Surfactant Mediated Microphase Separation in Miscible Block Copolymer of Poly(4-vinyl pyridine-<italic style="font-style: italic">b</italic>-hydroxybutylacrylate)

Xiang-Yun Xu; Yu-Tong Gao; Ying-Ying Wang; You-Shuang Zhou; Bi-Jin Xiong; Jin-Tao Zhu

doi:10.1007/s10118-022-2876-0

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Surfactant Mediated Microphase Separation in Miscible Block Copolymer of Poly(4-vinyl pyridine-b-hydroxybutylacrylate)

RESEARCH ARTICLE | Updated：2023-05-26

- Surfactant Mediated Microphase Separation in Miscible Block Copolymer of Poly(4-vinyl pyridine-b-hydroxybutylacrylate)
- Surfactant Mediated Microphase Separation in Miscible Block Copolymer of Poly(4-vinyl pyridine-b-hydroxybutylacrylate)
- 高分子科学（英文版） 2023年41卷第6期页码：897-904
- Affiliations：
  
  a.Key Laboratory of Materials Chemistry for Energy Conversion and Storage (HUST) of Ministry of Education, School of Chemistry and Chemical Engineering. Huazhong University of Science and Technology (HUST), Wuhan 430074, China
  b.Key Laboratory of Optoelectronic Chemical Materials and Devices (Ministry of Education), Jianghan University, Wuhan 430056, China
  c.Key Laboratory of Green Preparation and Application of Functional Materials (Ministry of Education), Hubei Key Laboratory of Polymer Materials, Faculty of Materials Science and Engineering, Hubei University, Wuhan 430062, China
- Author bio：
  
  yingying.wang@jhun.edu.cn (Y.Y.W.)
  bjxiong@hust.edu.cn (B.J.X.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 51973077). The authors are grateful to HUST Analytical and Testing Center for their supports on its facilities as well.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-022-2876-0.
- DOI：10.1007/s10118-022-2876-0
  中图分类号：
- 收稿：2022-08-29，
  
  修回：2022-9-20，
  
  录用：2022-9-26，
  
  网络首发：2022-12-29，
  
  纸质出版：2023-06-01
- Accepted：
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Xu, X. Y.; Gao, Y. T.; Wang, Y. Y.; Zhou, Y. S.; Xiong, B. J.; Zhu, J. T. Surfactant mediated microphase separation in miscible block copolymer of poly(4-vinyl pyridine-b-hydroxybutylacrylate). Chinese J. Polym. Sci. 2023, 41, 897–904

Xiang-Yun Xu, Yu-Tong Gao, Ying-Ying Wang, et al. Surfactant Mediated Microphase Separation in Miscible Block Copolymer of Poly(4-vinyl pyridine-b-hydroxybutylacrylate)[J]. Chinese Journal of Polymer Science, 2023, 41(6): 897-904. DOI: 10.1007/s10118-022-2876-0.
Xu, X. Y.; Gao, Y. T.; Wang, Y. Y.; Zhou, Y. S.; Xiong, B. J.; Zhu, J. T. Surfactant mediated microphase separation in miscible block copolymer of poly(4-vinyl pyridine-b-hydroxybutylacrylate). Chinese J. Polym. Sci. 2023, 41, 897–904 DOI： 10.1007/s10118-022-2876-0.

Xiang-Yun Xu, Yu-Tong Gao, Ying-Ying Wang, et al. Surfactant Mediated Microphase Separation in Miscible Block Copolymer of Poly(4-vinyl pyridine-b-hydroxybutylacrylate)[J]. Chinese Journal of Polymer Science, 2023, 41(6): 897-904. DOI: 10.1007/s10118-022-2876-0. DOI：

摘要

Based on the disordered miscible block copolymer P4VP-b-P4HBA

we constructed the ordered microphase separation structure via blending with amphiphilic surfactants. Through the noncovalent interaction between P4VP and different amphiphilic molecules. ordered microstructures were obtained

giving rise to a new perspective for the fabrication of hierarchical nanostructures and nanomaterials from miscible block copolymers.

