Adsorbents Derived from Xylan Hemicellulose with Removal Properties of Pollutant Metals

Elizabeth Elgueta; Yerko Becerra; Ana Martínez; Miguel Pereira; Isabel Carrillo-Varela; Felipe Sanhueza; Dariela Nuñez; Bernabé L. Rivas

doi:10.1007/s10118-023-2897-3

Your Location：

Home >

Browse articles >

Adsorbents Derived from Xylan Hemicellulose with Removal Properties of Pollutant Metals

RESEARCH ARTICLE | Updated：2023-05-26

- Adsorbents Derived from Xylan Hemicellulose with Removal Properties of Pollutant Metals
- Adsorbents Derived from Xylan Hemicellulose with Removal Properties of Pollutant Metals
- 高分子科学（英文版） 2023年41卷第6期页码：874-886
- Affiliations：
  
  a.Centro de Investigación de Polímeros Avanzados, CIPA, Avenida Collao 1202, Edificio de Laboratorios, Concepción, Chile
  b.Polymer Department, Faculty of Chemistry, University of Concepción, Casilla 160-C, Concepción, Chile
  c.Departamento de Ingeniería Química, Facultad de Ingeniería, Universidad de Concepción, Casilla 160-C, Concepción, Chile
  d.Department of Materials Engineering, Faculty of Engineering, Universidad de Concepción, Concepción, Chile
  e.Departamento de Química Ambiental, Facultad de Ciencias, Universidad Católica de la Santísima Concepción, Concepción, Chile
- Author bio：
  
  eelgueta@ucsc.cl (E.E.)
  brivas@udec.cl (B.L.R.)
- Funds：
  
  This work was financially supported by FONDECYT (Nos. 11170753 and 1190469), CIPA, CONICYT Regional, GORE BIO BIO PRFC0002, and the University of Concepción, Chile.
- DOI：10.1007/s10118-023-2897-3
  中图分类号：
- 收稿：2022-08-29，
  
  修回：2022-11-3，
  
  录用：2022-11-14，
  
  网络首发：2023-01-03，
  
  纸质出版：2023-06-01
- Accepted：
Scan QR Code
Elgueta, E.; Becerra, Y.; Martínez, A.; Pereira, M.; Carrillo-Varela, I.; Sanhueza, F.; Nuñez, D.; Rivas, B. L. Adsorbents derived from xylan hemicellulose with removal properties of pollutant metals. Chinese J. Polym. Sci. 2023, 41, 874–886

Elizabeth Elgueta, Yerko Becerra, Ana Martínez, et al. Adsorbents Derived from Xylan Hemicellulose with Removal Properties of Pollutant Metals[J]. Chinese Journal of Polymer Science, 2023, 41(6): 874-886.
Elgueta, E.; Becerra, Y.; Martínez, A.; Pereira, M.; Carrillo-Varela, I.; Sanhueza, F.; Nuñez, D.; Rivas, B. L. Adsorbents derived from xylan hemicellulose with removal properties of pollutant metals. Chinese J. Polym. Sci. 2023, 41, 874–886 DOI： 10.1007/s10118-023-2897-3.

Elizabeth Elgueta, Yerko Becerra, Ana Martínez, et al. Adsorbents Derived from Xylan Hemicellulose with Removal Properties of Pollutant Metals[J]. Chinese Journal of Polymer Science, 2023, 41(6): 874-886. DOI： 10.1007/s10118-023-2897-3.

摘要

In this work

hydrogels derived from xylan hemicellulose were synthesized. Xylan was extracted from eucalyptus Kraft pulp and chemically modified to generate hydrogels with sulfonic or sulfonates groups with the capacity to adsorb polluting ions

such as Cd(II)

Cu(II)

and Pb(II) from aqueous solutions.

Abstract

The adsorption capacity of hydrogels derived from modified xylan hemicellulose has been tested in order to develop new bio-based adsorbent materials useful for removing metal ions pollutants

such as Cd(II)

Cu(II) and Pb(II) from an aqueous solution. Xylan was extracted from bleached kraft pulp of eucalyptus and subsequently modified with different proportions of functional sulfonic acid groups (HA3−HA7) and sulfonate groups (HS30−HS70) to generate hydrogels. The results showed that all the synthesized hydrogels were capable of adsorbing metal ions

being the hydrogels with 30% and 50% xylan the ones that presented the highest adsorption capacity. Maximum capacity studies at different initial concentrations revealed that at an initial concentration of 300 mg·L

