A Multi-model, Large-range Flexible Strain Sensor Based on Carbonized Silk Habotai for Human Health Monitoring

Shi-Dong Ma; Yu-Ting Wu; Jian Tang; Yu-Min Zhang; Tao Yan; Zhi-Juan Pan

doi:10.1007/s10118-023-2924-4

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A Multi-model, Large-range Flexible Strain Sensor Based on Carbonized Silk Habotai for Human Health Monitoring

RESEARCH ARTICLE | Updated：2023-07-18

- A Multi-model, Large-range Flexible Strain Sensor Based on Carbonized Silk Habotai for Human Health Monitoring
- A Multi-model, Large-range Flexible Strain Sensor Based on Carbonized Silk Habotai for Human Health Monitoring
- 高分子科学（英文版） 2023年41卷第8期页码：1238-1249
- Affiliations：
  
  a.College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, China
  b.National Engineering Laboratory for Modern Silk, Suzhou 215123, China
- Author bio：
  
  yantao@suda.edu.cn (T.Y.)
  zhjpan@suda.edu.cn (Z.J.P)
- Funds：
  
  This work was financially supported in part by the Jiangsu Provincial Key Research and Development Program (No. BE2019045); in part by the Third-Priority Academic Program Development of Jiangsu Higher Education Institutions; in part by the Opening Project of National Engineering Laboratory for Modern Silk, Soochow University (No. SDGC2245); in part by the Postgraduate Research & Practice Innovation Program of Jiangsu Province (No. KYCX21_2958); and Qing Lan Project.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-2924-4.
- DOI：10.1007/s10118-023-2924-4
  中图分类号：
- 收稿：2022-11-07，
  
  修回：2022-12-6，
  
  录用：2022-12-7，
  
  网络首发：2023-02-10，
  
  纸质出版：2023-08-01
- Accepted：
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Ma, S. D.; Wu, Y. T.; Tang, J.; Zhang, Y. M.; Yan, T.; Pan, Z. J. A multi-model, large-range flexible strain sensor based on carbonized silk habotai for human health monitoring. Chinese J. Polym. Sci. 2023, 41, 1238–1249

Shi-Dong Ma, Yu-Ting Wu, Jian Tang, et al. A Multi-model, Large-range Flexible Strain Sensor Based on Carbonized Silk Habotai for Human Health Monitoring[J]. Chinese Journal of Polymer Science, 2023, 41(8): 1238-1249.
Ma, S. D.; Wu, Y. T.; Tang, J.; Zhang, Y. M.; Yan, T.; Pan, Z. J. A multi-model, large-range flexible strain sensor based on carbonized silk habotai for human health monitoring. Chinese J. Polym. Sci. 2023, 41, 1238–1249 DOI： 10.1007/s10118-023-2924-4.

Shi-Dong Ma, Yu-Ting Wu, Jian Tang, et al. A Multi-model, Large-range Flexible Strain Sensor Based on Carbonized Silk Habotai for Human Health Monitoring[J]. Chinese Journal of Polymer Science, 2023, 41(8): 1238-1249. DOI： 10.1007/s10118-023-2924-4.

摘要

Abstract

In recent years

flexible strain sensors have received considerable attention owing to their excellent flexibility and multifunctionality. However

it is still a great challenge for them to accurately monitor multi-model deformations with high sensitivity and linearity. In this study

the industrial insulating silk habotai was successfully converted into carbonized silk habotai (CSH) for use in strain sensors. A strain sensor created using CSH exhibited excellent sensing performance under multi-model deformations

including stretching

twist and bending. The maximum tensile strain was 434%. The gauge factors were 14.6 in the wide tensile range of 0%–400% with a high linearity of 0.959. In addition

the CSH strain sensor exhibited an extremely fast response time (110 ms) and could accurately detect bending (0°–180°) and torsional (0°–180°) strains. High durability and repeatability were observed for the multi-model strains. Finally

a new type of smart pillow was developed to accurately record head movement and breathing during sleep. The sensor may also be used for auxiliary training in table tennis. The proposed CSH strain sensor has shown great potential for applications in smart devices and human-machine interactions.

