Spherical Packing Superlattices in Self-Assembly of Homogenous Soft Matter: Progresses and Potentials

Yuchu Liu; Huanyu Lei; Qing-Yun Guo; Xianyou Liu; Xinghan Li; Yuean Wu; Weiyi Li; Wei Zhang; GengXin Liu; Xiao-Yun Yan; Stephen Z. D. Cheng

doi:10.1007/s10118-023-2976-5

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Spherical Packing Superlattices in Self-Assembly of Homogenous Soft Matter: Progresses and Potentials

PERSPECTIVE | Updated：2023-04-21

- Spherical Packing Superlattices in Self-Assembly of Homogenous Soft Matter: Progresses and Potentials
- Spherical Packing Superlattices in Self-Assembly of Homogenous Soft Matter: Progresses and Potentials
- 高分子科学（英文版） 2023年41卷第5期页码：607-620
- Affiliations：
  
  a.South China Advanced Institute for Soft Matter Science and Technology, School of Molecular Science and Engineering, South China University of Technology, Guangzhou 510640, China
  b.School of Polymer Science and Polymer Engineering, The University of Akron, Akron OH 44325-3909, USA
  c.State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-dimension Materials, College of Material Science and Engineering, Donghua University, Shanghai 201620, China
- Author bio：
  
  xy23@uakron.edu(X.Y.Y.)
  scheng@uakron.edu(S.Z.D.C.)
- Funds：
  
  This work was financially supported by the Guangdong Provincial Key Laboratory of Functional and Intelligent Hybrid Materials and Devices (No. 2019B121203003), the Recruitment Program of Guangdong (No. 2016ZT06C322) and Major Program of National Natural Science Foundation of China (No. 51890871).;Xiao-Yun Yanreceived his B.S. degree (2014) from Xiamen University, China. He obtained his Ph.D. degree in polymer science from the University of Akron in December 2020 under the supervision of Prof. Stephen Z. D. Cheng. His research focused on the geometric effects of shape-persistent molecules in condensed states. In the spring of 2022, he joined Prof. Xuanhe Zhao’s group as a postdoctoral scholar at Massachusetts Institute of Technology.Stephen Z. D. Cheng’s research interests are in the area of macromolecular and supramolecular chemistry, physics and engineering. He held the Trustees, Robert C. Musson, and Frank C. Sullivan Distinguished Research Professors before his retirement from University of Akron. More than 100 Ph.D. students has been graduated from his group. He is a recipient of The Presidential Young Investigator Award (1991), American Physical Society John H. Dillon Medal (1995), Polymer Physics Prize (2013), Japan Society of Polymer Science International Award (2017) and others. He is a Fellow of the American Physical Society, American Association for the Advancement of Science, and an Honorary Fellow of Chinese Chemical Society. In 2008, he has been a member of the National Academic of Engineering of the USA (2008).
- DOI：10.1007/s10118-023-2976-5
  中图分类号：
- 收稿：2023-01-10，
  
  修回：2023-2-24，
  
  录用：2023-3-6，
  
  网络首发：2023-03-22，
  
  纸质出版：2023-05-01
- Accepted：
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Liu, Y.; Lei, H.; Guo, Q. Y.; Liu, X.; Li, X.; Wu, Y.; Li, W.; Zhang, W.; Liu, G. X.; Yan, X. Y.; Cheng, S. Z. D. Spherical packing superlattices in self-assembly of homogenous soft matter: progresses and potentials.Chinese J. Polym. Sci.2023,41, 607–620

Yuchu Liu, Huanyu Lei, Qing-Yun Guo, et al. Spherical Packing Superlattices in Self-Assembly of Homogenous Soft Matter: Progresses and Potentials[J]. Chinese Journal of Polymer Science, 2023, 41(5): 607-620.
Liu, Y.; Lei, H.; Guo, Q. Y.; Liu, X.; Li, X.; Wu, Y.; Li, W.; Zhang, W.; Liu, G. X.; Yan, X. Y.; Cheng, S. Z. D. Spherical packing superlattices in self-assembly of homogenous soft matter: progresses and potentials.Chinese J. Polym. Sci.2023,41, 607–620 DOI： 10.1007/s10118-023-2976-5.

Yuchu Liu, Huanyu Lei, Qing-Yun Guo, et al. Spherical Packing Superlattices in Self-Assembly of Homogenous Soft Matter: Progresses and Potentials[J]. Chinese Journal of Polymer Science, 2023, 41(5): 607-620. DOI： 10.1007/s10118-023-2976-5.

摘要

Bottom-up construction of complex superlattices using self-assembly of soft matter is a promising approach for large-scale production of intricate nano-patterns. Homogenous soft matter

i.e.

block copolymers

dendrimers

and giant molecules

can be used to fabricate complex 3D superlattices with extraordinary photonic and phonon properties. The article provides a perspective on the development of complex spherical packing superlattice by homogenous self-assembly

reviewing the unique hierarchical self-assembling processes

the general features of different superlattices

and discussing challenges and potentials in this field.

Abstract

The construction of complex superlattices using homogenous soft matter has great potential for the bottom-up fabrication of complex

nanoscale structures. This topic is not only interested in scientific exploring for new concepts of supramolecular crystals with nanometer in sizes

which is about thousand times larger in volumes than those of normal crystals

but also practically important to provide construction principles of metamaterials which are artificially structured materials for controlling and manipulating light

sound

and other physical behaviors. These systems have fast assembly kinetics and convenient processing procedures

making them ideal for large-scale superlattice production. In this perspective

we focus on recent developments in the construction of complex spherical packing superlattices using homogenous soft self-assemblies. We discuss the general mechanism of those formations of supramolecular motifs and provide an overview of the spherical packing superlattices self-assembled by homogenous soft matters based on different volume asymmetry. Additionally

we outline the potentials of utilizing this approach in constructing novel superlattices as well as its future challenges.

