Metal-Backboned Polymer: Conception, Design and Synthesis

Kai-Wen Zeng; Hui-Sheng Peng

doi:10.1007/s10118-022-2887-x

Your Location：

Home >

Browse articles >

Metal-Backboned Polymer: Conception, Design and Synthesis

RAPID COMMUNICATION | Updated：2022-12-19

- Metal-Backboned Polymer: Conception, Design and Synthesis
- Metal-Backboned Polymer: Conception, Design and Synthesis
- 高分子科学（英文版） 2023年41卷第1期页码：3-6
- Affiliations：
  
  State Key Laboratory of Molecular Engineering of Polymers and Department of Macromolecular Science, Fudan University, Shanghai 200438, China
- Author bio：
  
  penghs@fudan.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 22105045), The Science and Technology Commission of Shanghai Municipality (Nos. 20JC1414902 and 21511104900), and Shanghai Municipal Education Commission (2017-01-07-00-07-E00062). This work has benefited from the use of the 1W1B beamline at the Beijing Synchrotron Radiation Facility, and we would like to thank L. Zheng for the assistance with the measurements. We thank G. Wang, B. Zhang and R. Huang for their assistance.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-022-2887-x.
- DOI：10.1007/s10118-022-2887-x
  中图分类号：
- 收稿：2022-10-06，
  
  修回：2022-10-17，
  
  录用：2022-10-17，
  
  网络首发：2022-10-27，
  
  纸质出版：2023-01-01
- Accepted：
Scan QR Code
Zeng, K. W.; Peng, H. S. Metal-backboned polymer: conception, design and synthesis. Chinese J. Polym. Sci. 2023, 41, 3–6

Kai-Wen Zeng, Hui-Sheng Peng. Metal-Backboned Polymer: Conception, Design and Synthesis[J]. Chinese Journal of Polymer Science, 2023, 41(1): 3-6.
Zeng, K. W.; Peng, H. S. Metal-backboned polymer: conception, design and synthesis. Chinese J. Polym. Sci. 2023, 41, 3–6 DOI： 10.1007/s10118-022-2887-x.

Kai-Wen Zeng, Hui-Sheng Peng. Metal-Backboned Polymer: Conception, Design and Synthesis[J]. Chinese Journal of Polymer Science, 2023, 41(1): 3-6. DOI： 10.1007/s10118-022-2887-x.

摘要

A new type of polymers whose backbones are composed of metal atoms has been designed

synthesized

and studied

opening up a new avenue to design new functional polymers in the future.

Abstract

The backbones of polymers are generally composed of non-metal elements such as C

O and Si. Here we propose and synthesize a new class of polymers whose backbones are completely made from metal atoms connected by chemical bonds

and they are thus named metal-backboned polymers. As a demonstration

nickel is selected as the metal to construct the nickel-backboned polymers with varied lengths

which are verified by mass spectrometry and studied by ultraviolet-visible spectroscopy. These metal-bonded polymers open up a new avenue to develop functional polymers in the future.

关键词

Keywords

references

Percec, V . Introduction: frontiers in polymer chemistry . Chem. Rev. , 2001 . 101 3579 - 3580 . DOI: 10.1021/cr000885x http://doi.org/10.1021/cr000885x .

Aida, T.; Meijer, E. W.; Stupp, S. I . Functional supramolecular polymers . Science , 2012 . 335 813 - 817 . DOI: 10.1126/science.1205962 http://doi.org/10.1126/science.1205962 .

Zhu, Y. Q.; Romain, C.; Williams, C. K . Sustainable polymers from renewable resources . Nature , 2016 . 540 354 - 362 . DOI: 10.1038/nature21001 http://doi.org/10.1038/nature21001 .

Balint, R.; Cassidy, N. J.; Cartmell, S. H . Conductive polymers: towards a smart biomaterial for tissue engineering . Acta Biomater. , 2014 . 10 2341 - 2353 . DOI: 10.1016/j.actbio.2014.02.015 http://doi.org/10.1016/j.actbio.2014.02.015 .

