Hyper-crosslinked Conjugated Microporous Polymers with Increased Micropores Promotes Confining Polymerization for Electromagnetic Absorption Application

Hao Chen; Fang-Yuan Chu; Hai-Yan Zhuang; Lu Wang; Zhi-Min Ye; Wei Dong; Zhi-Peng Xie; A-Ming Xie

doi:10.1007/s10118-023-2962-y

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Hyper-crosslinked Conjugated Microporous Polymers with Increased Micropores Promotes Confining Polymerization for Electromagnetic Absorption Application

RESEARCH ARTICLE | Updated：2023-07-18

- Hyper-crosslinked Conjugated Microporous Polymers with Increased Micropores Promotes Confining Polymerization for Electromagnetic Absorption Application
- Hyper-crosslinked Conjugated Microporous Polymers with Increased Micropores Promotes Confining Polymerization for Electromagnetic Absorption Application
- 高分子科学（英文版） 2023年41卷第8期页码：1305-1316
- Affiliations：
  
  a.School of Mechanical Engineering, Nanjing University of Science & Technology, Nanjing 210094, China
  b.State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute (LSMRI), Xiamen 361100, China
  c.School of Chemistry and Chemical Engineering, Nanjing University of Science & Technology, Nanjing 210094, China
- Author bio：
  
  zhipengxie1982@163.com (Z.P.X.)
  xieaming@njust.edu.cn (A.M.X.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 52273267) and the Fundamental Research Funds for the Central Universities (Nos. 30920041102 and 30920021107) and thanks to Shiyanjia Lab (www.shiyanjia.com) for the XPS analysis.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-2962-y.
- DOI：10.1007/s10118-023-2962-y
  中图分类号：
- 收稿：2022-12-20，
  
  修回：2023-2-26，
  
  录用：2023-2-27，
  
  网络首发：2023-04-18，
  
  纸质出版：2023-08-01
- Accepted：
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Chen, H.; Chu, F. Y.; Zhuang, H. Y.; Wang, L.; Ye, Z. M.; Dong, W.; Xie, Z. P.; Xie, A. M. Hyper-crosslinked conjugated microporous polymers with increased micropores promotes confining polymerization for electromagnetic absorption application. Chinese J. Polym. Sci. 2023, 41, 1305–1316

Hao Chen, Fang-Yuan Chu, Hai-Yan Zhuang, et al. Hyper-crosslinked Conjugated Microporous Polymers with Increased Micropores Promotes Confining Polymerization for Electromagnetic Absorption Application[J]. Chinese Journal of Polymer Science, 2023, 41(8): 1305-1316.
Chen, H.; Chu, F. Y.; Zhuang, H. Y.; Wang, L.; Ye, Z. M.; Dong, W.; Xie, Z. P.; Xie, A. M. Hyper-crosslinked conjugated microporous polymers with increased micropores promotes confining polymerization for electromagnetic absorption application. Chinese J. Polym. Sci. 2023, 41, 1305–1316 DOI： 10.1007/s10118-023-2962-y.

Hao Chen, Fang-Yuan Chu, Hai-Yan Zhuang, et al. Hyper-crosslinked Conjugated Microporous Polymers with Increased Micropores Promotes Confining Polymerization for Electromagnetic Absorption Application[J]. Chinese Journal of Polymer Science, 2023, 41(8): 1305-1316. DOI： 10.1007/s10118-023-2962-y.

摘要

Abstract

Conjugated microporous polymers have excellent skeleton structures but poor electrical conductivity limits their applications in microwave absorption. To solve this problem

a strategy of molecular expansion and confining polymerization is proposed in this work to synthesize conductive hyper-crosslinked conjugated microporous polymer. The topology of the conjugated microporous polymer is changed into a three-dimensional skeleton structure with high specific surface area by using molecular expansion technique

and the controlled growth of polypyrrole in the channel constructs a unique network structure. The balance of excellent composite backbone structure

proper conductivity

attenuation capability and impedance matching enable the material to exhibit electromagnetic wave absorption performance. As a result

with low filler loading of 10 wt%

a strongest reflection loss of −52.68 dB and a maximum effective bandwidth of 5.76 GHz. Additionally

CST simulations of the radar scattering cross section have been carried out to verify the excellent material properties. This study provides new concepts for new conductive polymers and broadens the application of hyper-crosslinked conjugated microporous polymer in the field of electromagnetic wave absorption.

关键词

Keywords

references

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