a.Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
b.Qinghai University, Qinghai 810016, China
c.University of Chinese Academy of Sciences, Beijing 100049, China
fu.liu@nimte.ac.cn
收稿:2022-11-25,
修回:2022-12-25,
录用:2023-1-6,
网络首发:2023-02-09,
纸质出版:2023-04-01
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Lin, H. B.; Zhao, J. G.; Lu, N.; Han, Q.; Wang, J. Q.; Guan, J. M.; Wang, X.; Liu, F. Prussian blue/cellulose acetate thin film composite nanofiltration membrane for molecular sieving and catalytic fouling resistance. Chinese J. Polym. Sci. 2023, 41, 593–604
Hai-Bo Lin, Jian-Guo Zhao, Na Lu, et al. Prussian Blue/Cellulose Acetate Thin Film Composite Nanofiltration Membrane for Molecular Sieving and Catalytic Fouling Resistance[J]. Chinese Journal of Polymer Science, 2023, 41(4): 593-604.
Lin, H. B.; Zhao, J. G.; Lu, N.; Han, Q.; Wang, J. Q.; Guan, J. M.; Wang, X.; Liu, F. Prussian blue/cellulose acetate thin film composite nanofiltration membrane for molecular sieving and catalytic fouling resistance. Chinese J. Polym. Sci. 2023, 41, 593–604 DOI: 10.1007/s10118-023-2950-2.
Hai-Bo Lin, Jian-Guo Zhao, Na Lu, et al. Prussian Blue/Cellulose Acetate Thin Film Composite Nanofiltration Membrane for Molecular Sieving and Catalytic Fouling Resistance[J]. Chinese Journal of Polymer Science, 2023, 41(4): 593-604. DOI: 10.1007/s10118-023-2950-2.
The Prussian blue engineered cellulose acetate nanofiltration membrane was prepared via a thin film composite strategy. The defect-free FeCo-PB selective layer shows good separation performances for dye molecules and excellent photocatalytic degradation of organic foulants.
Nanofiltration (NF) membranes as high selective separators are appealing for molecular sieving
which still remains a great challenge for the mixed dyes with same charge. In this study
cellulose acetate (CA) membranes were firstly aminated by ethylene imine polymer (PEI)
and then the thin film of metal organic frameworks (MOFs) were constructed onto aminated CA membrane through forward-diffusion
slow crystallization and
in situ
growth of FeCo-Prussian blue (FeCo-PB) crystallization layers. The designed PB@CA composite NF membrane shows an ideal rejection for Congo red (CR)/methyl orange (MO) mixture solution
with 99.7%±0.2% for CR and 33.5%±2% for MO. In addition
the composite NF membrane demonstrated good efficiency for photocatalytic degradation of organic fouling (permeability recovery ratio was up to 92%) due to the active FeCo-PB micro-cubes. Thus
this work provides a practical strategy to prepare MOFs mediated thin film composite nanofiltration membrane for precise molecular sieving and catalytic antifouling performances.
Cai, Y.; Ji, C. D.; Zhang, S. B.; Su, Z. Q.; Yin, M. Z . Synthesis of water-soluble dye-cored poly(amidoamine) dendrimers for long-term live cell imaging . Sci. China Mater. , 2018 . 61 1475 - 1483 . DOI: 10.1007/s40843-018-9246-6 http://doi.org/10.1007/s40843-018-9246-6 .
Zhang, X. Y.; Fu, K.; Su, Z. Q . Fabrication of 3D MoS 2 -TiO 2 @PAN electro-spun membrane for efficient and recyclable photocatalytic degradation of organic dyes . Mater. Sci. Eng., B , 2021 . 269 115179 DOI: 10.1016/j.mseb.2021.115179 http://doi.org/10.1016/j.mseb.2021.115179 .
Alvarez, P. J. J.; Chan, C. K.; Elimelech, M.; Halas, N. J.; Villagran, D . Emerging opportunities for nanotechnology to enhance water security . Nat. Nanotechnol. , 2018 . 13 634 - 641 . DOI: 10.1038/s41565-018-0203-2 http://doi.org/10.1038/s41565-018-0203-2 .
Lin, H. B.; Fang, Q. L.; Wang, W.; Li, G. L.; Guan, J. M.; Shen, Y.; Ye, J. R.; Liu, F . Prussian blue/PVDF catalytic membrane with exceptional and stable Fenton oxidation performance for organic pollutants removal . Appl. Catal. B , 2020 . 273 119047 DOI: 10.1016/j.apcatb.2020.119047 http://doi.org/10.1016/j.apcatb.2020.119047 .
