthandelasticityderivedfromhydrogen-bondedpolymercomplexes. ACS Appl. Mater. Interfaces 2017 , 9 ,29120−29129..

Wang,W.Y.;Lu,W.;Goodwin,A.;Wang,H.Q.;Yin,P.C.;Kang,N.G.;Hong,K.L.;Mays,J.W.Recentadvancesinthermoplasticelastomersfromlivingpolymerizations:macromoleculararchitecturesandsupramolecularchemistry. Prog. Polym. Sci. 2019 , 95 ,1−31..

Hu,J.L.;Lu,J.;Zhu,Y.Newdevelopmentsinelasticfibers. Polym. Rev. 2008 , 48 ,275−301..

Nurhamiyah,Y.;Amir,A.;Chen,B.Q.Whollybiobased,highlystretchable,hydrophobic,andself-healingthermoplasticelastomer. ACS Appl. Mater. Interfaces 2021 , 13 ,6720−6730..

Zhu,M.M.;Wang,W.J.;Zhang,C.H.;Zhu,L.P.;Yang,S.G.Photo-responsivebehaviorsofhydrogen-bondedpolymercomplexfiberscontainingazobenzenefunctionalgroups. Adv. Fiber Mater. 2021 , 3 ,172−179..

Yu,J.C.;Chen,K.;Ji,H.;Zhang,Y.;Zhang,Y.M.;Pan,Z.J.Facileandlarge-scalefabricationofself-crimpingelasticfibersforlargestrainsensors. Chinese J. Polym. Sci. 2021 , 39 ,914−924..

Chen,M.X.;Wang,Z.;Li,K.W.;Wang,X.D.;Wei,L.Elasticandstretchablefunctionalfibers:areviewofmaterials,fabricationmethods,andapplications. Adv. Fiber Mater. 2021 , 3 ,1−13..

Ziabichi,A.,in Fundamentals of Fiber Formation ,JohnWiley & Sons:London, 1976 ,Chapter5..

Casey,P.;Chen,H.Y.;Poon,B.;Bensason,S.;Menning,B.;Liu,L.Z.;Hu,Y.S.;Hoenig,W.;Gelfer,M.;Dems,B.;Rego,M.Polyolefinbasedcrosslinkedelasticfiber:atechnicalreviewofDOWXLA TM elasticfibertechnology. Polym. Rev. 2008 , 48 ,302−316..

Lee,S.;Shin,S.;Lee,S.;Seo,J.;Lee,J.;Son,S.;Cho,H.J.;Algadi,H.;Al-Sayari,S.;Kim,D.E.;Lee,T.Agnanowirereinforcedhighlystretchableconductivefibersforwearableelectronics. Adv. Funct. Mater. 2015 , 25 ,3114−3121..

Hicks,E.M.J.;Ultee,A.J.;Drougas,J.Spandexelasticfibers:Developmentofanewtypeofelasticfiberstimulatesfurtherworkinthegrowingfieldofstretchfabrics. Science 1965 , 147 ,373−379..

Ma,R.;Kang,B.;Cho,S.;Choi,M.;Baik,S.Extraordinarilyhighconductivityofstretchablefibersofpolyurethaneandsilvernanoflowers. ACS Nano 2015 , 9 ,10876−10886..

Li,J.F.;Wang,Z.L.;Wen,L.G.;Nie,J.;Yang,S.G.;Xu,J.Cheng,S.Z.D.Highlyelasticfibersmadefromhydrogen-bondedpolymercomplex. ACS Macro Lett. 2016 , 5 ,814−818..

Wang,W.J.;Xu,X.;Zhang,C.H.;Huang,H.;Zhu,L.P.;Yue,K.;Zhu,M.F.;Yang,S.G.Skeletalmusclefibersinspiredpolymericactuatorbyassemblyoftriblockpolymers. Adv. Sci. 2022 , 9 ,2105764..

Liu,D.Z.;Zhu,L.P.;Huang,W.T.;Yue,K.;Yang,S.G.Polymercomplexfiberforlinearactuationwithhighworkingdensityandstablecatch-state. ACS Macro Lett. 2020 , 9 ,1507−1513..