关键词

Keywords

references

Amjadi,M.;Kyung,K.U.;Park,I.;Sitti,M.Stretchable,skin-mountable,andwearablestrainsensorsandtheirpotentialapplications:areview. Adv. Funct. Mater. 2016 , 26 ,1678−1698..

Wu,Y.T.;Yan,T.;Pan,Z.J.Wearablecarbon-basedresistivesensorsforstraindetection:areview. IEEE Sens. J. 2021 , 21 ,4030−4043..

Goldoni,R.;Ozkan-Aydin,Y.;Kim,Y.S.;Kim,J.;Zavanelli,N.;Mahmood,M.;Liu,B.;Hammond,F.L.,3rd;Goldman,D.I.;Yeo,W.H.Stretchablenanocompositesensors,nanomembraneinterconnectors,andwirelesselectronicstowardfeedback-loopcontrolofasoftearthwormrobot. ACS Appl. Mater. Interfaces 2020 , 12 ,43388−43397..

Zhang,M.;Wang,C.;Wang,Q.;Jian,M.;Zhang,Y.Sheath-coregraphite/silkfibermadebydry-meyer-rod-coatingforwearablestrainsensors. ACS Appl. Mater. Interfaces 2016 , 8 ,20894−20899..

Hang,C.Z.;Zhao,X.F.;Xi,S.Y.;Shang,Y.H.;Yuan,K.P.;Yang,F.;Wang,Q.G.;Wang,J.C.;Zhang,D.W.;Lu,H.L.Highlystretchableandself-healingstrainsensorsformotiondetectioninwirelesshuman-machineinterface. Nano Energy 2020 , 76 ,105064..

Tian,H.;Shu,Y.;Cui,Y.L.;Mi,W.T.;Yang,Y.;Xie,D.;Ren,T.L.Scalablefabricationofhigh-performanceandflexiblegraphenestrainsensors. Nanoscale 2014 , 6 ,699−705..

Yan,T.;Wu,Y.;Pan,Z.Anisotropyofresistance-typestrainsensingnetworksbasedonalignedcarbonnanofibermembrane. J Mater. Sci. 2021 , 56 ,6292−6305..

Zhao,M.;Li,D.;Huang,J.;Wang,D.;Mensah,A.;Wei,Q.Amultifunctionalandhighlystretchableelectronicdevicebasedonsilvernanowire/wrapyarncompositeforawearablestrainsensorandheater. J. Mater. Chem. C 2019 , 7 ,13468−13476..

Zhang,J.;Wan,L.;Gao,Y.;Fang,X.;Lu,T.;Pan,L.;Xuan,F.Highlystretchableandself-healablemxene/polyvinylalcoholhydrogelelectrodeforwearablecapacitiveelectronicskin. Adv. Electron. Mater. 2019 , 5 ,1900285..

Cai,L.;Song,L.;Luan,P.;Zhang,Q.;Zhang,N.;Gao,Q.;Zhao,D.;Zhang,X.;Tu,M.;Yang,F.;Zhou,W.;Fan,Q.;Luo,J.;Zhou,W.;Ajayan,P.M.;Xie,S.Super-stretchable,transparentcarbonnanotube-basedcapacitivestrainsensorsforhumanmotiondetection. Sci. Rep. 2013 , 3 ,3048..

Yang,J.C.;Kim,J.O.;Oh,J.;Kwon,S.Y.;Sim,J.Y.;Kim,D.W.;Choi,H.B.;Park,S.Microstructuredporouspyramid-basedultrahighsensitivepressuresensorinsensitivetostrainandtemperature. ACS Appl. Mater. Interfaces 2019 , 11 ,19472−19480..

Liu,Y.;Hu,Y.;Zhao,J.;Wu,G.;Tao,X.;Chen,W.Self-poweredpiezoionicstrainsensortowardthemonitoringofhumanactivities. Small 2016 , 12 ,5074−5080..

Qian,S.;Qin,L.;He,J.;Zhang,N.;Qian,J.;Mu,J.;Geng,W.;Hou,X.;Chou,X.Alead-freestretchablepiezoelectriccompositeforhumanmotionmonitoring. Mater. Lett. 2020 , 261 ,127119..