关键词

Keywords

references

Shalaev, V. M . Optical negative-index metamaterials . Nat. Photon. , 2007 , 1 41 - 48 . DOI: 10.1038/nphoton.2006.49 http://doi.org/10.1038/nphoton.2006.49 .

Poddubny, A.; Iorsh, I.; Belov, P.; Kivshar, Y . Hyperbolic metamaterials . Nat. Photon. , 2013 , 7 948 - 957 . DOI: 10.1038/nphoton.2013.243 http://doi.org/10.1038/nphoton.2013.243 .

Chen, H.; Chan, C. T.; Sheng, P . Transformation optics and metamaterials . Nat. Mater. , 2010 , 9 387 - 396 . DOI: 10.1038/nmat2743 http://doi.org/10.1038/nmat2743 .

Gabinet, U. R.; Osuji, C. O . Optical materials and metamaterials from nanostructured soft matter . Nano Res. , 2019 , 12 2172 - 2183 . DOI: 10.1007/s12274-019-2437-1 http://doi.org/10.1007/s12274-019-2437-1 .

von Freymann, G.; Kitaev, V.; Lotsch, B. V.; Ozin, G. A . Bottom-up assembly of photonic crystals . Chem. Soc. Rev. , 2013 , 42 2528 - 2554 . DOI: 10.1039/C2CS35309A http://doi.org/10.1039/C2CS35309A .

Lu, W.; Lieber, C. M . Nanoelectronics from the bottom up . Nat. Mater. , 2007 , 6 841 - 850 . DOI: 10.1038/nmat2028 http://doi.org/10.1038/nmat2028 .

Zhou, X.; Yu, G . Preparation engineering of two-dimensional heterostructures via bottom-up growth for device applications . ACS Nano , 2021 , 15 11040 - 11065 . DOI: 10.1021/acsnano.1c02985 http://doi.org/10.1021/acsnano.1c02985 .

Cheng, J. Y.; Ross, C. A.; Smith, H. I.; Thomas, E. L . Templated self-assembly of block copolymers: top-down helps bottom-up . Adv. Mater. , 2006 , 18 2505 - 2521 . DOI: 10.1002/adma.200502651 http://doi.org/10.1002/adma.200502651 .

Ren, J.; Segal-Peretz, T.; Zhou, C.; Craig, G. S. W.; Nealey, P. F. Three-dimensional superlattice engineering with block copolymer epitaxy, Sci. Adv. 2020 , 6 , DOI:10.1126/sciadv.aaz0002.

Xiong, S.; Wan, L.; Ishida, Y.; Chapuis, Y. A.; Craig, G. S. W.; Ruiz, R.; Nealey, P. F . Directed self-assembly of triblock copolymer on chemical patterns for sub-10-nm nanofabrication via solvent annealing . ACS Nano , 2016 , 10 7855 - 7865 . DOI: 10.1021/acsnano.6b03667 http://doi.org/10.1021/acsnano.6b03667 .

Hu, H.; Gopinadhan, M.; Osuji, C. O . Directed self-assembly of block copolymers: a tutorial review of strategies for enabling nanotechnology with soft matter . Soft Matter , 2014 , 10 3867 DOI: 10.1039/c3sm52607k http://doi.org/10.1039/c3sm52607k .

Zhang, W. B.; Yu, X. F.; Wang, C. L.; Sun, H. J.; Hsieh, I. F.; Li, Y.; Dong, X. H.; Yue, K.; Van Horn, R.; Cheng, S. Z. D . Molecular nanoparticles are unique elements for macromolecular science: from “nanoatoms” to giant molecules . Macromolecules , 2014 , 47 1221 - 1239 . DOI: 10.1021/ma401724p http://doi.org/10.1021/ma401724p .

Leibler, L . Theory of microphase separation in block copolymers . Macromolecules , 1980 , 13 1602 - 1617 . DOI: 10.1021/ma60078a047 http://doi.org/10.1021/ma60078a047 .

Sun, H. J.; Zhang, S.; Percec, V. . From structure to function via complex supramolecular dendrimer systems . Chem. Soc. Rev. , 2015 , 44 3900 - 3923 . DOI: 10.1039/c4cs00249k http://doi.org/10.1039/c4cs00249k .

Zhang, W. B.; Cheng, S. Z. D . Giant is different: size effects and the nature of macromolecules . Giant , 2020 , 1 100011 DOI: 10.1016/j.giant.2020.100011 http://doi.org/10.1016/j.giant.2020.100011 .

Wen, T.; Ni, B.; Liu, Y.; Zhang, W.; Guo, Z. H.; Lee, Y. C.; Ho, R. M.; Cheng, S. Z. D . Towards achieving a large-area and defect-free nano-line pattern via controlled self-assembly by sequential annealing . Giant , 2021 , 8 100078 DOI: 10.1016/j.giant.2021.100078 http://doi.org/10.1016/j.giant.2021.100078 .

Liu, Y.; Liu, T.; Yan, X. Y.; Guo, Q. Y.; Wang, J.; Zhang, R.; Zhang, S.; Su, Z.; Huang, J.; Liu, G. X.; Zhang, W.; Zhang, W.; Aida, T.; Yue, K.; Huang, M.; Cheng, S. Z. D.; Shi, A. C . Mesoatom alloys via self-sorting approach of giant molecules blends . Giant , 2020 , 4 100031 DOI: 10.1016/j.giant.2020.100031 http://doi.org/10.1016/j.giant.2020.100031 .

Xie, J.; Shi, A. C . Formation of complex spherical packing phases in diblock copolymer/homopolymer blends . Giant , 2021 , 5 100043 DOI: 10.1016/j.giant.2020.100043 http://doi.org/10.1016/j.giant.2020.100043 .

