Influence of Hydrogen Bonding on the Temperature-Accelerated Hydrolysis of Silicone Based Polyetherurethane

He-Cheng Wu; Shu-Ren Shao; Shuo-Hong Dong; Ao Wang; Zhen Li; Xiang-Long Han; Feng Luo; Jie-Hua Li; Dai-Guo Zhao; Wan-Ling Lan; Hong Tan

doi:10.1007/s10118-023-2957-8

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Influence of Hydrogen Bonding on the Temperature-Accelerated Hydrolysis of Silicone Based Polyetherurethane

RESEARCH ARTICLE | Updated：2023-07-18

- Influence of Hydrogen Bonding on the Temperature-Accelerated Hydrolysis of Silicone Based Polyetherurethane
- Influence of Hydrogen Bonding on the Temperature-Accelerated Hydrolysis of Silicone Based Polyetherurethane
- 高分子科学（英文版） 2023年41卷第8期页码：1230-1237
- Affiliations：
  
  a.College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Med-X Center for Materials, Sichuan University, Chengdu 610065, China
  b.State Key Laboratory of Oral Diseases, National Clinical Research Center for Oral Diseases, West China Hospital of Stomatology, Sichuan University, Chengdu 610041, China
  c.Sichuan Institute for Food and Drug Control, Chengdu 611731, China
- Author bio：
  
  zhenli@scu.edu.cn (Z.L.)
  hongtan@scu.edu.cn (H.T.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 51973134), the State Key Research Development Program of China (No. 2020YFC1107000), the NSAF (No. U1930204) and Interdisciplinary Innovation Projects of West China Hospital of Stomatology Sichuan University (No. RD-03-202001). We thank Chenxu Tian from the College of Polymer Science and Engineering of Sichuan University for her help in the measurement of SEM.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-2957-8.
- DOI：10.1007/s10118-023-2957-8
  中图分类号： M
- 收稿：2022-11-28，
  
  修回：2023-1-22，
  
  录用：2023-1-31，
  
  网络首发：2023-03-10，
  
  纸质出版：2023-08-01
- Accepted：
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Wu, H. C.; Shao, S. R.; Dong, S. H.; Wang, A.; Li, Z.; Han, X. L.; Luo, F.; Li, J. H.; Zhao, D. G.; Lan, W. L.; Tan, H. Influence of hydrogen bonding on the temperature-accelerated hydrolysis of silicone based polyetherurethane. Chinese J. Polym. Sci. 2023, 41, 1230–1237

He-Cheng Wu, Shu-Ren Shao, Shuo-Hong Dong, et al. Influence of Hydrogen Bonding on the Temperature-Accelerated Hydrolysis of Silicone Based Polyetherurethane[J]. Chinese Journal of Polymer Science, 2023, 41(8): 1230-1237.
Wu, H. C.; Shao, S. R.; Dong, S. H.; Wang, A.; Li, Z.; Han, X. L.; Luo, F.; Li, J. H.; Zhao, D. G.; Lan, W. L.; Tan, H. Influence of hydrogen bonding on the temperature-accelerated hydrolysis of silicone based polyetherurethane. Chinese J. Polym. Sci. 2023, 41, 1230–1237 DOI： 10.1007/s10118-023-2957-8.

He-Cheng Wu, Shu-Ren Shao, Shuo-Hong Dong, et al. Influence of Hydrogen Bonding on the Temperature-Accelerated Hydrolysis of Silicone Based Polyetherurethane[J]. Chinese Journal of Polymer Science, 2023, 41(8): 1230-1237. DOI： 10.1007/s10118-023-2957-8.

摘要

Abstract

Temperature-accelerated

in vitro

degradation was established to estimate the longevity of polyurethane applied for long-term implantation. However

the prediction did not correlate well with the data from clinical explants and the rationality of accelerated

in vitro

test is still in a controversial due to the deviation. To improve the accuracy of the

in vitro

prediction

the influence of hydrogen bonding (HB) on the accelerated hydrolysis of silicone based polyetherurethans (SPEUs) extended with three side chains. Combining the temperature-controlled FTIR and the physical properties after temperature-accelerated

in vitro

degradation

it was demonstrated that side chain could increase the degree of hydrogen bond dissociation at higher temperature

resulting in the decrease of the calculated activation energy (

) of hydrolysis. At low temperatures

changes in surface morphology and molar mass of PEUs are minimal and HB are less easily dissociated

which had barely impact on the hydrolysis resistance. It was proposed that the

will not be impacted and that the accuracy of prediction will be increased if the acceleration temperature is lower than 70 °C and HB change is less than 15%.

关键词

Keywords

references

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