Generation of Tough Poly(glycolic acid) (PGA)/Poly(butylene succinate-<italic style="font-style: italic">co</italic>-butylene adipate) (PBSA) Films with High Gas Barrier Performance through <italic style="font-style: italic">In situ</italic> Nanofibrillation of PBSA under an Elongational Flow Field

Fan Yang; Cai-Li Zhang; Yu Han; Zhi-Rui Ma; Yun-Xuan Weng

doi:10.1007/s10118-023-2972-9

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Generation of Tough Poly(glycolic acid) (PGA)/Poly(butylene succinate-co-butylene adipate) (PBSA) Films with High Gas Barrier Performance through In situ Nanofibrillation of PBSA under an Elongational Flow Field

RESEARCH ARTICLE | Updated：2023-11-10

- Generation of Tough Poly(glycolic acid) (PGA)/Poly(butylene succinate-co-butylene adipate) (PBSA) Films with High Gas Barrier Performance through In situ Nanofibrillation of PBSA under an Elongational Flow Field
- Generation of Tough Poly(glycolic acid) (PGA)/Poly(butylene succinate-co-butylene adipate) (PBSA) Films with High Gas Barrier Performance through In situ Nanofibrillation of PBSA under an Elongational Flow Field
- 高分子科学（英文版） 2023年41卷第11期页码：1805-1817
- Affiliations：
  
  College of Chemistry and Materials Engineering, Beijing Key Laboratory of Quality Evaluation Technology for Hygiene and Safety of Plastics, Beijing Technology and Business University, Beijing 100048, China
- Author bio：
  
  zhangcaili@btbu.edu.cn
- Funds：
  
  This study was financially supported by the National Key Research and Development Program of China (No. 2022YFB3704900), the National Natural Science Foundation of China (No. 52073004) and China National Tobacco Corporation Guizhou Company (No. 2023XM24).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-2972-9.
- DOI：10.1007/s10118-023-2972-9
  中图分类号：
- 收稿：2023-01-27，
  
  修回：2023-2-12，
  
  录用：2023-2-22，
  
  网络首发：2023-04-18，
  
  纸质出版：2023-11-01
- Accepted：
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Yang, F.; Zhang, C. L.; Han, Y.; Ma, Z. R.; Weng, Y. X. Generation of tough poly(glycolic acid) (PGA)/poly(butylene succinate-co-butylene adipate) (PBSA) films with high gas barrier performance through in situ nanofibrillation of PBSA under an elongational flow field. Chinese J. Polym. Sci. 2023, 41, 1805–1817

Fan Yang, Cai-Li Zhang, Yu Han, et al. Generation of Tough Poly(glycolic acid) (PGA)/Poly(butylene succinate-co-butylene adipate) (PBSA) Films with High Gas Barrier Performance through In situ Nanofibrillation of PBSA under an Elongational Flow Field[J]. Chinese Journal of Polymer Science, 2023, 41(11): 1805-1817. DOI: 10.1007/s10118-023-2972-9.
Yang, F.; Zhang, C. L.; Han, Y.; Ma, Z. R.; Weng, Y. X. Generation of tough poly(glycolic acid) (PGA)/poly(butylene succinate-co-butylene adipate) (PBSA) films with high gas barrier performance through in situ nanofibrillation of PBSA under an elongational flow field. Chinese J. Polym. Sci. 2023, 41, 1805–1817 DOI： 10.1007/s10118-023-2972-9.

Fan Yang, Cai-Li Zhang, Yu Han, et al. Generation of Tough Poly(glycolic acid) (PGA)/Poly(butylene succinate-co-butylene adipate) (PBSA) Films with High Gas Barrier Performance through In situ Nanofibrillation of PBSA under an Elongational Flow Field[J]. Chinese Journal of Polymer Science, 2023, 41(11): 1805-1817. DOI: 10.1007/s10118-023-2972-9. DOI：

摘要

In this work

fully biodegradable PGA/PBSA films with high PGA content were developed by extrusion blown film technique. The hierarchical structure of PBSA nanofibers and interfacially oriented PGA crystals enable the films to have high barrier performance and mechanical properties.

Abstract

Poly(glycolic acid) (PGA) is derived from glycolide obtained by fermenting pineapples or sugarcane

which has excellent gas barrier properties and a small carbon footprint. PGA is a potential substitute for the current aluminum-plastic composite films used in high barrier packaging applications. However

its poor ductility and narrow processing window limit its application in food packaging. Herein

poly(butylene succinate-

-butylene adipate) (PBSA) was used to fabricate PGA/PBSA blend films through an

in situ

fibrillation technique and blown film extrusion. Under the elongational flow field used during the extrusion process

a unique hierarchical structure based on the PBSA nanofibrils and interfacially oriented PGA crystals was obtained. This structure enhances the strength

ductility and gas barrier properties of the PGA/PBSA blend film. In addition

an epoxy chain extender (ADR4468) was used as a compatibilizer to further enhance the interfacial adhesion between PGA and PBSA. 70PGA/0.7ADR exhibited a very low oxygen permeability (2.34×10

−4

Barrer) with significantly high elongating at break (604.4%)

tensile strength (47.4 MPa)

and transparency

which were superior to those of petroleum-based polymers. Thus

the 70PGA/0.7ADR blown films could satisfy the requirements for most instant foods such as coffee

peanuts

and fresh meat.

关键词

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references

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Generation of Tough Poly(glycolic acid) (PGA)/Poly(butylene succinate-co-butylene adipate) (PBSA) Films with High Gas Barrier Performance through In situ Nanofibrillation of PBSA under an Elongational Flow Field

Generation of Tough Poly(glycolic acid) (PGA)/Poly(butylene succinate-co-butylene adipate) (PBSA) Films with High Gas Barrier Performance through In situ Nanofibrillation of PBSA under an Elongational Flow Field

DOI：10.1007/s10118-023-2972-9

摘要

Abstract

关键词

Keywords

references