Wang, Z. B.; Ni, D.; Shang, Y. L.; Guan, Y. J . Recycling of dye from wastewater using a ceramic membrane modified with bismuth/stibium co-doped tin dioxide . J. Clean. Prod. , 2019 . 213 192 - 198 . DOI: 10.1016/j.jclepro.2018.12.159 http://doi.org/10.1016/j.jclepro.2018.12.159 .
Jiang, B.; Zheng, J. T.; Lu, X.; Liu, Q.; Wu, M. B.; Yan, Z. F.; Qiu, S.; Xue, Q. Z.; Wei, Z. X.; Xiao, H. J.; Liu, M. M . Degradation of organic dye by pulsed discharge non-thermal plasma technology assisted with modified activated carbon fibers . Chem. Eng. J. , 2013 . 215 969 - 978 . DOI: 10.1016/j.cej.2012.11.046 http://doi.org/10.1016/j.cej.2012.11.046 .
Archin, S.; Sharifi, S. H.; Asadpour, G . Optimization and modeling of simultaneous ultrasound-assisted adsorption of binary dyes using activated carbon from tobacco residues: response surface methodology . J. Clean. Prod. , 2019 . 239 118136 DOI: 10.1016/j.jclepro.2019.118136 http://doi.org/10.1016/j.jclepro.2019.118136 .
Xu, R.; Jian, M.; Ji, Q.; Hu, C.; Tang, C.; Liu, R.; Zhang, X.; Qu, J . 2D water-stable zinc-benzimidazole framework nanosheets for ultrafast and selective removal of heavy metals . Chem. Eng. J. , 2020 . 382 122658 DOI: 10.1016/j.cej.2019.122658 http://doi.org/10.1016/j.cej.2019.122658 .
Kang, J.; Zhou, L.; Duan, X.; Sun, H.; Ao, Z.; Wang, S . Degradation of cosmetic microplastics via functionalized carbon nanosprings . Matter , 2019 . 1 745 - 758 . DOI: 10.1016/j.matt.2019.06.004 http://doi.org/10.1016/j.matt.2019.06.004 .
Tang, Y.; He, D.; Guo, Y.; Qu, W.; Dong, W . Electrochemical oxidative degradation of X-6G dye by boron-doped diamond anodes: effect of operating parameters . Chemosphere , 2020 . 258 127368 DOI: 10.1016/j.chemosphere.2020.127368 http://doi.org/10.1016/j.chemosphere.2020.127368 .
Sudmalis, D.; Silva, P. D.; Temmink, H.; Bijmans, M.M.; Pereira, M.A . Biological treatment of produced water coupled with recovery of neutral lipids . Water Res. , 2018 . 147 33 - 42 . DOI: 10.1016/j.watres.2018.09.050 http://doi.org/10.1016/j.watres.2018.09.050 .
Fatima, J.; Faheem, U.; Razlan, Z. M.; Md, A. H . An approach to classification and hi-tech applications of room-temperature ionic liquids (RTILs): a review . J. Mol. Liquids , 2018 . 271 403 - 420 . DOI: 10.1016/j.molliq.2018.09.005 http://doi.org/10.1016/j.molliq.2018.09.005 .
Buscio, V.; Crespi, M.; Gutiérrez-Bouzán, C . Sustainable dyeing of denim using indigo dye recovered with polyvinylidene difluoride ultrafiltration membranes . J. Clean. Prod. , 2015 . 91 201 - 207 . DOI: 10.1016/j.jclepro.2014.12.016 http://doi.org/10.1016/j.jclepro.2014.12.016 .
Zhang, Z.; Yang, H.; Cao, C.; Liu, Y.; Liang, S.; Wang, M.; Wang, H.; Cao, X.; Pan, F.; Wu, H.; Jiang, Z . Vapor-liquid interfacial polymerization of covalent organic framework membranes for efficient alcohol dehydration . J. Membr. Sci. , 2022 . 641 119905 DOI: 10.1016/j.memsci.2021.119905 http://doi.org/10.1016/j.memsci.2021.119905 .