Niu,W.W.;Zhu,Y.L.;Wang,R.;Lu,Z.Y.;Liu,X.K.;Sun,J.Q.Remalleable,healable,andhighlysustainablesupramolecularpolymericmaterialscombiningsuperhighstrengthandultrahightoughness. ACS Appl. Mater. Interfaces 2020 , 12 ,30805−30814..

Bokobza,L.Thereinforcementofelastomericnetworksbyfillers. Macromol. Mater. Eng. 2004 , 289 ,607−621..

Heinrich,G.;Kluppel,M.;Vilgis,T.A.Reinforcementofelastomers. Curr. Opin. Solid State Mater. Sci. 2002 , 6 ,195−203..

Creton,C.50 th Anniversaryperspective:networksandgels:softbutdynamicandtough. Macromolecules 2017 , 50 ,8297-8316..

Gong,J.P.;Katsuyama,Y.;Kurokawa,T.;Osada,Y.Double-networkhydrogelswithextremelyhighmechanicalstrength. Adv. Mater. 2003 , 15 ,1155−1158..

Hu,J.;Hiwatashi,K.;Kurokawa,T.;Liang,S.M.;Wu,Z.L.;Gong,J.P.Microgel-reinforcedhydrogelfilmswithhighmechanicalstrengthandtheirvisiblemesoscalefracturestructure. Macromolecules 2011 , 44 ,7775−7781..

Li,H.J.;Zheng,H.;Tan,Y.J.;Tor,S.B.Zhou,K.Developmentofanultrastretchabledouble-networkhydrogelforflexiblestrainsensors. ACS Appl. Mater. Interfaces 2021 , 13 ,12814−12823..

Feng,J.F.;Chen,Z.H.;Fan,S.T.;Yu,L.P.;Tan,M.;Liao,L.G.;Li,B.J.;Zhang,S.Bioinspiredultratear-resistantelastomerwithaslidabledouble-networkstructure. ACS Appl. Mater. Interfaces 2022 , 14 ,31424−31434..

Zhang,N.;Pang,Y.;Li,Z.H.;Yang,C.H.;Zong,L.;Yang,H.S.;Wu,H.;Duan,Y.X.;Zhang,J.M.Rubber-likeandbiodegradablepoly(vinylalcohol)compositeswithtriplenetworksforhigh-efficiencysolventbarrier. Compos. Sci. Technol. 2023 , 231 ,109801..

Lu,H.F.;Wang,M.;Chen,X.M.;Lin,B.P.;Yang,H.Interpenetratingliquid-crystalpolyurethane/polyacrylateelastomerwithultrastrongmechanicalproperty. J. Am. Chem. Soc. 2019 , 141 ,14364−14369..

Kang,J.H.;Son,D.;Wang,G.J.N.;Liu,Y.X.;Lopez,J.;Kim,Y.;Oh,J.Y.;Katsumata,T.;Mun,J.W.;Lee,Y.Toughandwater-insensitiveself-healingelastomerforrobustelectronicskin. Adv. Mater. 2018 , 30 ,1706846..

Voorhaar,L.;Diaz,M.M.;Leroux,F.;Rogers,S.;Abakumov,A.M.;VanTendeloo,G.;VanAssche,G.;VanMele,B.;Hoogenboom,R.Supramolecularthermoplasticsandthermoplasticelastomermaterialswithself-healingabilitybasedonoligomericchargedtriblockcopolymers. NPG Asia Mater. 2017 , 9 ,e385..

Zhao,X.H.Multi-scalemulti-mechanismdesignoftoughhydrogels:buildingdissipationintostretchynetworks. Soft Matter 2014 , 10 ,672−687..

Yin,Q.Y.;Dai,C.H.;Chen,H.;Gou,K.;Guan,H.Z.;Wang,P.H.;Jiang,J.T.;Weng,G.S.Toughdoublemetal-ioncross-linkedelastomerswithtemperature-adaptableself-healingandluminescenceproperties. Chinese J. Polym. Sci. 2021 , 39 ,554−565..

Krogsgaard,M.;Nue,V.;Birkedal,H.Mussel-inspiredmaterials:Self-healingthroughcoordinationchemistry. Chem. Eur. J. 2016 , 22 ,844−857..