Meng,B.;Tang,W.;Too,Z.H.;Zhang,X.;Han,M.;Liu,W.;Zhang,H.Atransparentsingle-friction-surfacetriboelectricgeneratorandself-poweredtouchsensor. Energy Environ. Sci. 2013 , 6 ,3235−3240..

Wang,S.H.;Lin,L.;Wang,Z.L.Triboelectricnanogeneratorsasself-poweredactivesensors. Nano Energy 2015 , 11 ,436−462..

Gao,Y.;Guo,F.;Cao,P.;Liu,J.;Li,D.;Wu,J.;Wang,N.;Su,Y.;Zhao,Y.Winding-lockedcarbonnanotubes/polymernanofibershelicalyarnforultrastretchableconductorandstrainsensor. ACS Nano 2020 , 14 ,3442−3450..

Ding,L.;Xuan,S.;Feng,J.;Gong,X.Magnetic/conductivecompositefiber:amultifunctionalstrainsensorwithmagneticallydrivenproperty. Compos. Part A 2017 , 100 ,97−105..

Tang,J.;Wu,Y.;Ma,S.;Yan,T.;Pan,Z.FlexiblestrainsensorbasedonCNT/TPUcompositenanofiberyarnforsmartsportsbandage. Compos. Part B Eng. 2022 , 232 ,109605..

Ma,S.D.;Tang,J.;Yan,T.;Pan,Z.J.Performanceofflexiblestrainsensorswithdifferenttransitionmechanisms:areview. IEEE Sens. J. 2022 , 22 ,7475−7498..

Tang,J.;Wu,Y.;Ma,S.;Yan,T.;Pan,Z.Strain-sensingcompositenanofiberfilamentandregulationmechanismofshoulderpeaksbasedoncarbonnanomaterialdispersion. ACS Appl. Mater. Interfaces 2023 , 15 ,7329−7404..

Wu,Y.;Yan,T.;Zhang,K.;Pan,Z.Ahollowcore-sheathcompositefiberbasedonpolyaniline/polyurethane:preparation,properties,andmulti-modelstrainsensingperformance. Adv. Mater. Technol. 2023 , 8 ,2200777..

Park,J.J.;Hyun,W.J.;Mun,S.C.;Park,Y.T.;Park,O.O.Highlystretchableandwearablegraphenestrainsensorswithcontrollablesensitivityforhumanmotionmonitoring. ACS Appl. Mater. Interfaces 2015 , 7 ,6317−6324..

Cai,Y.;Shen,J.;Ge,G.;Zhang,Y.;Jin,W.;Huang,W.;Shao,J.;Yang,J.;Dong,X.StretchableTi 3 C 2 T x MXene/carbonnanotubecompositebasedstrainsensorwithultrahighsensitivityandtunablesensingrange. ACS Nano 2018 , 12 ,56−62..

Yee,M.J.;Mubarak,N.M.;Abdullah,E.C.;Khalid,M.;Walvekar,R.;Karri,R.R.;Nizamuddin,S.;Numan,A.Carbonnanomaterialsbasedfilmsforstrainsensingapplication-areview. Nano-Struct. Nano-Object 2019 , 18 ,100312..

Huang,J.;Li,D.;Zhao,M.;Mensah,A.;Lv,P.;Tian,X.;Huang,F.;Ke,H.;Wei,Q.HighlysensitiveandstretchableCNT-bridgedAgNPstrainsensorbasedonTPUelectrospunmembraneforhumanmotiondetection. Adv. Electron. Mater. 2019 , 1900241 ,5..

Sang,S.;Liu,L.;Jian,A.;Duan,Q.;Ji,J.;Zhang,Q.;Zhang,W.Highlysensitivewearablestrainsensorbasedonsilvernanowiresandnanoparticles. Nanotechnology 2018 , 29 ,255202..

Li,M.;Li,H.;Zhong,W.;Zhao,Q.;Wang,D.Stretchableconductivepolypyrrole/polyurethane(PPy/PU)strainsensorwithnetlikemicrocracksforhumanbreathdetection. ACS Appl. Mater. Interfaces 2014 , 6 ,1313−1319..

