Structural Evolution of PGA Nascent Fiber during Single Low-Temperature and Segmented High-Temperature Hot Stretching

Yu-Shuang Miao; Hua-Shuai Cui; Jin Guo; Jin-Tang Zhu; Yi-Guo Li; Zong-Bao Wang

doi:10.1007/s10118-023-2892-8

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Structural Evolution of PGA Nascent Fiber during Single Low-Temperature and Segmented High-Temperature Hot Stretching

RESEARCH ARTICLE | Updated：2023-06-14

- Structural Evolution of PGA Nascent Fiber during Single Low-Temperature and Segmented High-Temperature Hot Stretching
- Structural Evolution of PGA Nascent Fiber during Single Low-Temperature and Segmented High-Temperature Hot Stretching
- 高分子科学（英文版） 2023年41卷第7期页码：1078-1092
- Affiliations：
  
  a.School of Materials Science and Chemical Engineering, Key Laboratory of Impact and Safety Engineering, Ministry of Education, Ningbo University, Ningbo 315211, China
  b.State Key Laboratory of Biobased Fiber Manufacturing Technology, China Textile Academy, Beijing 100025, China
- Author bio：
  
  wangzongbao@nbu.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51973097 and 52173021) and the Open Fund of State Key Laboratory of Biobased Fiber Manufacturing Technology (No. SKL202207). We thank Shanghai Synchrotron Radiation Facility (SSRF) for supporting the SAXS and WAXD tests.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-2892-8.
- DOI：10.1007/s10118-023-2892-8
  中图分类号：
- 收稿：2022-09-13，
  
  修回：2022-10-13，
  
  录用：2022-10-24，
  
  网络首发：2022-12-28，
  
  纸质出版：2023-07-01
- Accepted：
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Miao, Y. S.; Cui, H. S.; Guo, J.; Zhu, J. T.; Li, Y. G.; Wang, Z. B. Structural evolution of PGA nascent fiber during single low-temperature and segmented high-temperature hot stretching. Chinese J. Polym. Sci. 2023, 41, 1078–1092

Yu-Shuang Miao, Hua-Shuai Cui, Jin Guo, et al. Structural Evolution of PGA Nascent Fiber during Single Low-Temperature and Segmented High-Temperature Hot Stretching[J]. Chinese Journal of Polymer Science, 2023, 41(7): 1078-1092.
Miao, Y. S.; Cui, H. S.; Guo, J.; Zhu, J. T.; Li, Y. G.; Wang, Z. B. Structural evolution of PGA nascent fiber during single low-temperature and segmented high-temperature hot stretching. Chinese J. Polym. Sci. 2023, 41, 1078–1092 DOI： 10.1007/s10118-023-2892-8.

Yu-Shuang Miao, Hua-Shuai Cui, Jin Guo, et al. Structural Evolution of PGA Nascent Fiber during Single Low-Temperature and Segmented High-Temperature Hot Stretching[J]. Chinese Journal of Polymer Science, 2023, 41(7): 1078-1092. DOI： 10.1007/s10118-023-2892-8.

摘要

Hot stretching is conducive to the crystal perfection of PGA fiber

single low-temperature stretching can be divided into three stages: the stretching of amorphous regions

stretch-induced crystallization and the stretching of crystalline regions. High-temperature stretching compared with low-temperature stretching is more favorable for crystal perfection and structural evolution.

Abstract

Polyglycolide (PGA) fibers applied as surgical sutures strongly depend on their microstructure. The structural evolution of PGA nascent fibers during single low-temperature stretching and segmented high-temperature stretching was analyzed based on a combination of

in situ

WAXD/SAXS and DSC measurements. The results indicated that the hot stretching was conducive to the crystal perfection and the local fragmentation and recrystallization of the lamellar crystals may occur under stress induction. The single low-temperature stretching of PGA nascent fibers could be divided into three stages: the stretching of amorphous regions

stretch-induced crystallization and the stretching of crystalline regions. The elongation at break of the fibers can be substantially increased by adopting a segmented stretching method

and the high-temperature stretching can also significantly increase the crystallinity and orientation. The amorphous orientation peak appearing in the low-temperature stretching was gradually converted to crystallization peak during the heating process

which greatly improved the crystallinity and orientation of the fibers. High-temperature stretching compared with low-temperature stretching was more favorable for crystal perfection and structural evolution

where lamellar crystals underwent stress-induced fragmentation recrystallization to transform to fibrous crystals as the strain increased.

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references

Malmir,S.;Montero,B.;Rico,M.;Barral,L.;Bouza,R.;Farrag,Y.Effectsofpoly(3-hydroxybutyrate- co -hydroxyvalerate)microparticlesonmorphological,mechanical,thermal,andbarrierpropertiesinthermoplasticpotatostarchfilms. Carbohydr. Polym. 2018 , 194 ,357−364..

Williams,C.K.;Hillmyer,M.A.Polymersfromrenewableresources:aperspectiveforaspecialissueofpolymerreviews. Polym. Rev. 2008 , 48 ,1−10..