Wang, Y.; Huang, J.; Yan, X.; Lei, H.; Liu, X.; Guo, Q.; Liu, Y.; Liu, T.; Huang, M.; Bian, F.; Su, Z.; Cheng, S. Z. D . Soft alloys constructed with distinct mesoatoms via self-sorting assembly of giant shape amphiphiles . Angew. Chem. Int. Ed. , 2022 , 61 e202200637 DOI: 10.1002/anie.202200637 http://doi.org/10.1002/anie.202200637 .

Liu, Y.; Liu, T.; Yan, X. Y.; Guo, Q. Y.; Lei, H.; Huang, Z.; Zhang, R.; Wang, Y.; Wang, J.; Liu, F.; Bian, F. G.; Meijer, E. W.; Aida, T.; Huang, M.; Cheng, S. Z. D . Expanding quasiperiodicity in soft matter: supramolecular decagonal quasicrystals by binary giant molecule blends . Proc. Natl. Acad. Sci. U. S. A. , 2022 , 119 21613 - 21621 . DOI: 10.1073/pnas.2115304119 http://doi.org/10.1073/pnas.2115304119 .

Yan, X. Y.; Guo, Q. Y.; Liu, X. Y.; Wang, Y.; Wang, J.; Su, Z.; Huang, J.; Bian, F.; Lin, H.; Huang, M.; Lin, Z.; Liu, T.; Liu, Y.; Cheng, S. Z. D . Superlattice engineering with chemically precise molecular building blocks . J. Am. Chem. Soc. , 2021 , 143 21613 - 21621 . DOI: 10.1021/jacs.1c09831 http://doi.org/10.1021/jacs.1c09831 .

Lei, H.; Liu, Y.; Liu, T.; Guo, Q.; Yan, X.; Wang, Y.; Zhang, W.; Su, Z.; Huang, J.; Xu, W.; Bian, F.; Huang, M.; Cheng, S. Z. D . Unimolecular nanoparticles toward more precise regulations of self-assembled superlattices in soft matter . Angew. Chem. Int. Ed. , 2022 , 61 e202203433 DOI: 10.1002/anie.202203433 http://doi.org/10.1002/anie.202203433 .

Kim, K.; Schulze, M. W.; Arora, A.; Lewis, R. M.; Hillmyer, M. A.; Dorfman, K. D.; Bates, F. S . Thermal processing of diblock copolymer melts mimics metallurgy . Science , 2017 , 356 520 - 523 . DOI: 10.1126/science.aam7212 http://doi.org/10.1126/science.aam7212 .

Chanpuriya, S.; Kim, K.; Zhang, J.; Lee, S.; Arora, A.; Dorfman, K. D.; Delaney, K. T.; Fredrickson, G. H.; Bates, F. S . Cornucopia of nanoscale ordered phases in sphere-forming tetrablock terpolymers . ACS Nano , 2016 , 10 4961 - 4972 . DOI: 10.1021/acsnano.6b00495 http://doi.org/10.1021/acsnano.6b00495 .

Balagurusamy, V. S. K.; Ungar, G.; Percec, V.; Johansson, G . Rational design of the first spherical supramolecular dendrimers self-organized in a novel thermotropic cubic liquid-crystalline phase and the determination of their shape by X-ray analysis . J. Am. Chem. Soc. , 1997 , 119 1539 - 1555 . DOI: 10.1021/ja963295i http://doi.org/10.1021/ja963295i .

Huang, M.; Hsu, C. H.; Wang, J.; Mei, S.; Dong, X.; Li, Y.; Li, M.; Liu, H.; Zhang, W. B.; Aida, T.; Zhang, W. B.; Yue, K.; Cheng, S. Z. D . Selective assemblies of giant tetrahedra via precisely controlled positional interactions . Science , 2015 , 348 424 - 428 . DOI: 10.1126/science.aaa2421 http://doi.org/10.1126/science.aaa2421 .

Su, Z.; Hsu, C. H.; Gong, Z.; Feng, X.; Huang, J.; Zhang, R.; Wang, Y.; Mao, J.; Wesdemiotis, C.; Li, T.; Seifert, S.; Zhang, W.; Aida, T.; Huang, M.; Cheng, S. Z. D . Identification of a Frank-Kasper Z phase from shape amphiphile self-assembly . Nat. Chem. , 2019 , 11 899 - 905 . DOI: 10.1038/s41557-019-0330-x http://doi.org/10.1038/s41557-019-0330-x .

Zhao, M.; Li, W . Laves phases formed in the binary blend of AB 4 miktoarm star copolymer and a-homopolymer . Macromolecules , 2019 , 52 1832 - 1842 . DOI: 10.1021/acs.macromol.8b02407 http://doi.org/10.1021/acs.macromol.8b02407 .

Lakes, R . Materials with structural hierarchy . Nature , 1993 , 361 511 - 515 . DOI: 10.1038/361511a0 http://doi.org/10.1038/361511a0 .

Boles, M. A.; Engel, M.; Talapin, D. V . Self-assembly of colloidal nanocrystals: from intricate structures to functional materials . Chem. Rev. , 2016 , 116 11220 - 11289 . DOI: 10.1021/acs.chemrev.6b00196 http://doi.org/10.1021/acs.chemrev.6b00196 .

Shevchenko, E. V.; Talapin, D. V.; Kotov, N. A.; O’Brien, S.; Murray, C. B . Structural diversity in binary nanoparticle superlattices . Nature , 2006 , 439 55 - 59 . DOI: 10.1038/nature04414 http://doi.org/10.1038/nature04414 .

Deng, K.; Luo, Z.; Tan, L.; Quan, Z . Self-assembly of anisotropic nanoparticles into functional superstructures . Chem. Soc. Rev. , 2020 , 49 6002 - 6038 . DOI: 10.1039/D0CS00541J http://doi.org/10.1039/D0CS00541J .