Lutz, J. F.; Ouchi, M.; Liu, D. R.; Sawamoto, M . Sequence-controlled polymers . Science , 2013 . 341 1238149 DOI: 10.1126/science.1238149 http://doi.org/10.1126/science.1238149 .

Peng, H.; Sun, X.; Cai, F.; Chen, X.; Zhu, Y.; Liao, G.; Chen, D.; Li, Q.; Lu, Y.; Zhu, Y.; Jia, Q . Electrochromatic carbon nanotube/ polydiacetylene nanocomposite fibres . Nat. Nanotechnol. , 2009 . 4 738 - 741 . DOI: 10.1038/nnano.2009.264 http://doi.org/10.1038/nnano.2009.264 .

Wilbon, P . A.; Chu, F.; Tang, C. Progress in renewable polymers from natural terpenes, terpenoids, and rosin . Macromol. Rapid Commun. , 2013 . 34 8 - 37 . DOI: 10.1002/marc.201200513 http://doi.org/10.1002/marc.201200513 .

Saheb, D. N.; Jog, J. P . Natural fiber polymer composites: a review . Adv. Polym. Technol. , 1999 . 18 351 - 363 . DOI: 10.1002/(SICI)1098-2329(199924)18:4<351::AID-ADV6>3.0.CO;2-X http://doi.org/10.1002/(SICI)1098-2329(199924)18:4<351::AID-ADV6>3.0.CO;2-X .

Mohammed, L.; Ansari, M. N. M.; Pua, G.; Jawaid, M.; Islam, M. S . A review on natural fiber reinforced polymer composite and its applications . Int. J. Polym. Sci. , 2015 . 2015 243947 DOI: 10.1155/2015/243947 http://doi.org/10.1155/2015/243947 .

Staudinger, H . Über polymerisation . Ber. dtsch. Chem. Ges. A/B , 1920 . 53 1073 - 1085 . DOI: 10.1002/cber.19200530627 http://doi.org/10.1002/cber.19200530627 .

Hu, J. L.; Zhu, Y.; Huang, H. H.; Lu, J . Recent advances in shape-memory polymers: structure, mechanism, functionality, modeling and applications . Prog. Polym. Sci. , 2012 . 37 1720 - 1763 . DOI: 10.1016/j.progpolymsci.2012.06.001 http://doi.org/10.1016/j.progpolymsci.2012.06.001 .

Mohanty, A. K.; Wu, F.; Mincheva, R.; Hakkarainen, M.; Raquez, J. M.; Mielewski, D. F.; Narayan, R.; Netravali, A. N.; Misra, M . Sustainable polymers . Nat. Rev. Methods Primers , 2022 . 2 46 DOI: 10.1038/s43586-022-00124-8 http://doi.org/10.1038/s43586-022-00124-8 .

Song, Z.; Han, Z.; Lv, S.; Chen, C.; Chen, L.; Yin, L.; Cheng, J . Synthetic polypeptides: from polymer design to supramolecular assembly and biomedical application . Chem. Soc. Rev. , 2017 . 46 6570 - 6599 . DOI: 10.1039/C7CS00460E http://doi.org/10.1039/C7CS00460E .

Namsheer, K.; Rout, C. S . Conducting polymers: a comprehensive review on recent advances in synthesis, properties and applications . RSC Adv. , 2021 . 11 5659 - 5697 . DOI: 10.1039/D0RA07800J http://doi.org/10.1039/D0RA07800J .

Das, T. K.; Prusty, S . Review on conducting polymers and their applications . Polym-Plast. Technol. , 2012 . 51 1487 - 1500 . DOI: 10.1080/03602559.2012.710697 http://doi.org/10.1080/03602559.2012.710697 .

Tang, H.; Liang, Y.; Liu, C.; Hu, Z.; Deng, Y.; Guo, H.; Yu, Z.; Song, A.; Zhao, H.; Zhao, D.; Zhang, Y.; Guo, X.; Pei, J.; Ma, Y.; Cao, Y.; Huang, F. . A solution-processed n-type conducting polymer with ultrahigh conductivity . Nature , 2022 . 611 271 - 277 . DOI: 10.1038/s41586-022-05295-8 http://doi.org/10.1038/s41586-022-05295-8 .