Ikada,Y.;Tsuji,H.Biodegradablepolyestersformedicalandecologicalapplications. Macromol. Rapid Commun. 2000 , 21 ,117−132..

Wei,Y.H.;Xia,G.Q.;Wang,Y.S.Biodegradablepolymermaterialsusedinbiomedicalfield. J. Yunnan Uni. 2004 , 26 ,121−124..

Zhu,Y.Q.;Romain,C.;Williams,C.K.Sustainablepolymersfromrenewableresources. Nature 2016 , 540 ,354−362..

Malinova,V.;Meier,W.Polymermaterialsforbiomedicalapplications. RSC Nanosci. Nanotechnol. 2010 , 3 ,3−15..

Zhao,Y.;Zhu,B.;Wang,Y.;Liu,C.,Shen,C.Effectofdifferentsterilizationmethodsonthepropertiesofcommercialbiodegradablepolyestersforsingle-use,disposablemedicaldevices. Mater. Sci. Eng. 2019 , 105 ,110041..

Fang,Y.;Li,Z.;Qiu,Z.Miscibilityandcrystallizationbehaviorofbiodegradablepoly(3-hydroxybutyrate- co -3-hydroxyvalerate)/phenolicblends. J. Appl. Polym. Sci. 2011 , 123 ,2781−2786..

Doppalapudi,S.;Jain,A.;Khan,W.;Domb,A.J.Biodegradablepolymers & mdash;anoverview. Polymer 2014 , 25 ,427−435..

Wisniewska,K.;Rybak,Z.;Watrobinski,M.;Struszczyk,M.H.;Filipiak,J.;Zywicka,B.;Szymonowicz,M.Bioresorbablepolymericmaterials-currentstateofknowledge. Polimery 2021 , 66 ,3−10..

Naira,L.S.;Laurencina,C.T.Biodegradablepolymersasbiomaterials. Prog. Polym. Sci. 2007 , 32 ,762−798..

Liang,H.G.;Huang,K.Developmentstatusandtrendofbiomedicalpolymermaterials. New Mater. Ind. 2016 , 2 ,12−15..

Landes,C.A.;Ballon,A.;Roth,C.MaxillaryandmandibularosteosyntheseswithPLGAandP(L/DL)LAimplants:a5-yearinpatientbiocompatibilityanddegradationexperience. Plast. Reconstr. Surg. 2006 , 117 ,2347−2360..

Singhal,J.P.;Singh,H.;Ray,A.R.Absorbablesuturematerials:preparationandproperties. J. Macromol. Sci., Rev. Macromol. Chem. Phys. 1988 , 28 ,475−502..

Gomzyak,V.I.;Demina,V.A.;Razuvaeva,E.V.;Sedush,N.G.;Chvalun,S.N.Biodegradablepolymerscaffoldstoregenerateorgans. Fine Chem. Technol. 2017 , 12 ,5−20..

Lim,L.T.;Auras,R.;Rubino,M.Processingtechnologiesforpoly(lacticacid). Prog. Polym. Sci. 2008 , 33 ,820−852..

Shawe,S.;Buchanan,F.;Harkin-Jones,E.;Farrar,D.Astudyontherateofdegradationofthebioabsorbablepolymerpolyglycolicacid(PGA). J. Mater. Sci. 2006 , 41 ,4832−4838..

Gilding,D.K.;Reed,A.M.Biodegradablepolymersforuseinsurgery-polyglycolic/poly(lacticacid)homo-andcopolymers. Polymer 1979 , 20 ,1459−1464..

Cui,A.J.;Li,Z.F.;C,Q.;He,M.Y.Biodegradablematerialpolyhydroxyaceticacidanditscrystallizationproperties. New. Che. Mater. 2012 , 40 ,87−90..

Martin,O.;Avérous,L.Poly(lacticacid):plasticizationandpropertiesofbiodegradablemultiphasesystems. Polymer 2001 , 42 ,6209−6219..

Fu,B.X.;Hsiao,B.S.;Chen,G.;Zhou,J.;Lin,S.;Yuan,J.;Koyfman,I.;Jamiolkowski,D.D.;Dormier,E.Astudyofstructureandpropertychangesofbiodegradablepolyglycolideandpoly(glycolide- co -lactide)fibersduringprocessingand in vitro degradation. Chinese J. Polym. Sci. 2003 , 21 ,159−167..

Fu,B.X.;Hsiao,B.S.;Chen,G.;Zhou,J.;Koyfman,I.;Jamiolkowski,D.;Dormier,E.Structureandpropertystudiesofbioabsorbablepoly(glycolide -co- lactide)fiberduringprocessingand in vitro degradation. Polymer 2002 , 43 ,5527−5534..

Zong,X.H.;Wang,Z.G.;Hsiao,B.S.;Chu,B.;Zhou,J.J.;Jamiolkowski,D.D.;Muse,E.;Dormier,E.Structureandmorphologychangesinabsorbablepoly(glycolide)andpoly(glycolide- co -lactide)during in vitro degradation. Macromolecules 1999 , 32 ,8107−8114..

Wang,Y.;Li,M.;Shen,C.Effectofconstrainedannealingonthemicrostructuresofextrusioncastpolylacticacidfilms. Mater. Lett. 2011 , 65 ,3525−3528..