−1

the HA3 hydrogel presented an adsorption capacity of 193 mg Pb(II)

182 mg Cd(II)

and 66 mg Cu(II) per g hydrogel. The HA5 hydrogel presented a capacity of 185 mg Pb(II)

113 mg Cd(II)

and 48 mg Cu(II) per g hydrogel. The HS30 hydrogel exhibited an adsorption of 205 mg Pb(II)

174 mg Cd(II)

and 71 mg Cu(II) per g hydrogel

and HS50 hydrogel exhibited an adsorption capacity of 273 mg Pb(II)

143 mg Cd(II)

and 45 mg Cu(II) per g hydrogel. These results show that modified Xylan hemicellulose is a promising adsorbent for removal Cd(II)

Cu(II)

and Pb(II) ions from aqueous solutions.

关键词

Keywords

references

Kundu,D.;Mondal,S.K.;Banerjee,T.Developmentof β -cyclodextrin-cellulose/hemicellulose-basedhydrogelsfortheremovalofCd(II)andNi(II):synthesis,kinetics,andadsorptionaspects. J. Chem. Eng. Data. 2019 , 64 ,2601−2617..

Bosu,S.;Rajamohan,N.;Rajasimman,M.EnhancedremediationofLead(II)andCadmium(II)ionsfromaqueousmediausingporousmagneticnanocomposites-acomprehensivereviewonapplicationsandmechanism. Environ. Res. 2022 , 213 ,113720..

Ahmadijokani,F.;Molavi,H.;Peyghambari,A.;Shojaei,A.;Rezakazemi,M.;Aminabhavi,T.M.;Arjmand,M.Efficientremovalofheavymetalionsfromaqueousmediabyunmodifiedandmodifiednanodiamonds. J. Environ. Manage. 2022 , 316 ,115214..

Saleh,T.A.;Mustaqeem,M.;Khaled,M.Watertreatmenttechnologiesinremovingheavymetalionsfromwastewater:areview. Environ. Nanotechnol. Monit. Manag. 2022 , 17 ,100617..

Kafetzi,M.;Borchert,K.B.L.;Steinbach,C.;Schwarz,D.;Pispas,S.;Schwarz,S.ThermoresponsivePNIPAM- b -PAAblockcopolymersas“smart”adsorbentsofCu(II)forwaterrestoretreatments. Colloids Surf. A Physicochem. Eng. Asp. 2021 , 614 ,126049..

Dautoo,U.K.;Shandil,Y.;Ranote,S.;Jamwal,S.;Chauhan,G.S.Newefficientpoly(acrylicacid)-basedbifunctionalCu 2+ ionsadsorbents. Colloids Surf. A Physicochem. Eng. Asp. 2022 , 635 ,128090..

Zahri,N.A.M.;Jamil,S.N.A.M.;Abdullah,L.C.;JiaHuey,S.;Yaw,T.C.S.;Mobarekeh,M.N.;Rapeia,N.S.M.Equilibriumandkineticbehavioroncadmiumandleadremovalbyusingsyntheticpolymer. J. Water Process Eng. 2017 , 17 ,277−289..

Karimi-Maleh,H.;Ayati,A.;Ghanbari,S.;Orooji,Y.;Tanhaei,B.;Karimi,F.;Alizadeh,M.;Rouhi,J.;Fu,L.;Sillanpää,M.RecentadvancesinremovaltechniquesofCr(VI)toxicionfromaqueoussolution:acomprehensivereview. J. Mol. Liq. 2021 , 329 ,115062..

Mashhadikhan,S.;EbadiAmooghin,A.;Sanaeepur,H.;Shirazi,M.M.A.Acriticalreviewoncadmiumrecoveryfromwastewatertowardsenvironmentalsustainability. Desalination 2022 , 535 ,115815..

Rivas,B.L.;Sanchez,J.;Butter,B.Biopolymersappliedtoremovemetalionsthroughultrafiltration.Areview. J. Chil. Chem. Soc. 2020 , 65 ,5004−5010..

Encina,L.;Elgueta,E.;Rivas,B.L.;Pereira,M.;Sanhueza,F.Hydrogelsderivedfromgalactoglucomannanhemicellulosewithinorganiccontaminantremovalproperties. RSC Adv. 2021 , 11 ,35960−35972..

Núñez,D.;Serrano,J.A.;Mancisidor,A.;Elgueta,E.;Varaprasad,K.;Oyarzún,P.;Cáceres,R.;Ide,W.;Rivas,B.L.Heavymetalremovalfromaqueoussystemsusinghydroxyapatitenanocrystalsderivedfromclamshells. RSC Adv. 2019 , 9 ,22883−22890..

