Surfactant Mediated Microphase Separation in Miscible Block Copolymer of Poly(4-vinyl pyridine-<italic style="font-style: italic">b</italic>-hydroxybutylacrylate)

Xiang-Yun Xu; Yu-Tong Gao; Ying-Ying Wang; You-Shuang Zhou; Bi-Jin Xiong; Jin-Tao Zhu

doi:10.1007/s10118-022-2876-0

Your Location：

Home >

Browse articles >

Surfactant Mediated Microphase Separation in Miscible Block Copolymer of Poly(4-vinyl pyridine-b-hydroxybutylacrylate)

RESEARCH ARTICLE | Updated：2023-05-26

- Surfactant Mediated Microphase Separation in Miscible Block Copolymer of Poly(4-vinyl pyridine-b-hydroxybutylacrylate)
  Enhanced Publication
- Surfactant Mediated Microphase Separation in Miscible Block Copolymer of Poly(4-vinyl pyridine-b-hydroxybutylacrylate)
- 高分子科学（英文版） 2023年41卷第6期页码：897-904
- Affiliations：
  
  a.Key Laboratory of Materials Chemistry for Energy Conversion and Storage (HUST) of Ministry of Education, School of Chemistry and Chemical Engineering. Huazhong University of Science and Technology (HUST), Wuhan 430074, China
  b.Key Laboratory of Optoelectronic Chemical Materials and Devices (Ministry of Education), Jianghan University, Wuhan 430056, China
  c.Key Laboratory of Green Preparation and Application of Functional Materials (Ministry of Education), Hubei Key Laboratory of Polymer Materials, Faculty of Materials Science and Engineering, Hubei University, Wuhan 430062, China
- Author bio：
  
  yingying.wang@jhun.edu.cn (Y.Y.W.)
  bjxiong@hust.edu.cn (B.J.X.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 51973077). The authors are grateful to HUST Analytical and Testing Center for their supports on its facilities as well.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-022-2876-0.
- DOI：10.1007/s10118-022-2876-0
  中图分类号：
Scan for full text
Surfactant Mediated Microphase Separation in Miscible Block Copolymer of Poly(4-vinyl pyridine-b-hydroxybutylacrylate)[J]. 高分子科学（英文版）, 2023,41(6):897-904.

Xiang-Yun Xu, Yu-Tong Gao, Ying-Ying Wang, et al. Surfactant Mediated Microphase Separation in Miscible Block Copolymer of Poly(4-vinyl pyridine-b-hydroxybutylacrylate)[J]. Chinese Journal of Polymer Science, 2023,41(6):897-904.
Surfactant Mediated Microphase Separation in Miscible Block Copolymer of Poly(4-vinyl pyridine-b-hydroxybutylacrylate)[J]. 高分子科学（英文版）, 2023,41(6):897-904. DOI： 10.1007/s10118-022-2876-0.

Xiang-Yun Xu, Yu-Tong Gao, Ying-Ying Wang, et al. Surfactant Mediated Microphase Separation in Miscible Block Copolymer of Poly(4-vinyl pyridine-b-hydroxybutylacrylate)[J]. Chinese Journal of Polymer Science, 2023,41(6):897-904. DOI： 10.1007/s10118-022-2876-0.

摘要

Based on the disordered miscible block copolymer P4VP-b-P4HBA, we constructed the ordered microphase separation structure via blending with amphiphilic surfactants. Through the noncovalent interaction between P4VP and different amphiphilic molecules. ordered microstructures were obtained, giving rise to a new perspective for the fabrication of hierarchical nanostructures and nanomaterials from miscible block copolymers.

Abstract

Miscible disordered block copolymers (BCPs) are rarely studied due to the limits in self-assembly into ordered microstructures. Herein, we proposed a facile method for the transformation of disordered miscible BCPs to comb-like BCPs with well-ordered microphase separation structures ,via, blending with amphiphilic surfactants. In this work, poly(4-vinyl pyridine-,b,-hydroxybutylacrylate) (P4VP-,b,-P4HBA) was applied as a model of miscible disordered BCPs and the microphase separation was induced ,via, blending with surfactants of dodecylbenzene sulfonic acid (DBSA) and 3-pentadecylphenol (PDP). The ordered microstructures including spherical and cylindrical morphologies were confirmed by transmission electron microscopy (TEM) and small angle X-ray scattering (SAXS) investigation. These ordered microstructures thermal sensitive, in which ordered and disordered transformation (ODT) was observed in the blend of P4VP-,b,-P4HBA and PDP whereas it disappeared in the blend of P4VP-,b,-P4HBA and DBSA. The results show that the thermal stability of the ordered microstructures are strongly depends on the interactions between the miscible BCPs and surfactants, which investigated by,in situ, SAXS and Fourier transform infrared spectrometer (FTIR). The combination of miscible BCPs and surfactant creates a feasible strategy to fabricate ordered nanostructures, which could be employed to develop complicated nanomaterials.