Gong,X.X.;Fei,G.T.;Fu,W.B.;Fang,M.;Gao,X.D.;Zhong,B.N.;Zhang,L.D.FlexiblestrainsensorwithhighperformancebasedonPANI/PDMSfilms. Org. Electron. 2017 , 47 ,51−56..

Jia,Y.;Shen,L.;Liu,J.;Zhou,W.;Du,Y.;Xu,J.;Liu,C.;Zhang,G.;Zhang,Z.;Jiang,F.AnefficientPEDOT-coatedtextileforwearablethermoelectricgeneratorsandstrainsensors. J. Mater. Chem. C 2019 , 7 ,3496−3502..

TranQuang,T.;Lee,N.E.Flexibleandstretchablephysicalsensorintegratedplatformsforwearablehuman-activitymonitoringandpersonalhealthcare. Adv. Mater. 2016 , 28 ,4338−4372..

Tang,J.;Wu,Y.;Ma,S.;Yan,T.;Pan,Z.Sensingmechanismofaflexiblestrainsensordevelopeddirectlyusingelectrospuncompositenanofiberyarnwithternarycarbonnanomaterials. iScience 2022 , 25 ,105162..

Ma,D.L.;Ma,Y.;Chen,Z.W.;Hu,A.M.Asilkfabricderivedcarbonfibrenetfortransparentcapacitivetouchpadsandall-solidsupercapacitors. J. Mater. Chem. A 2017 , 5 ,20608−20614..

Pan,P.;Hu,Y.;Wu,K.;Cheng,Z.;Shen,Z.;Jiang,L.;Mao,J.;Ni,C.;Ge,Y.;Wang,Z.GrowthofZnCo 2 O 4 nanocubesonflexiblebiocharsubstratederivedfromnaturalsilkwastefabricforlithium-ionbatteryanode. J. Alloys. Compd. 2020 , 814 ,152306..

Li,X.;Zhao,J.;Cai,Z.;Ge,F.Free-standingcarbonelectrodematerialswiththree-dimensionalhierarchicallyporousstructurederivedfromwastedyedsilkfabrics. Mater. Res. Bull. 2018 , 107 ,355−360..

Li,X.;Sun,C.;Cai,Z.;Ge,F.High-performanceall-solid-statesupercapacitorderivedfromPPycoatedcarbonizedsilkfabric. Appl. Surf. Sci. 2019 , 473 ,967−975..

Chen,C.;Ran,R.;Yang,Z.;Lv,R.;Shen,W.;Kang,F.;Huang,Z.H.Anefficientflexibleelectrochemicalglucosesensorbasedoncarbonnanotubes/carbonizedsilkfabricsdecoratedwithPtmicrospheres. Sens. Actuators B 2018 , 256 ,63−70..

Ji,W.;Wu,D.;Tang,W.;Xi,X.;Su,Y.;Guo,X.;Liu,R.Carbonizedsilkfabric-basedflexibleorganicelectrochemicaltransistorsforhighlysensitiveandselectivedopaminedetection. Sens. Actuators B 2020 , 304 ,127414..

Martel,A.;Burghammer,M.;Davies,R.J.;Riekel,C.Thermalbehaviorofbombyxmorisilk:evolutionofcrystallineparameters,molecularstructure,andmechanicalproperties. Biomacromolecules 2007 , 8 ,3548−3556..

Xiong,X.;Tang,Y.;Xu,C.;Huang,Y.;Wang,Y.;Fu,L.;Lin,C.;Zhou,D.;Lin,Y.Highcarbonizationtemperaturetotriggerenzymemimickingactivitiesofsilk-derivednanosheets. Small 2020 , 16 ,e2004129..

Li,X.;Zhao,J.;Cai,Z.;Ge,F.Adyeing-inducedheteroatom-co-dopedroutetowardflexiblecarbonelectrodederivedfromsilkfabric. J. Mater. Sci. 2018 , 53 ,7735−7743..