Elgueta,E.;Rivas,B.L.;Mancisidor,A.;Núñez,D.;Dahrouch,M.Hydrogelsderivedfrom2-hydroxyethyl-methacrylateand2-acrylamido-2-methyl-1-propanesulfonicacid,withabilitytoremovemetalcationsfromwastewater. Polym. Bull. 2019 , 76 ,6503−6528..

Saravanan,A.;SenthilKumar,P.;Jeevanantham,S.;Karishma,S.;Tajsabreen,B.;Yaashikaa,P.R.;Reshma,B.Effectivewater/wastewatertreatmentmethodologiesfortoxicpollutantsremoval:processesandapplicationstowardssustainabledevelopment. Chemosphere 2021 , 280 ,130595..

Busetty,S.Environmentaltreatmenttechnologies:adsorption.In Handbook of Environmental Materials Management ;Hussain,C.M.,Ed.;SpringerInternationalPublishing:Cham, 2019 ;pp1367–1397..

Kaur,J.;Sengupta,P.;Mukhopadhyay,S.Criticalreviewofbioadsorptiononmodifiedcelluloseandremovalofdivalentheavymetals(Cd,Pb,andCu). Ind. Eng. Chem. Res. 2022 , 61 ,1921−1954..

Gupta,A.D.;Rawat,K.P.;Bhadauria,V.;Singh,H.Recenttrendsintheapplicationofmodifiedstarchintheadsorptionofheavymetalsfromwater:areview. Carbohydr. Polym. 2021 , 269 ,117763..

Begum,S.;Yuhana,N.Y.;MdSaleh,N.;Kamarudin,N.H.N.;Sulong,A.B.Reviewofchitosancompositeasaheavymetaladsorbent:materialpreparationandproperties. Carbohydr. Polym. 2021 , 259 ,117613..

Nguyen,K.D.;Trang,T.T.C.;Kobayashi,T.Chitin-halloysitenanoclayhydrogelcompositeadsorbenttoaqueousheavymetalions. J. Appl. Polym. Sci. 2019 , 136 ,47207..

Fouda-Mbanga,B.G.;Prabakaran,E.;Pillay,K.Carbohydratebiopolymers,ligninbasedadsorbentsforremovalofheavymetals(Cd 2+ ,Pb 2+ ,Zn 2+ )fromwastewater,regenerationandreuseforspentadsorbentsincludinglatentfingerprintdetection:areview. Biotechnol. Rep. 2021 , 30 ,e00609..

Figueira,P.;Henriques,B.;Teixeira,F.;Afonso,N.;Pinto,J.;Tavares,D.;Vale,C.;Pereira,E.Potentialitiesofagro-basedwastestoremoveCd,Hg,Pb,andasfromcontaminatedwaters. Wat. Air Soil Poll. 2022 , 233 ,78..

Zia,Z.;Hartland,A.;Mucalo,M.R.Useoflow-costbiopolymersandbiopolymericcompositesystemsforheavymetalremovalfromwater. IJEST 2020 , 17 ,4389−4406..

Peng,X.;Ren,J.;Zhong,L.;Sun,R.;Shi,W.;Hu,B.Glycidylmethacrylatederivatizedxylan-richhemicelluloses:synthesisandcharacterizations. Cellulose 2012 , 19 ,1361−1372..

Johari,N.;Moroni,L.;Samadikuchaksaraei,A.Tuningtheconformationandmechanicalpropertiesofsilkfibroinhydrogels. Eur. Polym. J. 2020 , 134 ,109842..

Ahmad,Z.;Salman,S.;Khan,S.A.;Amin,A.;Rahman,Z.U.;Al-Ghamdi,Y.O.;Akhtar,K.;Bakhsh,E.M.;Khan,S.B.Versatilityofhydrogels:fromsyntheticstrategies,classification,andpropertiestobiomedicalapplications. Gels 2022 , 8 ,167..

Teow,Y.H.;Kam,L.M.;Mohammad,A.W.Synthesisofcellulosehydrogelforcopper(II)ionsadsorption. J. Environ. Chem. Eng 2018 , 6 ,4588−4597..

Qin,X.;Lu,A.;Zhang,L.GelationbehaviorofcelluloseinNaOH/ureaaqueoussystem via cross-linking. Cellulose 2013 , 20 ,1669−1677..

