Modifying Poly(propylene carbonate) with Furan-based Non-Isocyanate Polyurethanes

Xiao-Jing Li; Ying-Feng Wen; Yong Wang; Xing-Ping Zhou; Xiao-Lin Xie

doi:10.1007/s10118-023-2904-8

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Modifying Poly(propylene carbonate) with Furan-based Non-Isocyanate Polyurethanes

RESEARCH ARTICLE | Updated：2023-06-14

- Modifying Poly(propylene carbonate) with Furan-based Non-Isocyanate Polyurethanes
- Modifying Poly(propylene carbonate) with Furan-based Non-Isocyanate Polyurethanes
- 高分子科学（英文版） 2023年41卷第7期页码：1069-1077
- Affiliations：
  
  Key Laboratory for Material Chemistry of Energy Conversion and Storage, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
- Author bio：
  
  tcwy@mail.hust.edu.cn (Y.W.)
  xpzhou@mail.hust.edu.cn (X.P.Z.)
- Funds：
  
  The authors thank financial support from the National Key Research and Development Program of China (No. 2016YFB0302400) and the National Natural Science Foundation of China (No. 21604027) as well as the analytical and testing assistance from the Analysis and Testing Centre of HUST.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-2904-8.
- DOI：10.1007/s10118-023-2904-8
  中图分类号：
- 收稿：2022-09-09，
  
  修回：2022-11-1，
  
  录用：2022-11-14，
  
  网络首发：2023-01-18，
  
  纸质出版：2023-07-01
- Accepted：
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Li, X. J.; Wen, Y. F.; Wang, Y.; Zhou, X. P.; Xie, X. L. Modifying poly(propylene carbonate) with furan-based non-isocyanate polyurethanes. Chinese J. Polym. Sci. 2023, 41, 1069–1077

Xiao-Jing Li, Ying-Feng Wen, Yong Wang, et al. Modifying Poly(propylene carbonate) with Furan-based Non-Isocyanate Polyurethanes[J]. Chinese Journal of Polymer Science, 2023, 41(7): 1069-1077.
Li, X. J.; Wen, Y. F.; Wang, Y.; Zhou, X. P.; Xie, X. L. Modifying poly(propylene carbonate) with furan-based non-isocyanate polyurethanes. Chinese J. Polym. Sci. 2023, 41, 1069–1077 DOI： 10.1007/s10118-023-2904-8.

Xiao-Jing Li, Ying-Feng Wen, Yong Wang, et al. Modifying Poly(propylene carbonate) with Furan-based Non-Isocyanate Polyurethanes[J]. Chinese Journal of Polymer Science, 2023, 41(7): 1069-1077. DOI： 10.1007/s10118-023-2904-8.

摘要

Furan-based NIPUs have been synthesized starting from CO

and 5-hydroxymethylfurfural

and further exploited as the second component for PPC blends

which allows for the preparation of high-performance CO2-based biodegradable polymeric materials with low carbon footprint

good sustainability

and ideal biocompatibility.

Abstract

Poly(propylene carbonate) (PPC) is gaining significant momentum as a biodegradable polymer using CO

as an abundant

low-cost and renewable feedstock. Yet

PPC suffers from unsatisfactory thermal and mechanical properties

and its blends with other synthetic polymers as the second component typically exhibit poor compatibility. Herein

novel furan-based non-isocyanate polyurethanes (NIPUs) with high molecular weights and narrow distributions have been synthesized starting from 5-hydroxymethylfurfural (HMF)

via

a four-step procedure including reduction

glycidylation

carbonation of CO

and step-growth polymerization with diamines. Owing to the structural similarity and intermolecular hydrogen bonding interactions

furan-based NIPUs display good compatibility with PPC. A sea-island morphology can be observed in SEM images of PPC/NIPU blends

where the NIPU phases are randomly dispersed in the PPC matrix. Moreover

the blends exhibit only one

(higher than both that of PPC and the corresponding NIPU) on the DSC curves

which first increase and then decrease when increasing the content of NIPUs from 0 wt% to 15 wt%. Notably

the physical crosslinking formed by hydrogen bonding interactions

coupled with the rigidity of furan rings

confer simultaneous improvements of elongation at the break and tensile strength

affording high-performance CO

-based biodegradable polymeric materials with low carbon footprint

good sustainability

and ideal biocompatibility.

关键词

Keywords

references

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