Abstract

Miscible disordered block copolymers (BCPs) are rarely studied due to the limits in self-assembly into ordered microstructures. Herein

we proposed a facile method for the transformation of disordered miscible BCPs to comb-like BCPs with well-ordered microphase separation structures

via

blending with amphiphilic surfactants. In this work

poly(4-vinyl pyridine-

-hydroxybutylacrylate) (P4VP-

-P4HBA) was applied as a model of miscible disordered BCPs and the microphase separation was induced

via

blending with surfactants of dodecylbenzene sulfonic acid (DBSA) and 3-pentadecylphenol (PDP). The ordered microstructures including spherical and cylindrical morphologies were confirmed by transmission electron microscopy (TEM) and small angle X-ray scattering (SAXS) investigation. These ordered microstructures thermal sensitive

in which ordered and disordered transformation (ODT) was observed in the blend of P4VP-

-P4HBA and PDP whereas it disappeared in the blend of P4VP-

-P4HBA and DBSA. The results show that the thermal stability of the ordered microstructures are strongly depends on the interactions between the miscible BCPs and surfactants

which investigated by

in situ

SAXS and Fourier transform infrared spectrometer (FTIR). The combination of miscible BCPs and surfactant creates a feasible strategy to fabricate ordered nanostructures

which could be employed to develop complicated nanomaterials.

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references

Radjabian,M.;Abetz,V.Advancedporouspolymermembranesfromself-assemblingblockcopolymers. Prog. Polym. Sci. 2020 , 102 ,101219..

Xu,J.;Berg,A.I.;Noheda,B.;Loos,K.Progressandperspectiveonpolymertemplatingofmultifunctionaloxidenanostructures. J. Appl. Phys. 2020 , 128 ,190903..

Liang,Y.;Ouyang,W.;Wang,P.;Zhang,W.;Wang,S.;Tian,L.;Ju,Y.;Li,G.Blockcopolymerassistedtopochemicalpolymerization:afacileandefficientroutetorobustpolymericnanoporousmembranesdecoratedwithversatileaminoacids. Chinese Chem. Lett. 2020 , 31 ,885−889..

Nunes,S.P.;Car,A.Fromcharge-mosaictomicelleself-assembly:blockcopolymermembranesinthelast40years. Ind. Eng. Chem. Res. 2012 , 52 ,993−1003..

Mai,Y.;Eisenberg,A.Self-assemblyofblockcopolymers. Chem. Soc. Rev. 2012 , 41 ,5969−5985..

Li,H.;Xiong,B.;Xu,J.;Zhu,J.Chiraltransfer-dictatedself-assemblyofchiralblockcopolymers. Aggregate 2021 , 2 ,e122..

Widin,J.M.;Schmitt,A.K.;Schmitt,A.L.;Im,K.;Mahanthappa,M.K.Unexpectedconsequencesofblockpolydispersityontheself-assemblyofABAtriblockcopolymers. J. Am. Chem. Soc. 2012 , 134 ,3834−3844..

Gunkel,I.Directingblockcopolymerself-assemblyonpatternedsubstrates. Small 2018 , 14 ,e1802872..

Kao,J.;Tingsanchali,J.;Xu,T.Effectsofinterfacialinteractionsandfilmthicknessonnonequilibriumhierarchicalassembliesofblockcopolymer-basedsupramoleculesinthinfilms. Macromolecules 2011 , 44 ,4392−4400..

Lee,D.;Kim,J.;Ku,K.H.;Li,S.;Shin,J.J.;Kim,B.J.Poly(vinylpyridine)-containingblockcopolymersforsmart,multicompartmentparticles. Polym. Chem. 2022 , 13 ,2570−2588..

Shi,L.Y.;Zhou,Y.;Fan,X.H.;Shen,Z.Remarkablyrichvarietyofnanostructuresandorder-ordertransitionsinarod-coildiblockcopolymer. Macromolecules 2013 , 46 ,5308−5316..

Rattanakawin,P.;Yoshimoto,K.;Hikima,Y.;Nagamine,S.;Jiang,Y.;Tosaka,M.;Yamago,S.;Ohshima,M.ControlofthecellstructureofUV-inducedchemicallyblownnanocellularfoamsbyself-assembledblockcopolymermorphology. Macromolecules 2022 , 55 ,5176−5187..

Shi,H.;Zhao,Y.;Dong,X.;Zhou,Y.;Wang,D.Frustratedcrystallisationandhierarchicalself-assemblybehaviourofcomb-likepolymers. Chem. Soc. Rev. 2013 , 42 ,2075−2099..

Chen,H.L.;Lu,J.S.;Yu,C.H.;Yeh,C.L.;Jeng,U.S.;Chen,W.C.Tetragonallypackedcylinderstructureviahierarchicalassemblyofcomb-coildiblockcopolymer. Macromolecules 2007 , 40 ,3271−3276..

Rancatore,B.J.;Kim,B.;Mauldin,C.E.;Fréchet,J.M.J.;Xu,T.Organicsemiconductor-containingsupramolecules:effectofsmallmoleculecrystallizationandmolecularpacking. Macromolecules 2016 , 49 ,833−843..

Huang,J.;Hall,A.;Jayapurna,I.;Algharbi,S.;Ginzburg,V.;Xu,T.Nanocompositesbasedoncoil-combdiblockcopolymers. Macromolecules 2021 , 54 ,1006−1016..