Li, T.; Cai, G.; Lin, Y.; Lu, X.; Zhan, X . Effects of thieno[3,2- b ]thiophene number on narrow-bandgap fused-ring electron acceptors . Chinese J. Polym. Sci. , 2022 . 40 914 - 920 . DOI: 10.1007/s10118-022-2735-z http://doi.org/10.1007/s10118-022-2735-z .

Harisomayajula, N. V. S.; Wu, B. H.; Lu, D. Y.; Kuo, T. S.; Chen, I. C.; Tsai, Y. C . Ligand-unsupported cuprophilicity in the preparation of dodecacopper(I) complexes and raman studies . Angew. Chem. Int. Ed. , 2018 . 57 9925 - 9929 . DOI: 10.1002/anie.201801955 http://doi.org/10.1002/anie.201801955 .

Rivada-Wheelaghan, O.; Aristizabal, S. L.; Lopez-Serrano, J.; Fayzullin, R. R.; Khusnutdinova, J. R . Controlled and reversible stepwise growth of linear copper(I) chains enabled by dynamic ligand scaffolds . Angew. Chem. Int. Ed. , 2017 . 56 16267 - 16271 . DOI: 10.1002/anie.201709167 http://doi.org/10.1002/anie.201709167 .

Ismayilov, R. H.; Wang, W. Z.; Lee, G. H.; Yeh, C. Y.; Hua, S. A.; Song, Y.; Rohmer, M. M.; Benard, M.; Peng, S. M . Two linear undecanickel mixed-valence complexes: increasing the size and the scope of the electronic properties of nickel metal strings . Angew. Chem. Int. Ed. , 2011 . 50 2045 - 2053 . DOI: 10.1002/anie.201006695 http://doi.org/10.1002/anie.201006695 .

Goto, E.; Begum, R . A.; Ueno, C.; Hosokawa, A.; Yamamoto, C.; Nakamae, K.; Kure, B.; Nakajima, T.; Kajiwara, T.; Tanase, T. Electron-deficient Pt 2 M 2 Pt 2 hexanuclear metal strings (M = Pt, Pd) supported by triphosphine ligands . Organometallics , 2014 . 33 1893 - 1904 . DOI: 10.1021/om401211d http://doi.org/10.1021/om401211d .

Horiuchi, S.; Tachibana, Y.; Yamashita, M.; Yamamoto, K.; Masai, K.; Takase, K.; Matsutani, T.; Kawamata, S.; Kurashige, Y.; Yanai, T.; Murahashi, T . Multinuclear metal-binding ability of a carotene . Nat. Commun. , 2015 . 6 6742 DOI: 10.1038/ncomms7742 http://doi.org/10.1038/ncomms7742 .

Dyker, G.; Mastalerz, M.; Merz, K . From a calix[4]arene to a hexameric supracycle . Eur. J. Org. Chem. , 2003 . 2003 4355 - 4362 . DOI: 10.1002/ejoc.200300380 http://doi.org/10.1002/ejoc.200300380 .

Hua, S. A.; Cheng, M. C.; Chen, C. H.; Peng, S. M . From homonuclear metal string complexes to heteronuclear metal string complexes . Eur. J. Inorg. Chem. , 2015 . 2510 - 2523 . DOI: 10.1002/ejic.201403237 http://doi.org/10.1002/ejic.201403237 .

浏览量

218

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Real-Time Monitoring of Component Conversion during the Foaming and Curing Process of Self-expanding Polyurethane Grouts

Polymeric Hydrogels as Wound Dressing and Wound Healing Applications: A Review

Iminopyridine Manganese and Nickel Complexes: Synthesis, Characterization and Behavior in the Polymerization of 1,3-Butadiene

Highly Regio- and trans-Selective Ring-opening Metathesis Polymerization of Chiral Aza-norbornene with a Simple Phenylimido-Tungsten Catalyst

Circularly Polarized Luminescence Based on Helical Polymers: Structure-Property Relationships and Regulation Mechanisms