Bilal, M.; Asgher, M.; Parra-Saldivar, R.; Hu, H.; Wang, W.; Zhang, X.; Iqbal, H. M. N . Immobilized ligninolytic enzymes: an innovative and environmental responsive technology to tackle dye-based industrial pollutants—a review . Sci. Total Environ. , 2017 . 576 646 - 659 . DOI: 10.1016/j.scitotenv.2016.10.137 http://doi.org/10.1016/j.scitotenv.2016.10.137 .
Tuong, T.; Tran, V.; Kumar, S. R.; Lue, S. J . Separation mechanisms of binary dye mixtures using a PVDF ultrafiltration membrane: donnan effect and intermolecular interaction . J. Membr. Sci. , 2019 . 575 38 - 49 . DOI: 10.1016/j.memsci.2018.12.070 http://doi.org/10.1016/j.memsci.2018.12.070 .
Chan, L. S.; Cheung, W. H.; Allen, S. J.; McKay, G . Separation of acid-dyes mixture by bamboo derived active carbon . Separ. Purif. Technol. , 2009 . 67 166 - 172 . DOI: 10.1016/j.seppur.2009.03.020 http://doi.org/10.1016/j.seppur.2009.03.020 .
Cheng, N.; Hu, Q.; Guo, Y.; Wang, Y.; Yu, L . Efficient and selective removal of dyes using imidazolium-based supramolecular gels . ACS Appl. Mater. Interfaces , 2015 . 7 10258 - 10265 . DOI: 10.1021/acsami.5b00814 http://doi.org/10.1021/acsami.5b00814 .
Zhang, L. L.; Xu, L.; Yu, H. Y.; Yao, P. Y.; Zhang, M.; Guo, F. X.; Yu, L. M . Capsaicin mimic-polyethyleneimine crosslinked antifouling loose nanofiltration membrane for effective dye/salt wastewater treatment . J. Membr. Sci. , 2022 . 641 119923 DOI: 10.1016/j.memsci.2021.119923 http://doi.org/10.1016/j.memsci.2021.119923 .
Li, Y. J.; Wang, Y. X.; Liu, Z. Y.; Jiang, L. Y.; Yang, H.; Xu, Z. L . Separation of anionic dye mixtures by Al-metal-organic framework filled polyacrylonitrile-ethanolamine membrane and its modified product . J. Clean. Prod. , 2021 . 284 124778 DOI: 10.1016/j.jclepro.2020.124778 http://doi.org/10.1016/j.jclepro.2020.124778 .
Makhetha, T. A.; Moutloali, R. M . Antifouling properties of Cu(tpa)@GO/PES composite membranes and selective dye rejection . J. Membr. Sci. , 2018 . 554 195 - 210 . DOI: 10.1016/j.memsci.2018.03.003 http://doi.org/10.1016/j.memsci.2018.03.003 .
Cao, L.; Wen, Q.; Feng, Y.; Ji, D.; Li, H.; Li, N.; Jiang, L.; Guo, W . On the origin of ion selectivity in ultrathin nanopores: insights for membrane-scale osmotic energy conversion . Adv. Funct. Mater. , 2018 . 28 1804189 DOI: 10.1002/adfm.201804189 http://doi.org/10.1002/adfm.201804189 .
Yaghi, O. M.; Li, H. L . Hydrothermal synthesis of a metal-organic framework containing large rectangular channels . J. Am. Chem. Soc. , 1995 . 117 10401 - 10402 . DOI: 10.1021/ja00146a033 http://doi.org/10.1021/ja00146a033 .
Henrique, A.; Rodrigues, A. E.; Silva, J. A. C . Separation of hexane isomers in ZIF-8 by fixed bed adsorption . Ind. Eng. Chem. Res. , 2019 . 58 378 - 394 . DOI: 10.1021/acs.iecr.8b05126 http://doi.org/10.1021/acs.iecr.8b05126 .
Li, T.; Ma, S.; Yang, H.; Xu, Z. L . Preparation of carbonized MOF/MgCl 2 hybrid products as dye adsorbent and supercapacitor: morphology evolution and Mg salt effect . Ind. Eng. Chem. Res. , 2019 . 58 1601 - 1612 . DOI: 10.1021/acs.iecr.8b06437 http://doi.org/10.1021/acs.iecr.8b06437 .
