Synthetic Features and Mechanism for the Preparation of Vinyl Chloride-<italic style="font-style: italic">co</italic>-Butyl Acrylate-<italic style="font-style: italic">co</italic>-Vinyl Acetate Terpolymer <italic style="font-style: italic">via</italic> Precipitation Polymerization

Chang-Tong Song; Xian-Hong Zhang; Dong Chen; Yu-Hong Ma; Wan-Tai Yang

doi:10.1007/s10118-023-2965-8

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Synthetic Features and Mechanism for the Preparation of Vinyl Chloride-co-Butyl Acrylate-co-Vinyl Acetate Terpolymer via Precipitation Polymerization

RESEARCH ARTICLE | Updated：2023-11-10

- Synthetic Features and Mechanism for the Preparation of Vinyl Chloride-co-Butyl Acrylate-co-Vinyl Acetate Terpolymer via Precipitation Polymerization
- Synthetic Features and Mechanism for the Preparation of Vinyl Chloride-co-Butyl Acrylate-co-Vinyl Acetate Terpolymer via Precipitation Polymerization
- 高分子科学（英文版） 2023年41卷第11期页码：1714-1724
- Affiliations：
  
  a.State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  b.College of Material Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
- Author bio：
  
  xhzhang@mail.buct.edu.cn (X.H.Z.)
  yangwt@mail.buct.edu.cn (W.T.Y.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 51988102) and Fundamental Research Funds for the Central Universities (No. XK2020-01).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-2965-8.
- DOI：10.1007/s10118-023-2965-8
  中图分类号：
- 收稿：2022-12-08，
  
  修回：2023-1-8，
  
  录用：2023-2-2，
  
  网络首发：2023-03-22，
  
  纸质出版：2023-11-01
- Accepted：
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Song, C. T.; Zhang, X. H.; Chen, D.; Ma, Y. H.; Yang, W. T. Synthetic features and mechanism for the preparation of vinyl chloride-co-butyl acrylate-co-vinyl acetate terpolymer via precipitation polymerization. Chinese J. Polym. Sci. 2023, 41, 1714–1724

Chang-Tong Song, Xian-Hong Zhang, Dong Chen, et al. Synthetic Features and Mechanism for the Preparation of Vinyl Chloride-co-Butyl Acrylate-co-Vinyl Acetate Terpolymer via Precipitation Polymerization[J]. Chinese Journal of Polymer Science, 2023, 41(11): 1714-1724. DOI: 10.1007/s10118-023-2965-8.
Song, C. T.; Zhang, X. H.; Chen, D.; Ma, Y. H.; Yang, W. T. Synthetic features and mechanism for the preparation of vinyl chloride-co-butyl acrylate-co-vinyl acetate terpolymer via precipitation polymerization. Chinese J. Polym. Sci. 2023, 41, 1714–1724 DOI： 10.1007/s10118-023-2965-8.

Chang-Tong Song, Xian-Hong Zhang, Dong Chen, et al. Synthetic Features and Mechanism for the Preparation of Vinyl Chloride-co-Butyl Acrylate-co-Vinyl Acetate Terpolymer via Precipitation Polymerization[J]. Chinese Journal of Polymer Science, 2023, 41(11): 1714-1724. DOI: 10.1007/s10118-023-2965-8. DOI：

摘要

The poly[(vinyl chloride)-

-(n-butyl acrylate)-

-(vinyl acetate)] random terpolymers are synthesized successfully via precipitation polymerization. The reaction medium and the monomer feed ratios are crucial factors both for the polymer morphology and reaction kinetic. Moreover

precipitation polymerization is suitable to synthesize ternary copolymer with low number-average molecular weight and high content of BA.

Abstract

Without any type of surfactant or dispersing agent

precipitation polymerization has great superiorities in both polymer synthesis and applications. In the present work

the polymerization of vinyl chloride (VC)

-butyl acrylate (BA)

and vinyl acetate (VAc) are conducted in the precipitation polymerization system and series of their random terpolymers poly(vinyl chloride-

-butyl acrylate

-co

-vinyl acetate) (PCBV) are synthesized successfully. The effects of various polymerization conditions

including solvent polarity

temperature

initiator concentration

and monomer feed ratios on the polymerization kinetics

number-average molecular weight (

)

and terpolymer composition are investigated systematically. The solvent and the monomer feed ratio are crucial factors not only for the polymer morphology

but also for the reaction kinetic. In the non-polar solvent such as

-hexane

the PCBV displays particle morphology when the composition of BA ratio lower than 10 wt%. Otherwise

the PCBV forms a uniform polymer phase and precipitates out from the mixture. In the polar solvent

e.g.

dimethyl carbonate (DMC) and ethanol

the PCBV polymer maintains a slurry state either in low or in high monomer feed ratio. Impressively

VC based ternary copolymer that obtained in

-hexane has much lower

(

20 kDa) and much higher BA units mass fraction (

40 wt%) compared with emulsion and suspension polymerization. Additionally

the terpolymer can be easily separated by simple centrifugation.

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Synthetic Features and Mechanism for the Preparation of Vinyl Chloride-co-Butyl Acrylate-co-Vinyl Acetate Terpolymer via Precipitation Polymerization

Synthetic Features and Mechanism for the Preparation of Vinyl Chloride-co-Butyl Acrylate-co-Vinyl Acetate Terpolymer via Precipitation Polymerization

DOI：10.1007/s10118-023-2965-8

摘要

Abstract

关键词

Keywords

references