Coropceanu, I.; Boles, M. A.; Talapin, D. V . Systematic mapping of binary nanocrystal superlattices: the role of topology in phase selection . J. Am. Chem. Soc. , 2019 , 141 5728 - 5740 . DOI: 10.1021/jacs.8b12539 http://doi.org/10.1021/jacs.8b12539 .

Zhang, J.; Santos, P. J.; Gabrys, P. A.; Lee, S.; Liu, C.; Macfarlane, R. J . Self-assembling nanocomposite tectons . J. Am. Chem. Soc. , 2016 , 138 16228 - 16231 . DOI: 10.1021/jacs.6b11052 http://doi.org/10.1021/jacs.6b11052 .

Auyeung, E.; Cutler, J. I.; Macfarlane, R. J.; Jones, M. R.; Wu, J.; Liu, G.; Zhang, K.; Osberg, K. D.; Mirkin, C. A . Synthetically programmable nanoparticle superlattices using a hollow three-dimensional spacer approach . Nat. Nanotechnol. , 2012 , 7 24 - 28 . DOI: 10.1038/nnano.2011.222 http://doi.org/10.1038/nnano.2011.222 .

Santos, P. J.; Gabrys, P. A.; Zornberg, L. Z.; Lee, M. S.; Macfarlane, R. J . Macroscopic materials assembled from nanoparticle superlattices . Nature , 2021 , 591 586 - 591 . DOI: 10.1038/s41586-021-03355-z http://doi.org/10.1038/s41586-021-03355-z .

Yoon, Y. J.; Kang, S. H.; Kim, T. H . Temperature-selective self-assembled superlattices of gold nanoparticles driven by block copolymer template guidance . J. Phys. Chem. Lett. , 2021 , 12 11960 - 11967 . DOI: 10.1021/acs.jpclett.1c03268 http://doi.org/10.1021/acs.jpclett.1c03268 .

Nykypanchuk, D.; Maye, M. M.; van der Lelie, D.; Gang, O . DNA-guided crystallization of colloidal nanoparticles . Nature , 2008 , 451 549 - 552 . DOI: 10.1038/nature06560 http://doi.org/10.1038/nature06560 .

Park, S. Y.; Lytton-Jean, A. K. R.; Lee, B.; Weigand, S.; Schatz, G. C.; Mirkin, C. A . DNA-programmable nanoparticle crystallization . Nature , 2008 , 451 553 - 556 . DOI: 10.1038/nature06508 http://doi.org/10.1038/nature06508 .

Lee, S.; Calcaterra, H. A.; Lee, S.; Hadibrata, W.; Lee, B.; Oh, E.; Aydin, K.; Glotzer, S. C.; Mirkin, C. A . Shape memory in self-adapting colloidal crystals . Nature , 2022 , 610 674 - 679 . DOI: 10.1038/s41586-022-05232-9 http://doi.org/10.1038/s41586-022-05232-9 .

Li, Y.; Zhou, W.; Tanriover, I.; Hadibrata, W.; Partridge, B. E.; Lin, H.; Hu, X.; Lee, B.; Liu, J.; Dravid, V. P.; Aydin, K.; Mirkin, C. A . Open-channel metal particle superlattices . Nature , 2022 , 611 695 - 701 . DOI: 10.1038/s41586-022-05291-y http://doi.org/10.1038/s41586-022-05291-y .

Zhang, C.; MacFarlane, R. J.; Young, K. L.; Choi, C. H. J.; Hao, L.; Auyeung, E.; Liu, G.; Zhou, X.; Mirkin, C. A . A general approach to DNA-programmable atom equivalents . Nat. Mater. , 2013 , 12 741 - 746 . DOI: 10.1038/nmat3647 http://doi.org/10.1038/nmat3647 .

Macfarlane, R. J.; Lee, B.; Jones, M. R.; Harris, N.; Schatz, G. C.; Mirkin, C. A . Nanoparticle superlattice engineering with DNA . Science , 2011 , 334 204 - 208 . DOI: 10.1126/science.1210493 http://doi.org/10.1126/science.1210493 .

Bailey, E. J.; Winey, K. I . Dynamics of polymer segments, polymer chains, and nanoparticles in polymer nanocomposite melts: a review . Prog. Polym. Sci. , 2020 , 105 101242 DOI: 10.1016/j.progpolymsci.2020.101242 http://doi.org/10.1016/j.progpolymsci.2020.101242 .

Liu, Y.; Liu, G.; Zhang, W.; Du, C.; Wesdemiotis, C.; Cheng, S. Z. D . Cooperative soft-cluster glass in giant molecular clusters . Macromolecules , 2019 , 52 4341 - 4348 . DOI: 10.1021/acs.macromol.9b00549 http://doi.org/10.1021/acs.macromol.9b00549 .

Liu, G.; Feng, X.; Lang, K.; Zhang, R.; Guo, D.; Yang, S.; Cheng, S. Z. D . Dynamics of shape-persistent giant molecules: zimm-like melt, elastic plateau, and cooperative glass-like . Macromolecules , 2017 , 50 6637 - 6646 . DOI: 10.1021/acs.macromol.7b01058 http://doi.org/10.1021/acs.macromol.7b01058 .

Zhu, Y.; Luo, J.; Zou, Q.; Ouyang, X.; Ruan, Y.; Liu, Y.; Liu, G . Glassy feature in melts of 3-dimensional architectured polymer blends . Polymer , 2022 , 238 124336 DOI: 10.1016/j.polymer.2021.124336 http://doi.org/10.1016/j.polymer.2021.124336 .