Chiang,W.S.;Lin,C.H.;Nandan,B.;Yeh,C.L.;Rahman,M.H.;Chen,W.C.;Chen,H.L.Moleculararchitectureeffectontheself-assemblybehaviorofcomb-coilblockcopolymersdisplayinglamellae-within-lamellaemorphology. Macromolecules 2008 , 41 ,8138−8147..

Ikkala,O.;Brinke,G.T.Hierarchicalself-assemblyinpolymericcomplexes:towardsfunctionalmaterials. Chem. Commun. 2004 , 19 ,2131−2137..

Lee,Y.H.;Chang,C.J.;Yang,Y.L.;Chiang,C.J.;Lee,Y.P.;Shen,C.;Tsai,K.T.;Chen,Y.F.;Dai,C.A.Phasetransformationandself-assemblybehaviorofsupramolecularrod-combblockcopolymers. Polymer 2014 , 55 ,2481−2490..

Hanski,S.;Houbenov,N.;Ruokolainen,J.;Chondronicola,D.;Iatrou,H.;Hadjichristidis,N.;Ikkala,O.Hierarchicalionicself-assemblyofrod-combblockcopolypeptide-surfactantcomplexes. Biomacromolecules 2006 , 7 ,3379−3384..

Korhonen,J.T.;Verho,T.;Rannou,P.;Ikkala,O.Self-assemblyandhierarchiesinpyridine-containinghomopolymersandblockcopolymerswithhydrogen-bondedcholestericside-chains. Macromolecules 2010 , 43 ,1507−1514..

Ikkala,O.;Brinke,G.T.Functionalmaterialsbasedonself-assemblyofpolymericsupramolecules. Science 2002 , 295 ,2407−2409..

Bai,P.;Kim,M.I.;Xu,T.Thermallycontrolledmorphologiesinablockcopolymersupramolecule via nonreversibleorder-ordertransitions. Macromolecules 2013 , 46 ,5531−5537..

Ruokolainen,J.;Makinen,R.;Torkkeli,M.;Makela,T.;Serimaa,R.;Brinke,G.T.;Ikkala,O.Switchingsupramolecularpolymericmaterialswithmultiplelengthscales. Science 1998 , 280 ,557−560..

Tillmann,S.D.;HermidaMerino,D.;Winter,M.;CekicLaskovic,I.;Loos,K.;NanoporouspolymerfoamsderivedfromhighmolecularPS- b -P4VP(PDP) x fortemplate-directedsynthesisapproaches. RSC Adv. 2016 , 6 ,52998−53003..

Chang,B.S.;Ma,L.;He,M.;Xu,T.NMRstudiesofblockcopolymer-basedsupramoleculesinsolution. ACS Macro Lett. 2020 , 9 ,1060−1066..

Quintieri,G.;Saccone,M.;Spengler,M.;Giese,M.;Groschel,A.H.SupramolecularmodificationofABCtriblockterpolymersinconfinementassembly. Nanomaterials 2018 , 8 ,8121029..

Huang,W.H.;Chen,P.Y.;Tung,S.H.Effectsofannealingsolventsonthemorphologyofblockcopolymer-basedsupramolecularthinfilms. Macromolecules 2012 , 45 ,1562−1569..

Vukovic,I.;Brinke,G.T.;Loos,K.HexagonallyperforatedlayermorphologyinPS- b -P4VP(PDP)supramolecules. Macromolecules 2012 , 45 ,9409−9418..

Zhu,J.T.;Yu,H.Z.;Jiang,W.MorphologicaltransitionofaggregatesfromABAamphiphilictriblockcopolymerinducedbyhydrogenbonding. Macromolecules 2005 , 38 ,7492−7501..

Lin,I.H.;Kuo,S.W.;Chang,F.C.Self-assemblystructuresthroughcompetitiveinteractionsofmisciblecrystalline-amorphousdiblockcopolymer/homopolymerblends. Polymer 2009 , 50 ,5276−5287..

Kuo,S.W.;Tung,P.H.;Chang,F.C.Synthesesandthestudyofstronglyhydrogen-bondedpoly(vinylphenol- b -vinylpyridine)diblockcopolymerthroughanionicpolymerization. Macromolecules 2006 , 39 ,9388−9395..

Cesteros,L.C.;Meaurio,E.;Katime,I.Miscibilityandspecificinteractionsinblendsofpoly(hydroxymethacrylates)withpoly(vinylpyridines). Macromolecules 1993 , 26 ,2323−2330..

Hofman,A.H.;AlberdavanEkenstein,G.O.R.;Woortman,A.J.J.;Brinke,G.T.;Loos,K.Poly(4-vinylpyridine)-block-poly( N -acryloylpiperidine)diblockcopolymers:synthesis,self-assemblyandinteraction. Polym. Chem. 2015 , 6 ,7015−7026..