Bentley,W.E.;Payne,G.F.Nature'sotherself-assemblers. Science 2013 , 341 ,136−137..

Azevedo,S.;Costa,A.M.S.;Andersen,A.;Choi,I.S.;Birkedal,H.;Mono,J.F.Bioinspiredultratoughhydrogelwithfastrecovery,self-healing,injectabilityandcytocompatibility. Adv. Mater. 2017 , 29 ,1700759..

Filippidi,E.;Cristiani,T.R.;Eisenbach,C.D.;Waite,J.H.;Israelachvili,J.N.;Ahn,B.K.;Valentine,M.T.Tougheningelastomersusingmussel-inspirediron-catecholcomplexes. Science 2017 , 358 ,502−505..

Liao,J.X.;Huang,J.H.;Wang,T.;Sun,W.X.;Tong,Z.RapidshapememoryandpH-modulatedspontaneousactuationofdopaminecontaininghydrogels. Chinese J. Polym. Sci. 2017 , 35 ,1297−1306..

Wu,J.J.;Zhang,L.;Wang,Y.X.;Long,Y.H.;Gao,H.;Zhang,X.L.;Zhao,N.;Cai,Y.L.;Xu,J.Mussel-inspiredchemistryforrobustandsurface-modifiablemultilayerfilms. Langmuir 2011 , 27 ,13684−13691..

Nie,J.;Wang,Z.L.;Li,J.F.;Gong,Y.;Sun,J.X.;Yang,S.G.Interfacehydrogen-bondedcore-shellnanofibersbycoaxialelectrospinning. Chinese J. Polym. Sci. 2017 , 35 ,1001−1008..

Lutkenhaus,J.L.;Hrabak,K.D.;McEnnis,K.;Hammond,P.T.Elastomericflexiblefree-standinghydrogen-bondednanoscaleassemblies. J. Am. Chem. Soc. 2005 , 127 ,17228−17234..

Cheng,S.;Chen,J.H.;Barley,J.S.;Zhang,A.Q.;Habenschuss,A.;Zschack,P.R.Isothermalthickeningandthinningprocessesinlowmolecular-weightpoly(ethyleneoxide)fractionscrystallizedfromthemelt.3.Molecularweightdependence. Macromolecules 1992 , 25 ,1453−1460..

Cheng,S.;Zhang,A.Q.;Barley,J.S.;Chen,J.H.;Habenschuss,A.;Zschack,P.R.Isothermalthickeningandthinningprocessesinlow-molecular-weightpoly(ethyleneoxide)fractions.1.Fromnonintegral-foldingtointegral-foldingchaincrystaltransitions. Macromolecules 1991 , 24 ,3937−3944..

Li,J.F.;Sun,J.X.;Wu,D.;Huang,W.T.;Zhu,M.F.;Reichmanis,E.;Yang,S.G.Functionalization-directedstabilizationofhydrogen-bondedpolymercomplexfibers:elasticityandconductivity. Adv. Fiber Mater. 2019 , 1 ,71−81..

Sun,J.X.;Su,C.;Zhang,X.J.;Yin,W.J.;Xu,J.;Yang,S.G.Reversibleswelling-shrinkingbehaviorofhydrogen-bondedfree-standingthinfilmstabilizedbycatecholreaction. Langmuir 2015 , 31 ,5147−5154..

Shi,L.Y.;Ding,P.H.;Wang,Y.Z.;Zhang,Y.;Ossipov,D.;Hilborn,J.Self-healingpolymerichydrogelformedbymetal-ligandcoordinationassembly:design,fabrication,andbiomedicalapplications. Macromol. Rapid Commun. 2019 , 40 ,1800837..

Sever,M.J.;Weisser,J.T.;Monahan,J.;Srinivasan,S.;Wilker,J.J.Metal-mediatedcross-linkinginthegenerationofamarine-musseladhesive. Angew. Chem. 2004 , 116 ,454−456..

Auvil,N.C.;DeVasquez,M.G.V.;Allen,H.C.Zinc-carboxylatebindinginmixedoctadecanoicacidandoctadecanolmonolayersonproxyseawatersolutionsurfaces. ACS Earth Space Chem. 2021 , 5 ,2947−2956..