Liu, Y.; Yan, X.; Guo, Q.; Lei, H.; Liu, X.; Li, X.; Wu, Y.; Zhang, W.; Liu, G.; Cheng, S. Z. D . Recent progress on the rheology of giant molecules . Macromol. Chem. Phys. , 2022 , 224 2200357 DOI: 10.1002/macp.202200357 http://doi.org/10.1002/macp.202200357 .

Zou, Q.; Zhu, Y.; Ruan, Y.; Zhang, R.; Liu, G. X . Coarse-grained soft-clusters remain non-diffusing in the melt state . Giant , 2021 , 8 100070 DOI: 10.1016/j.giant.2021.100070 http://doi.org/10.1016/j.giant.2021.100070 .

Feng, X.; Liu, G.; Guo, D.; Lang, K.; Zhang, R.; Huang, J.; Su, Z.; Li, Y.; Huang, M.; Li, T.; Cheng, S. Z. D . Transition kinetics of self-assembled supramolecular dodecagonal quasicrystal and Frank-Kasper σ Phases in AB n dendron-like giant molecules . ACS Macro Lett. , 2019 , 8 875 - 881 . DOI: 10.1021/acsmacrolett.9b00287 http://doi.org/10.1021/acsmacrolett.9b00287 .

Xie, N.; Li, W.; Qiu, F.; Shi, A. C . σ Phase formed in conformationally asymmetric AB-type block copolymers . ACS Macro Lett. , 2014 , 3 906 - 910 . DOI: 10.1021/mz500445v http://doi.org/10.1021/mz500445v .

Li, W.; Duan, C.; Shi, A. C . Nonclassical spherical packing phases self-assembled from AB-type block copolymers . ACS Macro Lett. , 2017 , 6 1257 - 1262 . DOI: 10.1021/acsmacrolett.7b00756 http://doi.org/10.1021/acsmacrolett.7b00756 .

Bates, M. W.; Lequieu, J.; Barbon, S. M.; Lewis, R. M.; Delaney, K. T.; Anastasaki, A.; Hawker, C. J.; Fredrickson, G. H.; Bates, C. M . Stability of the A15 phase in diblock copolymer melts . Proc. Natl. Acad. Sci. , 2019 , 116 13194 - 13199 . DOI: 10.1073/pnas.1900121116 http://doi.org/10.1073/pnas.1900121116 .

Reddy, A.; Buckley, M. B.; Arora, A.; Bates, F. S.; Dorfman, K. D.; Grason, G. M . Stable Frank-Kasper phases of self-assembled, soft matter spheres . Proc. Natl. Acad. Sci. U. S. A. , 2018 , 115 10233 - 10238 . DOI: 10.1073/pnas.1809655115 http://doi.org/10.1073/pnas.1809655115 .

Bates, M. W.; Barbon, S. M.; Levi, A. E.; Lewis, R. M.; Beech, H. K.; Vonk, K. M.; Zhang, C.; Fredrickson, G. H.; Hawker, C. J.; Bates, C. M . Synthesis and self-assembly of AB n miktoarm star polymers . ACS Macro Lett. , 2020 , 9 396 - 403 . DOI: 10.1021/acsmacrolett.0c00061 http://doi.org/10.1021/acsmacrolett.0c00061 .

Ma, Z.; Tan, R.; Gan, Z.; Zhou, D.; Yang, Y.; Zhang, W.; Dong, X. H . Modulation of the complex spherical packings through rationally doping a discrete homopolymer into a discrete block copolymer: a quantitative study . Macromolecules , 2022 , 55 4331 - 4340 . DOI: 10.1021/acs.macromol.2c00682 http://doi.org/10.1021/acs.macromol.2c00682 .

Yue, K.; Huang, M.; Marson, R. L.; He, J.; Huang, J.; Zhou, Z.; Wang, J.; Liu, C.; Yan, X.; Wu, K.; Guo, Z.; Liu, H.; Zhang, W.; Ni, P.; Wesdemiotis, C.; Zhang, W. B.; Glotzer, S. C.; Cheng, S. Z. D . Geometry induced sequence of nanoscale Frank-Kasper and quasicrystal mesophases in giant surfactants . Proc. Natl. Acad. Sci. U. S. A. , 2016 , 113 14195 - 14200 . DOI: 10.1073/pnas.1609422113 http://doi.org/10.1073/pnas.1609422113 .

Su, H.; Li, Y.; Yue, K.; Wang, Z.; Lu, P.; Feng, X.; Dong, X. H.; Zhang, S.; Cheng, S. Z. D.; Zhang, W. B . Macromolecular structure evolution toward giant molecules of complex structure: tandem synthesis of asymmetric giant gemini surfactants . Polym. Chem. , 2014 , 5 3697 DOI: 10.1039/c4py00107a http://doi.org/10.1039/c4py00107a .

Feng, X.; Zhang, R.; Li, Y.; Hong, Y. L.; Guo, D.; Lang, K.; Wu, K. Y.; Huang, M.; Mao, J.; Wesdemiotis, C.; Nishiyama, Y.; Zhang, W.; Miyoshi, T.; Li, T.; Cheng, S. Z. D . Hierarchical self-organization of AB n dendron-like molecules into a supramolecular lattice sequence . ACS Cent. Sci. , 2017 , 3 860 - 867 . DOI: 10.1021/acscentsci.7b00188 http://doi.org/10.1021/acscentsci.7b00188 .

Percec, V.; Imam, M. R.; Peterca, M.; Wilson, D. A.; Heiney, P. A . Self-assembly of dendritic crowns into chiral supramolecular spheres . J. Am. Chem. Soc. , 2009 , 131 1294 - 1304 . DOI: 10.1021/ja8087778 http://doi.org/10.1021/ja8087778 .

Lee, S.; Leighton, C.; Bates, F. S . Sphericity and symmetry breaking in the formation of Frank-Kasper phases from one component materials . Proc. Natl. Acad. Sci. U. S. A. , 2014 , 111 17723 - 17731 . DOI: 10.1073/pnas.1408678111 http://doi.org/10.1073/pnas.1408678111 .