Tseng,T.C.;Kuo,S.W.Hydrogen-bondingstrengthinfluenceshierarchicalself-assembledstructuresinunusualmiscible/immisciblediblockcopolymerblends. Macromolecules 2018 , 51 ,6451−6459..

Tseng,T.C.;Kuo,S.W.Hydrogenbondinginducesunusualself-assembledstructuresfrommixturesoftwomiscibledisordereddiblockcopolymers. Eur. Polym. J. 2019 , 116 ,361−369..

Tureau,M.S.;Kuan,W.F.;Rong,L.;Hsiao,B.S.;Epps,T.H.Inducingorderfromdisorderedcopolymers:ondemandgenerationoftriblockmorphologiesincludingnetworks. Macromolecules 2012 , 45 ,4599−4605..

Chen,W.C.;Kuo,S.W.;Jeng,U.S.;Chang,F.C.Self-assemblythroughcompetitiveinteractionsofmisciblediblockcopolymer/homopolymerblends: poly(vinylphenol- b -methylmethacrylate)/poly(vinylpyrrolidone)blend. Macromolecules 2008 , 41 ,1401−1410..

Xu,X.Y.;Zhou,Y.S.;Gao,Y.T.;Liu,X.L.;Chen,S.B.;Xiong,B.J.;Wang,Y.Y.;Zhu,J.T.Competitivehydrogenbondinginducedphaseseparationinsupramolecularcomb-shapeddiblockcopolymer. Polymer 2022 , 243 ,124620..

Coleman,M.M.;Graf,J.F.;Painter,P.C.,in Specific interactions and the miscibility of polymer blends .TechnomicPublishing: 1991 ..

Ruokolainen,J.;Brinke,G.T.;Ikkala,O.Mesomorphicstructuresinflexiblepolymer-surfactantsystemsduetohydrogenbonding:poly(4-vinylpyridine)-pentadecylphenol. Macromolecules 1996 , 29 ,3409−3415..

Luyten,M.C.;Serimaa,R.;Brinke,G.T.;Ruokolainen,J.;Ikkala,O.;Crystallizationandcocrystallizationinsupramolecularcombcopolymer-likesystems:blendsofpoly(4-vinylpyridine)andpentadecylphenol. Macromolecules 1999 , 32 ,4404−4410..

Ikkala,O.;Ruokolainen,J.;Brinke,G.T.;Torkkeli,M.;Serimaa,R.Mesomorphicstateofpoly(vinylpyridine)-dodecylbenzene-sulfonicacidcomplexesinbulkandinxylenesolution. Macromolecules 1995 , 28 ,7088−7094..

Hofman,A.H.;Chen,Y.;Brinke,G.T.;Loos,K.Interactionstrengthinpoly(4-vinylpyridine)- n -alkylphenolsupramolecularcomb-shapedcopolymers. Macromolecules 2015 , 48 ,1554−1562..

Faber,M.;Hofman,A.H.;Polushkin,E.;vanEkenstein,G.A.;Seitsonen,J.;Ruokolainen,J.;Loos,K.;Brinke,G.T.Hierarchicalself-assemblyinsupramoleculardouble-combdiblockcopolymercomplexes. Macromolecules 2013 , 46 ,500−517..

Xiong,B.J.;Chen,Z.X.;Kang,J.Micro-macroscalerelationshipincreepdeformationofultrahighmolecularweightpolyethylene. Chinese J. Polym. Sci. 2021 , 39 ,1665−1672..

Hofman,A.H.;Reza,M.;Ruokolainen,J.;Brinke,G.T.;Loos,K.Hierarchicalself-assemblyofsymmetricsupramoleculardouble-combdiblockcopolymers:acombdensitystudy. Macromolecules 2014 , 47 ,5913−5925..

Nandan,B.;Lee,C.H.;Chen,H.L.;Chen,W.C.Moleculararchitectureeffectonmicrophaseseparationinsupramolecularcomb-coilcomplexesofpolystyrene-block-poly(2-vinylpyridine)withdodecylbenzenesulfonicacid:A n B n heteroarmstarcopolymer. Macromolecules 2006 , 39 ,4460−4468..

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Surfactant Mediated Microphase Separation in Miscible Block Copolymer of Poly(4-vinyl pyridine-b-hydroxybutylacrylate)

Surfactant Mediated Microphase Separation in Miscible Block Copolymer of Poly(4-vinyl pyridine-b-hydroxybutylacrylate)

DOI：10.1007/s10118-022-2876-0

摘要

Abstract

关键词

Keywords

references