Controlled Ring-opening (Co)Polymerization of Renewable Macrolactones by Al-based Catalysts with Different Sidearms

Wu-Chao Zhao; Jing Yuan; Jiang-Hua He; Yue-Tao Zhang

doi:10.1007/s10118-023-2947-x

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Controlled Ring-opening (Co)Polymerization of Renewable Macrolactones by Al-based Catalysts with Different Sidearms

RESEARCH ARTICLE | Updated：2023-11-10

- Controlled Ring-opening (Co)Polymerization of Renewable Macrolactones by Al-based Catalysts with Different Sidearms
- Controlled Ring-opening (Co)Polymerization of Renewable Macrolactones by Al-based Catalysts with Different Sidearms
- 高分子科学（英文版） 2023年41卷第11期页码：1706-1713
- Affiliations：
  
  State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China
- Author bio：
  
  hjh2015@jlu.edu.cn (J.H.H.)
  ytzhang2009@jlu.edu.cn (Y.T.Z.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 22225104, 22071077, 21871107 and 21975102) and China Postdoctoral Science Foundation (Nos. 2022TQ0115 and 2022M711297).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-2947-x.
- DOI：10.1007/s10118-023-2947-x
  中图分类号：
- 收稿：2022-12-14，
  
  修回：2023-1-4，
  
  录用：2023-1-5，
  
  网络首发：2023-03-10，
  
  纸质出版：2023-11-01
- Accepted：
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Zhao, W. C.; Yuan, J.; He, J. H.; Zhang, Y. T. Controlled ring-opening (co)polymerization of renewable macrolactones by Al-based catalysts with different sidearms. Chinese J. Polym. Sci. 2023, 41, 1706–1713

Wu-Chao Zhao, Jing Yuan, Jiang-Hua He, et al. Controlled Ring-opening (Co)Polymerization of Renewable Macrolactones by Al-based Catalysts with Different Sidearms[J]. Chinese Journal of Polymer Science, 2023, 41(11): 1706-1713.
Zhao, W. C.; Yuan, J.; He, J. H.; Zhang, Y. T. Controlled ring-opening (co)polymerization of renewable macrolactones by Al-based catalysts with different sidearms. Chinese J. Polym. Sci. 2023, 41, 1706–1713 DOI： 10.1007/s10118-023-2947-x.

Wu-Chao Zhao, Jing Yuan, Jiang-Hua He, et al. Controlled Ring-opening (Co)Polymerization of Renewable Macrolactones by Al-based Catalysts with Different Sidearms[J]. Chinese Journal of Polymer Science, 2023, 41(11): 1706-1713. DOI： 10.1007/s10118-023-2947-x.

摘要

Four

-based complexes with different sidearms were prepared and applied for controlled polymerization of pentadecalactone (PDL) furnishing polyesters with

high up to 90.3 kg/mol. Well-defined block copolyesters and random copolyesters with tailored

has also been obtained by copolymerizing PDL with small-lactones with controlling the polymerization condition.

Abstract

It remains a challenging task to achieve ring-opening (co)polymerization (ROP) of macrolactones. Hence

we synthesized a series of

-based catalysts and systemically investigated the effect of N-containing substituent on the sidearms on ROP of macrolactones.

Al3

possessing

-methyl group could effectively achieve controlled ROP of pentadecalactone (PDL) and macro(di)lactone ethylene brassylate (EB) in combination with BnOH

furnishing polyethylene-like PPDL and PEB with

up to 90.3 and 321 kg/mol

respectively. Random copolymerization of PDL and small-ring lactones

-caprolactone (

-CL) and

-valerolactone (

-VL) could prepare random copolyesters with tailored

in the range of 57−94 °C by controlling the ratios of PDL and

-CL

-VL. More importantly

well-defined block copolyesters could be obtained by sequential adding PDL and

-CL

-VL

which have been proved by GPC-MALLS

DSC and

C-NMR.

关键词

Keywords

references

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