Spherical Packing Superlattices in Self-Assembly of Homogenous Soft Matter: Progresses and Potentials

Yuchu Liu; Huanyu Lei; Qing-Yun Guo; Xianyou Liu; Xinghan Li; Yuean Wu; Weiyi Li; Wei Zhang; GengXin Liu; Xiao-Yun Yan; Stephen Z. D. Cheng

doi:10.1007/s10118-023-2976-5

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Spherical Packing Superlattices in Self-Assembly of Homogenous Soft Matter: Progresses and Potentials

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- Spherical Packing Superlattices in Self-Assembly of Homogenous Soft Matter: Progresses and Potentials
- Spherical Packing Superlattices in Self-Assembly of Homogenous Soft Matter: Progresses and Potentials
- 高分子科学（英文版） 2023年41卷第5期页码：607-620
- Affiliations：
  
  a.South China Advanced Institute for Soft Matter Science and Technology, School of Molecular Science and Engineering, South China University of Technology, Guangzhou 510640, China
  b.School of Polymer Science and Polymer Engineering, The University of Akron, Akron OH 44325-3909, USA
  c.State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-dimension Materials, College of Material Science and Engineering, Donghua University, Shanghai 201620, China
- Author bio：
  
  xy23@uakron.edu(X.Y.Y.)
  scheng@uakron.edu(S.Z.D.C.)
- Funds：
  
  This work was financially supported by the Guangdong Provincial Key Laboratory of Functional and Intelligent Hybrid Materials and Devices (No. 2019B121203003), the Recruitment Program of Guangdong (No. 2016ZT06C322) and Major Program of National Natural Science Foundation of China (No. 51890871).;Xiao-Yun Yanreceived his B.S. degree (2014) from Xiamen University, China. He obtained his Ph.D. degree in polymer science from the University of Akron in December 2020 under the supervision of Prof. Stephen Z. D. Cheng. His research focused on the geometric effects of shape-persistent molecules in condensed states. In the spring of 2022, he joined Prof. Xuanhe Zhao’s group as a postdoctoral scholar at Massachusetts Institute of Technology.Stephen Z. D. Cheng’s research interests are in the area of macromolecular and supramolecular chemistry, physics and engineering. He held the Trustees, Robert C. Musson, and Frank C. Sullivan Distinguished Research Professors before his retirement from University of Akron. More than 100 Ph.D. students has been graduated from his group. He is a recipient of The Presidential Young Investigator Award (1991), American Physical Society John H. Dillon Medal (1995), Polymer Physics Prize (2013), Japan Society of Polymer Science International Award (2017) and others. He is a Fellow of the American Physical Society, American Association for the Advancement of Science, and an Honorary Fellow of Chinese Chemical Society. In 2008, he has been a member of the National Academic of Engineering of the USA (2008).
- DOI：10.1007/s10118-023-2976-5
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Spherical Packing Superlattices in Self-Assembly of Homogenous Soft Matter: Progresses and Potentials[J]. 高分子科学（英文版）, 2023,41(5):607-620.

Yuchu Liu, Huanyu Lei, Qing-Yun Guo, et al. Spherical Packing Superlattices in Self-Assembly of Homogenous Soft Matter: Progresses and Potentials[J]. Chinese Journal of Polymer Science, 2023,41(5):607-620.
Spherical Packing Superlattices in Self-Assembly of Homogenous Soft Matter: Progresses and Potentials[J]. 高分子科学（英文版）, 2023,41(5):607-620. DOI： 10.1007/s10118-023-2976-5.

Yuchu Liu, Huanyu Lei, Qing-Yun Guo, et al. Spherical Packing Superlattices in Self-Assembly of Homogenous Soft Matter: Progresses and Potentials[J]. Chinese Journal of Polymer Science, 2023,41(5):607-620. DOI： 10.1007/s10118-023-2976-5.

摘要

Bottom-up construction of complex superlattices using self-assembly of soft matter is a promising approach for large-scale production of intricate nano-patterns. Homogenous soft matter, i.e., block copolymers, dendrimers, and giant molecules, can be used to fabricate complex 3D superlattices with extraordinary photonic and phonon properties. The article provides a perspective on the development of complex spherical packing superlattice by homogenous self-assembly, reviewing the unique hierarchical self-assembling processes, the general features of different superlattices, and discussing challenges and potentials in this field.

Abstract

The construction of complex superlattices using homogenous soft matter has great potential for the bottom-up fabrication of complex, nanoscale structures. This topic is not only interested in scientific exploring for new concepts of supramolecular crystals with nanometer in sizes, which is about thousand times larger in volumes than those of normal crystals, but also practically important to provide construction principles of metamaterials which are artificially structured materials for controlling and manipulating light, sound, and other physical behaviors. These systems have fast assembly kinetics and convenient processing procedures, making them ideal for large-scale superlattice production. In this perspective, we focus on recent developments in the construction of complex spherical packing superlattices using homogenous soft self-assemblies. We discuss the general mechanism of those formations of supramolecular motifs and provide an overview of the spherical packing superlattices self-assembled by homogenous soft matters based on different volume asymmetry. Additionally, we outline the potentials of utilizing this approach in constructing novel superlattices as well as its future challenges.

关键词

Keywords

Soft matterSelf-assemblySpherical packing phasesSuperlatticeBottom-up construction

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