Otun, K. O.; Liu, X.; Hildebrandt, D . Metal-organic framework (MOF)-derived catalysts for Fischer-Tropsch synthesis: recent progress and future perspectives . J. Energy Chem. , 2020 . 51 230 - 245 . DOI: 10.1016/j.jechem.2020.03.062 http://doi.org/10.1016/j.jechem.2020.03.062 .
Kirchon, A.; Feng, L.; Drake, H. F.; Joseph, E. A.; Zhou, H. C . From fundamentals to applications: a toolbox for robust and multifunctional MOF materials . Chem. Soc. Rev. , 2018 . 47 8611 - 8638 . DOI: 10.1039/C8CS00688A http://doi.org/10.1039/C8CS00688A .
Li, T.; Jia, X. X.; Li, J. P . Tuning the pore environment of MOFs toward efficient CH 4 /N 2 separation under humid conditions . ACS Appl. Mater. Interfaces , 2022 . 14 15830 - 15839 . DOI: 10.1021/acsami.2c01156 http://doi.org/10.1021/acsami.2c01156 .
Campbell, J.; Davies, R. P.; Braddock, D. C.; Livingston, A. G . Improving the permeance of hybrid polymer/metal–organic framework (MOF) membranes for organic solvent nanofiltration (OSN)—development of MOF thin films via interfacial synthesis . J. Mater. Chem. A , 2015 . 3 9668 - 9674 . DOI: 10.1039/C5TA01315A http://doi.org/10.1039/C5TA01315A .
Wang, Z.; Liu, L. Y.; Li, Z.; Goyal, N.; Du, T.; He, J. X.; Li, G. K . Shaping of Metal-organic frameworks: a review . Energy Fuels , 2022 . 36 2927 - 2944 . DOI: 10.1021/acs.energyfuels.1c03426 http://doi.org/10.1021/acs.energyfuels.1c03426 .
Lin, R. B.; Xiang, S. C.; Lin, B.; Cui, Y. J.; Qian, G. D.; Zhou, W.; Chen, B. L . Our journey of developing multifunctional metal-organic frameworks . Coord. Chem. Rev. , 2019 . 384 21 - 36 . DOI: 10.1016/j.ccr.2019.01.009 http://doi.org/10.1016/j.ccr.2019.01.009 .
Li, C.; Li, N.; Chang, L. M.; Gu, Z. G.; Zhang, J . Research progresses of metal-organic framework HKUST-1-based membranes in gas separations . Acta Chim. Sinica , 2022 . 80 340 - 358 . DOI: 10.6023/A21120545 http://doi.org/10.6023/A21120545 .
Xu, K.; Zhan, C.Y.; Zhao, W.; Yu, X.; Zhu, Q.; Yang, L . Tunable resistance of MOFs films via an anion exchange strategy for advanced gas sensing . J. Hazard. Mater. , 2021 . 416 125906 DOI: 10.1016/j.jhazmat.2021.125906 http://doi.org/10.1016/j.jhazmat.2021.125906 .
Yuan, J. W.; Hung, W. S.; Zhu, H. P.; Guan, K. C.; Ji, Y. F.; Mao, Y. Y.; Liu, G. P.; Lee, K. R.; Jin, W. Q . Fabrication of ZIF-300 membrane and its application for efficient removal of heavy metal ions from wastewater . J. Membr. Sci. , 2019 . 572 20 - 27 . DOI: 10.1016/j.memsci.2018.10.080 http://doi.org/10.1016/j.memsci.2018.10.080 .
Wan, L. L.; Chen, Z.; Xu, K.; Feng, B.; Huang, A.S . Synthesis of highly stable UiO-66-NH 2 membranes with high ions rejection for seawater desalination . Microporous Mesoporous Mater. , 2017 . 252 207 - 213 . DOI: 10.1016/j.micromeso.2017.06.025 http://doi.org/10.1016/j.micromeso.2017.06.025 .
Cui, X. L.; Kong, G. D.; Feng, Y.; Li, L. T.; Fan, W. D.; Pang, J.; Fan, L. L.; Wang, R. M.; Guo, H. L.; Kang, Z. X.; Sun, D. F . Interfacial polymerization of MOF “monomers” to fabricate flexible and thin membranes for molecular separation with ultrafast water transport . J. Mater. Chem. A , 2021 . 9 17528 - 17537 . DOI: 10.1039/d1ta04049a http://doi.org/10.1039/d1ta04049a .