El-Sawy,N.M.;AlSagheer,F.Radiation-inducedgraftpolymerizationofacrylicacidontopoly(tetrafluoroethylene-perfluorovinylether)copolymerfilms:complexationwithsometransitionmetalsandbiologicalactivity. Eur. Polym. J. 2001 , 37 ,161−166..

Yuan,T.;Qu,X.X.;Cui,X.M.;Sun,J.Q.Self-healingandrecyclablehydrogelsreinforcedwithinsitu-formedorganicnanofibrilsexhibitsimultaneouslyenhancedmechanicalstrengthandstretchability. ACS Appl. Mater. Interfaces 2019 , 11 ,32346−32353..

Peng,Y.;Yang,Y.;Wu,Q.;Wang,S.X.;Huang,G.S.;Wu,J.R.Strongandtoughself-healingelastomersenabledbydualreversiblenetworksformedbyionicinteractionsanddynamiccovalentbonds. Polymer 2018 , 157 ,172−179..

Fang,X.;Sun,J.Q.One-stepsynthesisofhealableweak-polyelectrolyte-basedhydrogelswithhighmechanicalstrength,toughness,andexcellentself-recovery. ACS Macro Lett. 2019 , 8 ,500−505..

Wang,W.J.;Wang,W.P.;Wang,F.;Xie,X.F.;Yi,G.;Li,Z.B.Toughandbody-temperatureself-healingpolysiloxaneelastomersthroughbuildingadoublephysicalcrosslinkingnetwork via competingnon-covalentinteractions. J. Mater. Chem. A 2022 , 10 ,23375−23383..

Du,R.C.;Xu,Z.C.;Zhu,C.;Jiang,Y.W.;Yan,H.P.;Wu,H.C.;Vardoulis,O.;Cai,Y.F.;Zhu,X.Y.;Bao,Z.N.;Zhang,Q.H.;Jia,X.D.Ahighlystretchableandself-healingsupramolecularelastomerbasedonslidingcrosslinksandhydrogenbonds. Adv. Funct. Mater. 2020 , 30 ,1907139..

Lai,J.;Jia,X.Y.;Wang,D.P.;Deng,Y.B.;Zheng,P.;Li,C.H.;Zuo,J.L.;Bao,Z.N.Thermodynamicallystablewhilstkineticallylabilecoordinationbondsleadtostrongandtoughself-healingpolymers. Nat. Commun. 2019 , 10 ,1164..

Yuan,T.;Cui,X.M.;Liu,X.K.;Qu,X.X.;Sun,J.Q.Highlytough,stretchable,self-healing,andrecyclablehydrogelsreinforcedby in situ -formedpolyelectrolytecomplexnanoparticles. Macromolecules 2019 , 52 ,3141−3149..

Fang,X.;Li,Y.X.;Li,X.;Liu,W.M.;Yu,X.H.;Yan,F.;Sun,J.Q.Dynamichydrophobicdomainsenablethefabricationofmechanicallyrobustandhighlyelasticpoly(vinylalcohol)-basedhydrogelswithexcellentself-healingability. ACS Mater. Lett. 2020 , 2 ,764−770..

Wu,D.L.;Liu,L.;Ma,Q.H.;Dong,Q.;Han,Y.Q.;Liu,L.;Zhao,S.F.;Zhang,R.L.;Wang,M.J.Biomimeticsupramolecularpolyurethanewithslidingpolyrotaxaneanddisulfidebondsforstrainsensorswithwidesensingrangeandself-healingcapability. J. Colloid Interface Sci. 2023 , 630 ,909−920..

Wang,L.P.;Zhang,M.G.;Hao,J.C.;Wang,X.Insertionofsupramolecularsegmentsintocovalentlycrosslinkedpolyurethanenetworkstowardsthefabricationofrecyclableelastomers. Chinese J. Polym. Sci. 2022 , 40 ,321−330..

Kim,S.M.;Jeon,H.;Shin,S.H.;Park,S.A.;Jegal,J.;Hwang,S.Y.;Oh,D.X.;Park,J.Superiortoughnessandfastself-healingatroomtemperatureengineeredbytransparentelastomers. Adv. Mater. 2018 , 30 ,1705145..

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