Malpure,P.S.;Patil,S.S.;More,Y.M.;Nikam,P.P.Areviewon-hydrogel. Am. J. PharmTech. Res. 2018 , 8 ,41−61..

Chouchane,T.;Khireddine,O.;Boukari,A.KineticstudiesofNi(II)ionsadsorptionfromaqueoussolutionsusingtheblastfurnaceslag(BFSlag). J. Eng. Appl. Sci. 2021 , 68 ,34..

Mustapha,S.;Shuaib,D.T.;Ndamitso,M.M.;Etsuyankpa,M.B.;Sumaila,A.;Mohammed,U.M.;Nasirudeen,M.B.Adsorptionisotherm,kineticandthermodynamicstudiesfortheremovalofPb(II),Cd(II),Zn(II)andCu(II)ionsfromaqueoussolutionsusingAlbiziaLebbeckPods. Appl. Water Sci. 2019 , 9 ,142..

Revellame,E.D.;Fortela,D.L.;Sharp,W.;Hernandez,R.;Zappi,M.E.Adsorptionkineticmodelingusingpseudo-firstorderandpseudo-secondorderratelaws:areview. Cleaner Eng. Technol. 2020 , 1 ,100032..

Hu,H.;Xu,K.Chapter8-PhysicochemicalTechnologiesforHRPsandRiskControl.In High-Risk Pollutants in Wastewater ;Ren,H.,Zhang,X.,Eds.;Elsevier, 2020 ;pp169–207.https://doi.org/https://doi.org/10.1016/B978-0-12-816448-8.00008-3..

López,Y.C.;Ortega,G.A.;Reguera,E.Hazardousionsdecontamination:fromtheelementtothematerial. Chem. Eng. J. Adv. 2022 , 11 ,100297..

Tyagi,R.;Jacob,J.Highlyporous,water-swellable,andreusablechelatingpolymericgelsforheavymetalionremovalfromaqueouswaste. J. Appl. Polym. Sci. 2021 , 138 ,51353..

Shuaiyang,W.;Huiling,L.;Junli,R.;Chuanfu,L.;Feng,P.;Runcang,S.Preparationofxylancitrate—apotentialadsorbentforindustrialwastewatertreatment. Carbohydr. Polym. 2013 , 92 ,1960−1965..

Peng,X.W.;Zhong,L.X.;Ren,J.L.;Sun,R.C.Highlyeffectiveadsorptionofheavymetalionsfromaqueoussolutionsbymacroporousxylan-richhemicelluloses-basedhydrogel. J. Agric. Food. Chem. 2012 , 60 ,3909−3916..

Wu,S.;Kan,J.;Dai,X.;Shen,X.;Zhang,K.;Zhu,M.Ternarycarboxymethylchitosan-hemicellulose-nanosizedTiO 2 compositeaseffectiveadsorbentforremovalofheavymetalcontaminantsfromwater. Fibers Polym. 2017 , 18 ,22−32..

CamañoEchavarria,J.A.;RiveraTorres,A.M.;ZapataMontoya,J.E.Sorptionisothermsandthermodynamicpropertiesofthedrysilageofredtilapiaviscera(oreochromisspp.)obtainedinadirectsolardryer. Heliyon 2021 , 7 ,e06798..

Chen,X.Modelingofexperimentaladsorptionisothermdata. Information 2015 , 6 ,14−22..

Desta,M.B.Batchsorptionexperiments:langmuirandfreundlichisothermstudiesfortheadsorptionoftextilemetalionsontoteffstraw(EragrostisTef)agriculturalwaste. J. Thermodyn. 2013 , 1 ,1−6..

Ibrahim,A.G.;Sayed,A.Z.;AbdEl-Wahab,H.;Sayah,M.M.Synthesisofahydrogelbygraftingofacrylamide-co-sodiummethacrylateontochitosanforeffectiveadsorptionoffuchsinbasicdye. Int. J. Biol. Macromol. 2020 , 159 ,422−432..

浏览量

191

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Removal of Methylene Blue with Hemicellulose/Clay Hybrid Hydrogels

Heavy Metal Ions Removal by Nano-sized Spherical Polymer Brushes

Experimental Investigation of Graphene and TiO2 Reinforced Poly(vinyl alcohol)-based Fiber Metal Laminates

From Molecular Defect to Macroscopic Performance: Manipulating Dichroism and Mechanics in Iodine-doped Poly(vinyl alcohol) via Ethylene Incorporation

2026-9 Contents