Ma, D. C.; Han, G.; Gao, Z. F.; Chen, S. B . Continuous UiO-66-type metal-organic framework thin film on polymeric support for organic solvent nanofiltration . ACS Appl. Mater. Interfaces , 2019 . 11 45290 - 45300 . DOI: 10.1021/acsami.9b16332 http://doi.org/10.1021/acsami.9b16332 .
Yao, J. F.; Dong, D. H.; Li, D.; He, L.; Xu, G. S.; Wang H. T . Contra-diffusion synthesis of ZIF-8 films on a polymer substrate . Chem. Commun. , 2011 . 47 2559 - 2561 . DOI: 10.1039/c0cc04734a http://doi.org/10.1039/c0cc04734a .
He, M.; Yao, J. F.; Li, L. X.; Zhong, Z. X.; Chen, F. Y.; Wang, H. T . Aqueous solution synthesis of ZIF-8 films on a porous nylon substrate by contra-diffusion method . Microporous Mesoporous Mater. , 2013 . 179 10 - 16 . DOI: 10.1016/j.micromeso.2013.05.015 http://doi.org/10.1016/j.micromeso.2013.05.015 .
Ahmadijokani, F.; Molavi, H.; Rezakazemi, M.; Tajahmadi, S.; Bahi, A.; Ko, F.; Aminabhavi, T. M.; Li, J. R.; Arjmand, M . UiO-66 metal-organic frameworks in water treatment: a critical review . Prog. Mater. Sci. , 2022 . 125 100904 .
Ma, Q. Y.; Dong, R.; Liu, H.; Zhu, A. Q.; Qiao, L. L.; Ma, Y. J.; Wang, J.; Xie, J. P.; Pan, J . Prussian blue analogue-derived Mn-Fe oxide nanocubes with controllable crystal structure and crystallinity as highly efficient OER electrocatalysts . J. Alloys Compd. , 2020 . 820 153438 DOI: 10.1016/j.jallcom.2019.153438 http://doi.org/10.1016/j.jallcom.2019.153438 .
Liu, X.; Wang, W.; Lin, H. B.; Shen, Y.; Fang, Q. L.; liu, F . Construction of hierarchical Prussian blue microcrystal with high sunlight absorption for efficient photo-thermal degradation of organic pollutants . Sep. Purif. Technol. , 2021 . 269 118724 DOI: 10.1016/j.seppur.2021.118724 http://doi.org/10.1016/j.seppur.2021.118724 .
Huang, J. Z.; Xu, P.; Gao, T. L.; Huangfu, J. S.; Wang, X. J.; Liu, S. W.; Zhang, Y. M.; Song, B . Controlled synthesis of hollow bimetallic Prussian blue analog for conversion into efficient oxygen evolution electrocatalyst . ACS Sustain. Chem. Eng. , 2020 . 8 1319 - 1328 . DOI: 10.1021/acssuschemeng.9b07122 http://doi.org/10.1021/acssuschemeng.9b07122 .
Qiang, R.; Du, Y. C.; Zhao, H. T.; Wang, Y.;Tian, C. H.; Li, Z. G.; Han, X. J.; Xu, P . Metal organic framework-derived Fe/C nanocubes toward efficient microwave absorption . J. Mater. Chem. A , 2015 . 3 13426 - 13434 . DOI: 10.1039/C5TA01457C http://doi.org/10.1039/C5TA01457C .
Wang, Q. Q.; Wang, N.; He, S. F.; Zhao, J. H.; Fang, J.; Shen, W. G . Simple synthesis of prussian blue analogues in room temperature ionic liquid solution and their catalytic application in epoxidation of styrene . Dalton Trans. , 2015 . 44 12878 - 12883 . DOI: 10.1039/C5DT01762A http://doi.org/10.1039/C5DT01762A .
Berrettoni, M.; Giorgetti, M.; Zamponi, S.; Conti, P.; Ranganathan, D.; Zanotto, A.; Saladino, M. L.; Caponetti, E . Synthesis and characterization of nanostructured cobalt hexacyanoferrate . J. Phys. Chem. C , 2010 . 114 6401 - 6407 . DOI: 10.1021/jp100367p http://doi.org/10.1021/jp100367p .
Feng, Y.; Yu, X. Y.; Paik, U . Formation of Co 3 O 4 microframes from MOFs with enhanced electrochemical performance for lithium storage and water oxidation . Chem. Commun. , 2016 . 52 6269 - 6272 . DOI: 10.1039/C6CC02093C http://doi.org/10.1039/C6CC02093C .
