Rapid Conversion of Perhydropolysilazane into Thin Silica Coating at Low Temperature

Wen-Yue Wang; Yu-Lin Zhang; Xiang Guo; Li-Ming Wang; Jun-Rong Zhang; Hui Yang; Guo-Jun Dong; Zong-Bo Zhang; Cai-Hong Xu

doi:10.1007/s10118-023-2959-6

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Rapid Conversion of Perhydropolysilazane into Thin Silica Coating at Low Temperature

RESEARCH ARTICLE | Updated：2023-07-18

- Rapid Conversion of Perhydropolysilazane into Thin Silica Coating at Low Temperature
- Rapid Conversion of Perhydropolysilazane into Thin Silica Coating at Low Temperature
- 高分子科学（英文版） 2023年41卷第8期页码：1198-1205
- Affiliations：
  
  a.Key Laboratory of Science and Technology on High-tech Polymer Materials, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  b.Yantai Research Institute, Harbin Engineering University, Yantai 264000, China
  c.Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China
  d.Spallation Neutron Source Science Center, Dongguan 523803, China
- Author bio：
  
  dgj1129@163.com (G.J.D.)
  zongbo@iccas.ac.cn (Z.B.Z.)
- Funds：
  
  A portion of this work is based on the data obtained at BSRF-1W1A. The authors gratefully acknowledge the cooperation of the beamline scientists at BSRF-1W1A beamline. This work was financially supported by the National Natural Science Foundation of China (No. 21872152), Guangdong Natural Science Foundation (No. 2019A1515111028) and Xiejialin Foundation in the Institute of High Energy Physics (No. E15466U210).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-2959-6.
- DOI：10.1007/s10118-023-2959-6
  中图分类号：
- 收稿：2022-12-27，
  
  修回：2023-1-19，
  
  录用：2023-1-31，
  
  网络首发：2023-03-17，
  
  纸质出版：2023-08-01
- Accepted：
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Wang, W. Y.; Zhang, Y. L.; Guo, X.; Wang, L. M.; Zhang, J. R.; Yang, H.; Dong, G. J.; Zhang, Z. B.; Xu, C. H. Rapid conversion of perhydropolysilazane into thin silica coating at low temperature. Chinese J. Polym. Sci. 2023, 41, 1198–1205

Wen-Yue Wang, Yu-Lin Zhang, Xiang Guo, et al. Rapid Conversion of Perhydropolysilazane into Thin Silica Coating at Low Temperature[J]. Chinese Journal of Polymer Science, 2023, 41(8): 1198-1205.
Wang, W. Y.; Zhang, Y. L.; Guo, X.; Wang, L. M.; Zhang, J. R.; Yang, H.; Dong, G. J.; Zhang, Z. B.; Xu, C. H. Rapid conversion of perhydropolysilazane into thin silica coating at low temperature. Chinese J. Polym. Sci. 2023, 41, 1198–1205 DOI： 10.1007/s10118-023-2959-6.

Wen-Yue Wang, Yu-Lin Zhang, Xiang Guo, et al. Rapid Conversion of Perhydropolysilazane into Thin Silica Coating at Low Temperature[J]. Chinese Journal of Polymer Science, 2023, 41(8): 1198-1205. DOI： 10.1007/s10118-023-2959-6.

摘要

Abstract

The conversion of perhydropolysilazane (PHPS) to silica at low temperature is beneficial for its application on thermally vulnerable substrates. In this work

it is demonstrated that (3-aminopropyl)triethoxysilane (APTES) has high catalytic efficiency for the low temperature conversion of PHPS and the catalytic mechanism of APTES was suggested. The influence of temperature and humidity on the catalytic conversion process was investigated

and it was found that PHPS can be rapidly converted to silica in 10 min at 80 °C with relative humidity of 90%. The achieved silica is mainly composed of SiNO

/SiO

OH and SiO

structure with O/Si of 1.74 and N content of 1%. As an approach to prepare inorganic coating

the low-temperature conversion method achieves a silica coating with low volume shrinkage of 0.86%

low roughness of

=0.293 nm

high nanoindentation hardness of 3.62 GPa and modulus of 30.06 GPa

which exhibits high potentials as protective coating for various materials even those vulnerable to high temperature.

关键词

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references

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