关键词

Keywords

Miscible block copolymerComb-like polymerMicro-phase separationSurfactantSupramolecular interaction

references

Radjabian,M.;Abetz,V.Advancedporouspolymermembranesfromself-assemblingblockcopolymers.Prog. Polym. Sci.2020,102,101219..

Xu,J.;Berg,A.I.;Noheda,B.;Loos,K.Progressandperspectiveonpolymertemplatingofmultifunctionaloxidenanostructures.J. Appl. Phys.2020,128,190903..

Liang,Y.;Ouyang,W.;Wang,P.;Zhang,W.;Wang,S.;Tian,L.;Ju,Y.;Li,G.Blockcopolymerassistedtopochemicalpolymerization:afacileandefficientroutetorobustpolymericnanoporousmembranesdecoratedwithversatileaminoacids.Chinese Chem. Lett.2020,31,885−889..

Nunes,S.P.;Car,A.Fromcharge-mosaictomicelleself-assembly:blockcopolymermembranesinthelast40years.Ind. Eng. Chem. Res.2012,52,993−1003..

Mai,Y.;Eisenberg,A.Self-assemblyofblockcopolymers.Chem. Soc. Rev.2012,41,5969−5985..

Li,H.;Xiong,B.;Xu,J.;Zhu,J.Chiraltransfer-dictatedself-assemblyofchiralblockcopolymers.Aggregate2021,2,e122..

Widin,J.M.;Schmitt,A.K.;Schmitt,A.L.;Im,K.;Mahanthappa,M.K.Unexpectedconsequencesofblockpolydispersityontheself-assemblyofABAtriblockcopolymers.J. Am. Chem. Soc.2012,134,3834−3844..

Gunkel,I.Directingblockcopolymerself-assemblyonpatternedsubstrates.Small2018,14,e1802872..

Kao,J.;Tingsanchali,J.;Xu,T.Effectsofinterfacialinteractionsandfilmthicknessonnonequilibriumhierarchicalassembliesofblockcopolymer-basedsupramoleculesinthinfilms.Macromolecules2011,44,4392−4400..

Lee,D.;Kim,J.;Ku,K.H.;Li,S.;Shin,J.J.;Kim,B.J.Poly(vinylpyridine)-containingblockcopolymersforsmart,multicompartmentparticles.Polym. Chem.2022,13,2570−2588..

Shi,L.Y.;Zhou,Y.;Fan,X.H.;Shen,Z.Remarkablyrichvarietyofnanostructuresandorder-ordertransitionsinarod-coildiblockcopolymer.Macromolecules2013,46,5308−5316..

Rattanakawin,P.;Yoshimoto,K.;Hikima,Y.;Nagamine,S.;Jiang,Y.;Tosaka,M.;Yamago,S.;Ohshima,M.ControlofthecellstructureofUV-inducedchemicallyblownnanocellularfoamsbyself-assembledblockcopolymermorphology.Macromolecules2022,55,5176−5187..

Shi,H.;Zhao,Y.;Dong,X.;Zhou,Y.;Wang,D.Frustratedcrystallisationandhierarchicalself-assemblybehaviourofcomb-likepolymers.Chem. Soc. Rev.2013,42,2075−2099..

Chen,H.L.;Lu,J.S.;Yu,C.H.;Yeh,C.L.;Jeng,U.S.;Chen,W.C.Tetragonallypackedcylinderstructureviahierarchicalassemblyofcomb-coildiblockcopolymer.Macromolecules2007,40,3271−3276..

Rancatore,B.J.;Kim,B.;Mauldin,C.E.;Fréchet,J.M.J.;Xu,T.Organicsemiconductor-containingsupramolecules:effectofsmallmoleculecrystallizationandmolecularpacking.Macromolecules2016,49,833−843..

Huang,J.;Hall,A.;Jayapurna,I.;Algharbi,S.;Ginzburg,V.;Xu,T.Nanocompositesbasedoncoil-combdiblockcopolymers.Macromolecules2021,54,1006−1016..

Chiang,W.S.;Lin,C.H.;Nandan,B.;Yeh,C.L.;Rahman,M.H.;Chen,W.C.;Chen,H.L.Moleculararchitectureeffectontheself-assemblybehaviorofcomb-coilblockcopolymersdisplayinglamellae-within-lamellaemorphology.Macromolecules2008,41,8138−8147..

Ikkala,O.;Brinke,G.T.Hierarchicalself-assemblyinpolymericcomplexes:towardsfunctionalmaterials.Chem. Commun.2004,19,2131−2137..

Lee,Y.H.;Chang,C.J.;Yang,Y.L.;Chiang,C.J.;Lee,Y.P.;Shen,C.;Tsai,K.T.;Chen,Y.F.;Dai,C.A.Phasetransformationandself-assemblybehaviorofsupramolecularrod-combblockcopolymers.Polymer2014,55,2481−2490..

Hanski,S.;Houbenov,N.;Ruokolainen,J.;Chondronicola,D.;Iatrou,H.;Hadjichristidis,N.;Ikkala,O.Hierarchicalionicself-assemblyofrod-combblockcopolypeptide-surfactantcomplexes.Biomacromolecules2006,7,3379−3384..