Lodge, T. P . Block copolymers: long-term growth with added value . Macromolecules , 2020 , 53 2 - 4 . DOI: 10.1021/acs.macromol.9b02069 http://doi.org/10.1021/acs.macromol.9b02069 .

Frank, F. C.; Kasper, J. S . Complex alloy structures regarded as sphere packings. ii. Analysis and classification of representative structures . Acta Crystallogr. , 1959 , 12 483 - 499 . DOI: 10.1107/s0365110x59001499 http://doi.org/10.1107/s0365110x59001499 .

Frank, F. C.; Kasper, J. S . Complex alloy structures regarded as sphere packings. i. Definitions and basic principles . Acta Crystallogr. , 1958 , 11 184 - 190 . DOI: 10.1107/s0365110x58000487 http://doi.org/10.1107/s0365110x58000487 .

Wigner, E.; Seitz, F . On the constitution of metallic sodium . Phys. Rev. , 1933 , 43 804 - 810 . DOI: 10.1103/PhysRev.43.804 http://doi.org/10.1103/PhysRev.43.804 .

Bohm, J.; Heimann, R. B.; Bohm, M . Voronoi polyhedra: a useful tool to determine the symmetry and bravais class of crystal lattices . Cryst. Res. Technol. , 1996 , 31 1069 - 1075 . DOI: 10.1002/crat.2170310816 http://doi.org/10.1002/crat.2170310816 .

Xie, R.; Mukherjee, S.; Levi, A. E.; Reynolds, V. G.; Wang, H.; Chabinyc, M. L.; Bates, C. M. . Room temperature 3D printing of super-soft and solvent-free elastomers . Sci. Adv. , 2020 , 6 eabc6900 DOI: 10.1126/sciadv.abc6900 http://doi.org/10.1126/sciadv.abc6900 .

Zhang, C.; Vigil, D. L.; Sun, D.; Bates, M. W.; Loman, T.; Murphy, E. A.; Barbon, S. M.; Song, J. A.; Yu, B.; Fredrickson, G. H.; Whittaker, A. K.; Hawker, C. J.; Bates, C. M . Emergence of hexagonally close-packed spheres in linear block copolymer melts . J. Am. Chem. Soc. , 2021 , 143 14106 - 14114 . DOI: 10.1021/jacs.1c03647 http://doi.org/10.1021/jacs.1c03647 .

Huang, Y. Y.; Hsu, J. Y.; Chen, H. L.; Hashimoto, T . Existence of FCC-packed spherical micelles in diblock copolymer melt . Macromolecules , 2007 , 40 406 - 409 . DOI: 10.1021/ma062149m http://doi.org/10.1021/ma062149m .

Bates, F. S.; Cohen, R. E.; Berney, C. V . Small-angle neutron scattering determination of macrolattice structure in a polystyrene-polybutadiene diblock copolymer . Macromolecules , 1982 , 15 589 - 592 . DOI: 10.1021/ma00230a073 http://doi.org/10.1021/ma00230a073 .

Yang, L.; Hong, S.; Gido, S. P.; Velis, G.; Hadjichristidis, N . I5S miktoarm star block copolymers: packing constraints on morphology and discontinuous chevron tilt grain boundaries . Macromolecules , 2001 , 34 9069 - 9073 . DOI: 10.1021/ma010737o http://doi.org/10.1021/ma010737o .

Yeardley, D. J. P.; Ungar, G.; Percec, V.; Holerca, M. N.; Johansson, G . Spherical supramolecular minidendrimers self-organized in an “inverse micellar”-like thermotropic body-centered cubic liquid crystalline phase . J. Am. Chem. Soc. , 2000 , 122 1684 - 1689 . DOI: 10.1021/ja993915q http://doi.org/10.1021/ja993915q .

Duan, H.; Hudson, S. D.; Ungar, G.; Holerca, M. N.; Percec, V . Definitive support by transmission electron microscopy, electron diffraction, and electron density maps for the formation of a BCC lattice from poly{ N -[3,4,5-tris( n -dodecan-l-yloxy)benzoyl]ethyleneimine} . Chem. Eur. J. , 2001 , 7 4134 - 4141 . DOI: 10.1002/1521-3765(20011001)7:19<4134::AID-CHEM4134>3.0.CO;2-W http://doi.org/10.1002/1521-3765(20011001)7:19<4134::AID-CHEM4134>3.0.CO;2-W .

Lin, Z.; Yang, X.; Xu, H.; Sakurai, T.; Matsuda, W.; Seki, S.; Zhou, Y.; Sun, J.; Wu, K. Y.; Yan, X. Y.; Zhang, R.; Huang, M.; Mao, J.; Wesdemiotis, C.; Aida, T.; Zhang, W.; Cheng, S. Z. D . Topologically directed assemblies of semiconducting sphere-rod conjugates . J. Am. Chem. Soc. , 2017 , 139 18616 - 18622 . DOI: 10.1021/jacs.7b10193 http://doi.org/10.1021/jacs.7b10193 .

Su, Z.; Huang, J.; Shan, W.; Yan, X. Y.; Zhang, R.; Liu, T.; Liu, Y.; Guo, Q. Y.; Bian, F.; Miao, X.; Huang, M.; Cheng, S. Z. D . Constituent isomerism-induced quasicrystal and Frank-Kasper σ superlattices based on nanosized shape amphiphiles . CCS Chem. , 2021 , 3 1434 - 1444 . DOI: 10.31635/ccschem.020.202000338 http://doi.org/10.31635/ccschem.020.202000338 .

