Regioregular Asymmetric Diketopyrrolopyrrole Copolymers with Good Molecular Ordered Assembly Ability for High-performance Polymer Transistors

Qing-Qing Liu; Jia-Xin Yang; Man Zhao; Can Gao; Bo Guan; Huan-Li Dong

doi:10.1007/s10118-023-2918-2

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Regioregular Asymmetric Diketopyrrolopyrrole Copolymers with Good Molecular Ordered Assembly Ability for High-performance Polymer Transistors

RESEARCH ARTICLE | Updated：2023-07-18

- Regioregular Asymmetric Diketopyrrolopyrrole Copolymers with Good Molecular Ordered Assembly Ability for High-performance Polymer Transistors
- Regioregular Asymmetric Diketopyrrolopyrrole Copolymers with Good Molecular Ordered Assembly Ability for High-performance Polymer Transistors
- 高分子科学（英文版） 2023年41卷第8期页码：1215-1222
- Affiliations：
  
  a.Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  b.School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
- Author bio：
  
  cangao@iccas.ac.cn (C.G.)
  guanbo@iccas.ac.cn (B.G.)
  dhl522@iccas.ac.cn (H.L.D.)
- Funds：
  
  This work was financially supported by the Ministry of Science and Technology of China (Nos. 2018YFA0703200 and 2022YFB3603800), the National Natural Science Foundation of China (Nos. 21875259, 52233010, 51725304, 61890943, 52103245 and 22021002), the CAS Project for Young Scientists in Basic Research (No. YSBR-053), the Youth Innovation Promotion Association of the Chinese Academy of Sciences, the National Program for Support of Top-notch Young Professionals, the Beijing National Laboratory for Molecular Sciences (No. BNLMS-CXXM-202012), and the Key Research Program of the Chinese Academy of Sciences (Nos. XDPB13 and 121111KYSB20200004).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-2918-2.
- DOI：10.1007/s10118-023-2918-2
  中图分类号： M
- 收稿：2022-10-28，
  
  修回：2022-11-27，
  
  录用：2022-12-1，
  
  网络首发：2023-02-01，
  
  纸质出版：2023-08-01
- Accepted：
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Liu, Q. Q.; Yang, J. X.; Zhao, M.; Gao, C.; Guan, B.; Dong, H. L. Regioregular asymmetric diketopyrrolopyrrole copolymers with good molecular ordered assembly ability for high-performance polymer transistors. Chinese J. Polym. Sci. 2023, 41, 1215–1222

Qing-Qing Liu, Jia-Xin Yang, Man Zhao, et al. Regioregular Asymmetric Diketopyrrolopyrrole Copolymers with Good Molecular Ordered Assembly Ability for High-performance Polymer Transistors[J]. Chinese Journal of Polymer Science, 2023, 41(8): 1215-1222.
Liu, Q. Q.; Yang, J. X.; Zhao, M.; Gao, C.; Guan, B.; Dong, H. L. Regioregular asymmetric diketopyrrolopyrrole copolymers with good molecular ordered assembly ability for high-performance polymer transistors. Chinese J. Polym. Sci. 2023, 41, 1215–1222 DOI： 10.1007/s10118-023-2918-2.

Qing-Qing Liu, Jia-Xin Yang, Man Zhao, et al. Regioregular Asymmetric Diketopyrrolopyrrole Copolymers with Good Molecular Ordered Assembly Ability for High-performance Polymer Transistors[J]. Chinese Journal of Polymer Science, 2023, 41(8): 1215-1222. DOI： 10.1007/s10118-023-2918-2.

摘要

Abstract

Introduction of asymmetric units into conjugated polymers is an important strategy to regulate the photophysical and electronic properties of polymers

as asymmetric units can not only regulate solubility and energy levels

but also molecular stacking and orientation

thus giving much higher optoelectronic properties. However

very few studies have been reported in this field. The semiconducting properties of conjugated polymers could be regulated through regioregularity adjustment. Here

we took the asymmetric thiophene/pyridine side group DPP as core and developed the regioregular monomer T-Py-DPP through three steps: alkyl chain introduction

tin monomer coupling and NBS double bromination. The T-Py-DPP monomer was polymerized into

reg

-PPyTDPP-2FBT with a head-to-head structure. The regioregularity of T-Py-DPP unit endowed

reg

-PPyTDPP-2FBT with backbone planarity

self-assembly orientation

network-like morphology and high crystallinity in films

thus the superior bipolar transport properties. The highest hole and electron mobilities of

reg

-PPyTDPP-2FBT were 0.93 and 0.57 cm

·V

−1

·s

−1

respectively

with 40% improvement relative to the regiorandom polymer.

关键词

Keywords

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