Hu, M.; Furukawa, S.; Ohtani, R.; Sukegawa, H.; Nemoto, Y.; Reboul, J.; Kitagawa, S.; Yamauchi, Y . Synthesis of Prussian blue nanoparticles with a hollow interior by controlled chemical etching . Angew. Chem. , 2012 . 51 984 - 988 . DOI: 10.1002/anie.201105190 http://doi.org/10.1002/anie.201105190 .
Liu, C. L.; Mao, H. C.; Zheng, J. F.; Zhang, S. B . Tight ultrafiltration membrane: Preparation and characterization of thermally resistant carboxylated cardo poly(arylene ether ketone)s (PAEK-COOH) tight ultrafiltration membrane for dye removal . J. Membr. Sci. , 2017 . 530 1 - 10 . DOI: 10.1016/j.memsci.2017.02.005 http://doi.org/10.1016/j.memsci.2017.02.005 .
Liu, H. Q.; Chen, Y. B.; Zhang, K.; Wang, C. F.; Hu, X. Y.; Cheng, B. W.; Zhang, Y. F . Poly(vinylidene fluoride) hollow fiber membrane for high-efficiency separation of dyes-salts . J. Membr. Sci. , 2019 . 578 43 - 52 . DOI: 10.1016/j.memsci.2019.02.029 http://doi.org/10.1016/j.memsci.2019.02.029 .
Sun, L.; Li, Z. L.; Li, Z.; Hu, Y.; Chen, C.; Yang, C. H.; Du, B. S.; Sun, Y.; Besenbacher, F.; Yu, M . Design and mechanism of core-shell TiO 2 nanoparticles as a high-performance photothermal agent . Nanoscale , 2017 . 9 16183 - 16192 . DOI: 10.1039/C7NR02848B http://doi.org/10.1039/C7NR02848B .
Gao, M. M.; Zhu, L. L.; Peh, C. K.; Ho, G. W . Solar absorber material and system designs for photothermal water vaporization towards clean water and energy production . Energy Environ. Sci. , 2019 . 12 841 - 864 . DOI: 10.1039/C8EE01146J http://doi.org/10.1039/C8EE01146J .
Huang, G. X.; Wang, C. Y.; Yang, C. W.; Guo, P. C.; Yu, H. Q . Degradation of Bisphenol A by peroxymonosulfate catalytically activated with Mn 1.8 Fe 1.2 O 4 nanospheres: synergism between Mn and Fe . Environ. Sci. Technol. , 2017 . 51 12611 - 12618 . DOI: 10.1021/acs.est.7b03007 http://doi.org/10.1021/acs.est.7b03007 .
Zhang, H. X.; Li, C. W.; Lyu, L.; Hu, C . Surface oxygen vacancy inducing peroxymonosulfate activation through electron donation of pollutants over cobalt-zinc ferrite for water purification . Appl. Catal. B , 2020 . 270 118874 DOI: 10.1016/j.apcatb.2020.118874 http://doi.org/10.1016/j.apcatb.2020.118874 .
Lu, N.; Lin, H. B.; Li, G. L.; Wang, J. Q.; Han, Q.; Liu, F . ZIF-67 derived nanofibrous catalytic membranes for ultrafast removal of antibiotics under flow-through filtration via non-radical dominated pathway . J. Membr. Sci. , 2021 . 639 119782 DOI: 10.1016/j.memsci.2021.119782 http://doi.org/10.1016/j.memsci.2021.119782 .
Yamashita, T.; Hayes, P . Analysis of XPS spectra of Fe 2+ and Fe 3+ ions in oxide materials . Appl. Surf. Sci. , 2008 . 254 2441 - 2449 . DOI: 10.1016/j.apsusc.2007.09.063 http://doi.org/10.1016/j.apsusc.2007.09.063 .
Huang, Q. Q.; Zhang, J. Y.; He, Z. Y.; Shi, P. H.; Qin, X.; Yao, W. F . Direct fabrication of lamellar selfsupporting Co 3 O 4 /N/C peroxymonosulfate activation catalysts for effective aniline degradation . Chem. Eng. J. , 2017 . 313 1088 - 1098 . DOI: 10.1016/j.cej.2016.11.002 http://doi.org/10.1016/j.cej.2016.11.002 .
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