Hsu, N. W.; Nouri, B.; Chen, L. T.; Chen, H. L . Hexagonal close-packed sphere phase of conformationally symmetric block copolymer . Macromolecules , 2020 , 53 9665 - 9675 . DOI: 10.1021/acs.macromol.0c01445 http://doi.org/10.1021/acs.macromol.0c01445 .

Zhang, J.; Sides, S.; Bates, F. S . Ordering of sphere forming SISO tetrablock terpolymers on a simple hexagonal lattice . Macromolecules , 2012 , 45 256 - 265 . DOI: 10.1021/ma202196c http://doi.org/10.1021/ma202196c .

Lindsay, A. P.; Cheong, G. K.; Peterson, A. J.; Weigand, S.; Dorfman, K. D.; Lodge, T. P.; Bates, F. S . Complex phase behavior in particle-forming AB/AB′ diblock copolymer blends with variable core block lengths . Macromolecules , 2021 , 54 7088 - 7101 . DOI: 10.1021/acs.macromol.1c01290 http://doi.org/10.1021/acs.macromol.1c01290 .

Mueller, A. J.; Lindsay, A. P.; Jayaraman, A.; Weigand, S.; Lodge, T. P.; Mahanthappa, M. K.; Bates, F. S . Tuning diblock copolymer particle packing symmetry with variable molecular weight core-homopolymers . Macromolecules , 2022 , 55 8332 - 8344 . DOI: 10.1021/acs.macromol.2c01267 http://doi.org/10.1021/acs.macromol.2c01267 .

Matsen, M. W . Effect of architecture on the phase behavior of AB-type block copolymer melts . Macromolecules , 2012 , 45 2161 - 2165 . DOI: 10.1021/ma202782s http://doi.org/10.1021/ma202782s .

Chen, L.; Qiang, Y.; Li, W . Tuning arm architecture leads to unusual phase behaviors in a (BAB) 5 star copolymer melt . Macromolecules , 2018 , 51 9890 - 9900 . DOI: 10.1021/acs.macromol.8b01484 http://doi.org/10.1021/acs.macromol.8b01484 .

Zhou, D.; Xu, M.; Ma, Z.; Gan, Z.; Tan, R.; Wang, S.; Zhang, Z.; Dong, X. H . Precisely encoding geometric features into discrete linear polymer chains for robust structural engineering . J. Am. Chem. Soc. , 2021 , 143 18744 - 18754 . DOI: 10.1021/jacs.1c09575 http://doi.org/10.1021/jacs.1c09575 .

Lachmayr, K. K.; Wentz, C. M.; Sita, L. R . An exceptionally stable and scalable sugar-polyolefin Frank-Kasper A15 phase . Angew. Chem. Int. Ed. , 2020 , 59 1521 - 1526 . DOI: 10.1002/anie.201912648 http://doi.org/10.1002/anie.201912648 .

Wilson, D. A.; Andreopoulou, K. A.; Peterca, M.; Leowanawat, P.; Sahoo, D.; Partridge, B. E.; Xiao, Q.; Huang, N.; Heiney, P. A.; Percec, V . Supramolecular spheres self-assembled from conical dendrons are chiral . J. Am. Chem. Soc. , 2019 , 141 6162 - 6166 . DOI: 10.1021/jacs.9b02206 http://doi.org/10.1021/jacs.9b02206 .

Zhang, R.; Feng, X.; Zhang, R.; Shan, W.; Su, Z.; Mao, J.; Wesdemiotis, C.; Huang, J.; Yan, X.; Liu, T.; Li, T.; Huang, M.; Lin, Z.; Shi, A.; Cheng, S. Z. D . Breaking parallel orientation of rods via a dendritic architecture toward diverse supramolecular structures . Angew. Chem. Int. Ed. , 2019 , 58 11879 - 11885 . DOI: 10.1002/anie.201904749 http://doi.org/10.1002/anie.201904749 .

Shao, Y.; Han, D.; Tao, Y.; Feng, F.; Han, G.; Hou, B.; Liu, H.; Yang, S.; Fu, Q.; Zhang, W. B. . Leveraging macromolecular isomerism for phase complexity in Janus nanograins . ACS Cent. Sci. , 2023 : 10.1021/acscentsci.2c01405 DOI: 10.1021/acscentsci.2c01405 http://doi.org/10.1021/acscentsci.2c01405 .

Weaire, D.; Fhelan, R . The structure of monodisperse foam . Philos. Mag. Lett. , 1994 , 70 345 - 350 . DOI: 10.1080/09500839408240997 http://doi.org/10.1080/09500839408240997 .

Weaire, D.; Phelan, R . A counter-example to Kelvin’s conjecture on minimal surfaces . Philos. Mag. Lett. , 1994 , 69 107 - 110 . DOI: 10.1080/09500839408241577 http://doi.org/10.1080/09500839408241577 .

Ziherl, P.; Kamien, R. D . Soap froths and crystal structures . Phys. Rev. Lett. , 2000 , 85 3528 - 3531 . DOI: 10.1103/PhysRevLett.85.3528 http://doi.org/10.1103/PhysRevLett.85.3528 .

Ungar, G.; Liu, Y.; Zeng, X.; Percec, V.; Cho, W. D . Giant supramolecular liquid crystal lattice . Science , 2003 , 299 1208 - 1211 . DOI: 10.1126/science.1078849 http://doi.org/10.1126/science.1078849 .

Zeng, X.; Ungar, G.; Liu, Y.; Percec, V.; Dulcey, A. E.; Hobbs, J. K . Supramolecular dendritic liquid quasicrystals . Nature , 2004 , 428 157 - 160 . DOI: 10.1038/nature02368 http://doi.org/10.1038/nature02368 .

Dubiel, S. M.; Cieślak, J . Sigma-phase in Fe-Cr and Fe-V alloy systems and its physical properties . Crit. Rev. Solid State Mater. Sci. , 2011 , 36 191 - 208 . DOI: 10.1080/10408436.2011.589232 http://doi.org/10.1080/10408436.2011.589232 .