Wang,Y.M.;Li,M.;Wang,K.J.;Shao,C.G.;Li,Q.;Shen,C.Y.Unusualstructuralevolutionofpoly(lacticacid)uponannealinginthepresenceofaninitiallyorientedmesophase. Soft Matter 2014 , 10 ,1512−1518..

Shen,C.Y.;Wang,Y.M.;Li,M.;Hu,D.F.Crystalmodificationsandmultiplemeltingbehaviorofpoly(L-lacticacid- co -D-lacticacid). J. Polym. Sci., Part B: Polym. Phys. 2011 , 49 ,409−413..

Lorenzo,A.T.;Arnal,M.L.;Sanchez,J.J.;Muller,A.J.Effectofannealingtimeontheself-nucleationbehaviorofsemicrystallinepolymers. J. Polym. Sci., Part B: Polym. Phys. 2006 , 44 ,1738−1750..

Yan,R.J.Uniaxialtensileandorientedstructureofcrystallinepolymers.I.Deformationmechanismoftensilecrystallinepolymers. Polym. Bull. 1993 ,230−233..

Yan,R.J.Uniaxialtensileandorientedstructureofcrystallinepolymers.II.Structuralmodelandplasticdeformationoforientedcrystallinepolymers. Polym. Bull. 1994 ,26−30..

Termonia,Y.,Smith,P.Kineticmodelfortensiledeformationofpolymers.5.Effectoftemperatureonorientationefficiency. Macromolecules 1993 , 26 ,3738−3741..

Li,J.Structureandpropertiesofglycolide-L-lactidecopolymerfiberduringdrawing. Tianjin University , 2007 ..

Li,J.;Huang,Q.;Li,X.CrystallizationandorientationofP(GA- co -LA)fibersduringdrawingprocess. J. Textile Res. 2011 , 32 ,1−5..

Huang,Q.;Gao,X.S.;Xu,J.G.;Li,J.;Wu,P.F.ThecrystallizationpropertiesofP(GA- co -LA)fibersduringmolding. Synthetic Fiber 2009 , 12 ,9−13..

Mu,W.M.;Zheng,Q.J.Developmentofpolyglycolideandpolyglycolidesuture. Synthetic Fiber 1991 , 020 ,24−29..

Dong,Z.;Miao,Y.;Cui,H.;Huang,Q.;Li,Y.;Wang,Z.Structuralevolutionofpolyglycolideandpoly(glycolide -co- lactide)fibersduringheat-setting. Biomacromolecules 2021 , 22 ,3342−3356..

Hammersley,A.P.;Svensson,S.O.;Thompson,A.Calibrationandcorrectionofspatialdistortionsin2Ddetectorsystems. Rev. Sci. Instrum. 1995 , 346 ,312−321..

Li,S.M.;Vert,M.Biodegradationofaliphaticpolyesters. Degrad. Polym. 2002 , 4 ,123−135..

Alexander,L.E.X-raydiffractionmethodsinpolymerscience. J. Mol. Struct. 1971 , 6 ,93..

Kortleve,G.;Vonk,C.G.X-raysmall-anglescatteringofbulkpolyethylene. J. Mol. Struct. 1968 , 225 ,124−131..

Tang,Y.;Jiang,Z.;Men,Y.Uniaxialdeformationofoverstretchedpolyethylene: in situ synchrotronsmallangleX-rayscatteringstudy. Polymer 2007 , 48 ,5125−5132..

Ruland,W.Small-anglescatteringstudiesoncarbonizedcellulosefibers. J. Polym. Sci., Part C: Polym. Symp. 1969 , 28 ,143−151..

Perret,R.;Ruland,W.SingleandmultipleX-raysmall-anglescatteringofcarbonfibers. J. Appl. Crystallogr. 1969 , 2 ,209−218..

Qian,R.;Wu,L.;Shen,D.;Napper,D.H.;Mann,R.A.;Sangster,D.F.Single-chainpolystyreneglasses. Macromolecules 1993 , 26 ,2950−2953..

Qian,R.Somebasicphysicalproblemsofpolymercondensationstate. Bull. Chin. Acad. Sci. 2000 , 3 ,174−177..

Ran,S.F.;Wang,Z.G.;Burger.C.B.;Chu,B.;Hsiao,B.S.Mesophaseastheprecursorforstrain-inducedcrystallizationinamorphouspoly(ethyleneterephthalate)film. Macromolecules 2002 , 35 ,10102−10107..

Sato,H.;Miyada,M.;Yamamoto,S.;RaghunathaReddy,K.;Ozaki,Y.C–HO(ether)hydrogenbondingalongthe(110)directioninpolyglycolicacidstudiedbyinfraredspectroscopy,wide-angleX-raydiffraction,quantumchemicalcalculationsandnaturalbondorbitalcalculations. RSC Adv. 2016 , 6 ,16817−16823..

Lee,S.;Hongo,C.;Nishino,T.Crystalmodulusofpoly(glycolicacid)anditstemperaturedependence. Macromolecules 2017 , 50 ,5074−5079..

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