Hu,M.;Hu,T.;Cheng,R.;Yang,J.;Cui,C.;Zhang,C.;Wang,X.MXene-coatedsilk-derivedcarbonclothtowardflexibleelectrodeforsupercapacitorapplication. J. Energy Chem. 2018 , 27 ,161−166..

Huang,P.;Yu,X.G.;Li,Y.Q.;Fu,Y.F.;Gan,D.M.;Taha,T.;Fu,Y.Q.;Hu,N.;Fu,S.Y.Architecturaldesignofflexibleanisotropicpiezoresistivecompositeformultiple-loadingrecognization. Compos. B. Eng. 2020 , 182 ,107631..

Deng,C.;Pan,L.;Cui,R.;Li,C.;Qin,J.Wearablestrainsensormadeofcarbonizedcottoncloth. J. Mater. Sci.: Mater. Electron. 2016 , 28 ,3535−3541..

Liu,Z.;Chen,K.;Fernando,A.;Gao,Y.;Li,G.;Jin,L.;Zhai,H.;Yi,Y.;Xu,L.;Zheng,Y.;Li,H.;Fan,Y.;Li,Y.;Zheng,Z.Permeablegraphitedhempfabrics-based,wearing-comfortablepressuresensorsformonitoringhumanactivities. Chem. Eng. J. 2021 , 403 ,126191..

Liang,J.J.;Zhao,Z.B.;Tang,Y.C.;Liang,Z.H.;Sun,L.L.;Pan,X.;Wang,X.Z.;Qiu,J.S.Awearablestrainsensorbasedoncarbonderivedfromlinenfabrics. New Carbon Mater. 2020 , 35 ,522−530..

Wang,C.;Zhang,M.;Xia,K.;Gong,X.;Wang,H.;Yin,Z.;Guan,B.;Zhang,Y.Intrinsicallystretchableandconductivetextilebyascalableprocessforelasticwearableelectronics. ACS Appl. Mater. Interfaces 2017 , 9 ,13331−13338..

Zhang,M.;Wang,C.;Wang,H.;Jian,M.;Hao,X.;Zhang,Y.Carbonizedcottonfabricforhigh-performancewearablestrainsensors. Adv. Funct. Mater. 2017 , 27 ,1604795..

Yan,T.;Zhou,H.;Niu,H.;Shao,H.;Wang,H.;Pan,Z.;Lin,T.Highlysensitivedetectionofsubtlemovementusingaflexiblestrainsensorfromhelicallywrappedcarbonyarns. J. Mater. Chem. C 2019 , 7 ,10049−10058..

Wang,C.;Xia,K.;Jian,M.;Wang,H.;Zhang,M.;Zhang,Y.Carbonizedsilkgeorgetteasanultrasensitivewearablestrainsensorforfull-rangehumanactivitymonitoring. J. Mater. Chem. C 2017 , 5 ,7604−7611..

Wang,C.;Li,X.;Gao,E.;Jian,M.;Xia,K.;Wang,Q.;Xu,Z.;Ren,T.;Zhang,Y.Carbonizedsilkfabricforultrastretchable,highlysensitive,andwearablestrainsensors. Adv. Mater. 2016 , 28 ,6640−6648..

Chen,Z.;Yan,T.;Pan,Z.Reviewofflexiblestrainsensorsbasedoncellulosecompositesformulti-facetedapplications. Cellulose 2021 , 28 ,615−645..

Rousseau,M.E.;Lefevre,T.;Beaulieu,L.;Asakura,T.;Pezolet,M.StudyofProteinconformationandorientationinsilkwormandspidersilkfibersusingRamanmicrospectroscopy. Biomacromolecules 2004 , 5 ,2247−2257..

Belin,T.;Epron,F.Characterizationmethodsofcarbonnanotubes:areview. J. Mater. Sci. Eng. B 2005 , 119 ,105−118..

Atchudan,R.;Edison,T.N.J.I.;Chakradhar,D.;Perumal,S.;Shim,J.J.;Lee,Y.R.Facilegreensynthesisofnitrogen-dopedcarbondotsusingchionanthusretususfruitextractandinvestigationoftheirsuitabilityformetalionsensingandbiologicalapplications. Sens. Actuators B 2017 , 246 ,497−509..

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