Kim, K.; Arora, A.; Lewis, R. M.; Liu, M.; Li, W.; Shi, A. C.; Dorfman, K. D.; Bates, F. S . Origins of low-symmetry phases in asymmetric diblock copolymer melts . Proc. Natl. Acad. Sci. U. S. A. , 2018 , 115 847 - 854 . DOI: 10.1073/pnas.1717850115 http://doi.org/10.1073/pnas.1717850115 .

Liu, M.; Qiang, Y.; Li, W.; Qiu, F.; Shi, A. C . Stabilizing the Frank-Kasper phases via binary blends of AB diblock copolymers . ACS Macro Lett. , 2016 , 5 1167 - 1171 . DOI: 10.1021/acsmacrolett.6b00685 http://doi.org/10.1021/acsmacrolett.6b00685 .

Gillard, T. M.; Lee, S.; Bates, F. S . Dodecagonal quasicrystalline order in a diblock copolymer melt . Proc. Natl. Acad. Sci. U.S.A. , 2016 , 113 5167 - 5172 . DOI: 10.1073/pnas.1601692113 http://doi.org/10.1073/pnas.1601692113 .

Mueller, A. J.; Lindsay, A. P.; Jayaraman, A.; Lodge, T. P.; Mahanthappa, M. K.; Bates, F. S . Quasicrystals and their approximants in a crystalline-amorphous diblock copolymer . Macromolecules , 2021 , 54 2647 - 2660 . DOI: 10.1021/acs.macromol.0c02871 http://doi.org/10.1021/acs.macromol.0c02871 .

Hayashida, K.; Dotera, T.; Takano, A.; Matsushita, Y . Polymeric quasicrystal: mesoscopic quasicrystalline tiling in ABC star polymers . Phys. Rev. Lett. , 2007 , 98 195502 DOI: 10.1103/PhysRevLett.98.195502 http://doi.org/10.1103/PhysRevLett.98.195502 .

Wilson, C. G.; Thomas, D. K.; Spooner, F. J . The crystal structure of Zr 4 Al 3 . Acta Crystallogr. , 1960 , 13 56 - 57 . DOI: 10.1107/S0365110X60000121 http://doi.org/10.1107/S0365110X60000121 .

Huang, J.; Zhang, R.; Wang, Y.; Su, Z.; Yan, X. Y.; Guo, Q. Y.; Liu, T.; Liu, Y.; Lei, H.; Huang, M.; Zhang, W.; Cheng, S. Z. D . Rational route toward the Frank-Kasper Z phase: effect of precise geometrical tuning on the supramolecular assembly of giant shape amphiphiles . Macromolecules , 2021 , 54 7777 - 7785 . DOI: 10.1021/acs.macromol.1c01120 http://doi.org/10.1021/acs.macromol.1c01120 .

Magruder, B. R.; Dorfman, K. D . The C36 Laves phase in diblock polymer melts . Soft Matter , 2021 , 17 8950 - 8959 . DOI: 10.1039/D1SM01063H http://doi.org/10.1039/D1SM01063H .

Stein, F.; Leineweber, A . Laves phases: a review of their functional and structural applications and an improved fundamental understanding of stability and properties . J. Mater. Sci. , 2021 , 56 5321 - 5427 . DOI: 10.1007/s10853-020-05509-2 http://doi.org/10.1007/s10853-020-05509-2 .

Uddin, M. H.; Rodriguez, C.; López-Quintela, A.; Leisner, D.; Solans, C.; Esquena, J.; Kunieda, H . Phase behavior and microstructure of poly(oxyethylene)-poly(dimethylsiloxane) copolymer melt . Macromolecules , 2003 , 36 1261 - 1271 . DOI: 10.1021/ma0210978 http://doi.org/10.1021/ma0210978 .

Mueller, A. J.; Lindsay, A. P.; Jayaraman, A.; Lodge, T. P.; Mahanthappa, M. K.; Bates, F. S . Emergence of a C15 Laves phase in diblock polymer/homopolymer blends . ACS Macro Lett. , 2020 , 9 576 - 582 . DOI: 10.1021/acsmacrolett.0c00124 http://doi.org/10.1021/acsmacrolett.0c00124 .

Magruder, B. R.; Park, S. J.; Collanton, R. P.; Bates, F. S.; Dorfman, K. D . Laves phase field in a diblock copolymer alloy . Macromolecules , 2022 , 55 2991 - 2998 . DOI: 10.1021/acs.macromol.2c00346 http://doi.org/10.1021/acs.macromol.2c00346 .

Zhao, F.; Dong, Q.; Li, Q.; Liu, M.; Li, W . Emergence and stability of exotic “binary” HCP-type spherical phase in binary AB/AB blends . Macromolecules , 2022 , 55 10005 - 10013 . DOI: 10.1021/acs.macromol.2c01957 http://doi.org/10.1021/acs.macromol.2c01957 .

Jun, T.; Park, H.; Jeon, S.; Jo, S.; Ahn, H.; Jang, W. D.; Lee, B.; Ryu, D. Y . Mesoscale Frank-Kasper crystal structures from dendron assembly by controlling core apex interactions . J. Am. Chem. Soc. , 2021 , 143 17548 - 17556 . DOI: 10.1021/jacs.1c07313 http://doi.org/10.1021/jacs.1c07313 .

Xie, N.; Liu, M.; Deng, H.; Li, W.; Qiu, F.; Shi, A. C . Macromolecular metallurgy of binary mesocrystals via designed multiblock terpolymers . J. Am. Chem. Soc. , 2014 , 136 2974 - 2977 . DOI: 10.1021/ja412760k http://doi.org/10.1021/ja412760k .

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