Korhonen,J.T.;Verho,T.;Rannou,P.;Ikkala,O.Self-assemblyandhierarchiesinpyridine-containinghomopolymersandblockcopolymerswithhydrogen-bondedcholestericside-chains.Macromolecules2010,43,1507−1514..

Ikkala,O.;Brinke,G.T.Functionalmaterialsbasedonself-assemblyofpolymericsupramolecules.Science2002,295,2407−2409..

Bai,P.;Kim,M.I.;Xu,T.Thermallycontrolledmorphologiesinablockcopolymersupramoleculevianonreversibleorder-ordertransitions.Macromolecules2013,46,5531−5537..

Ruokolainen,J.;Makinen,R.;Torkkeli,M.;Makela,T.;Serimaa,R.;Brinke,G.T.;Ikkala,O.Switchingsupramolecularpolymericmaterialswithmultiplelengthscales.Science1998,280,557−560..

Tillmann,S.D.;HermidaMerino,D.;Winter,M.;CekicLaskovic,I.;Loos,K.;NanoporouspolymerfoamsderivedfromhighmolecularPS-b-P4VP(PDP)xfortemplate-directedsynthesisapproaches.RSC Adv.2016,6,52998−53003..

Chang,B.S.;Ma,L.;He,M.;Xu,T.NMRstudiesofblockcopolymer-basedsupramoleculesinsolution.ACS Macro Lett.2020,9,1060−1066..

Quintieri,G.;Saccone,M.;Spengler,M.;Giese,M.;Groschel,A.H.SupramolecularmodificationofABCtriblockterpolymersinconfinementassembly.Nanomaterials2018,8,8121029..

Huang,W.H.;Chen,P.Y.;Tung,S.H.Effectsofannealingsolventsonthemorphologyofblockcopolymer-basedsupramolecularthinfilms.Macromolecules2012,45,1562−1569..

Vukovic,I.;Brinke,G.T.;Loos,K.HexagonallyperforatedlayermorphologyinPS-b-P4VP(PDP)supramolecules.Macromolecules2012,45,9409−9418..

Zhu,J.T.;Yu,H.Z.;Jiang,W.MorphologicaltransitionofaggregatesfromABAamphiphilictriblockcopolymerinducedbyhydrogenbonding.Macromolecules2005,38,7492−7501..

Lin,I.H.;Kuo,S.W.;Chang,F.C.Self-assemblystructuresthroughcompetitiveinteractionsofmisciblecrystalline-amorphousdiblockcopolymer/homopolymerblends.Polymer2009,50,5276−5287..

Kuo,S.W.;Tung,P.H.;Chang,F.C.Synthesesandthestudyofstronglyhydrogen-bondedpoly(vinylphenol-b-vinylpyridine)diblockcopolymerthroughanionicpolymerization.Macromolecules2006,39,9388−9395..

Cesteros,L.C.;Meaurio,E.;Katime,I.Miscibilityandspecificinteractionsinblendsofpoly(hydroxymethacrylates)withpoly(vinylpyridines).Macromolecules1993,26,2323−2330..

Hofman,A.H.;AlberdavanEkenstein,G.O.R.;Woortman,A.J.J.;Brinke,G.T.;Loos,K.Poly(4-vinylpyridine)-block-poly(N-acryloylpiperidine)diblockcopolymers:synthesis,self-assemblyandinteraction.Polym. Chem.2015,6,7015−7026..

Tseng,T.C.;Kuo,S.W.Hydrogen-bondingstrengthinfluenceshierarchicalself-assembledstructuresinunusualmiscible/immisciblediblockcopolymerblends.Macromolecules2018,51,6451−6459..

Tseng,T.C.;Kuo,S.W.Hydrogenbondinginducesunusualself-assembledstructuresfrommixturesoftwomiscibledisordereddiblockcopolymers.Eur. Polym. J.2019,116,361−369..

Tureau,M.S.;Kuan,W.F.;Rong,L.;Hsiao,B.S.;Epps,T.H.Inducingorderfromdisorderedcopolymers:ondemandgenerationoftriblockmorphologiesincludingnetworks.Macromolecules2012,45,4599−4605..

Chen,W.C.;Kuo,S.W.;Jeng,U.S.;Chang,F.C.Self-assemblythroughcompetitiveinteractionsofmisciblediblockcopolymer/homopolymerblends: poly(vinylphenol-b-methylmethacrylate)/poly(vinylpyrrolidone)blend.Macromolecules2008,41,1401−1410..

Xu,X.Y.;Zhou,Y.S.;Gao,Y.T.;Liu,X.L.;Chen,S.B.;Xiong,B.J.;Wang,Y.Y.;Zhu,J.T.Competitivehydrogenbondinginducedphaseseparationinsupramolecularcomb-shapeddiblockcopolymer.Polymer2022,243,124620..

Coleman,M.M.;Graf,J.F.;Painter,P.C.,inSpecific interactions and the miscibility of polymer blends.TechnomicPublishing:1991..

Ruokolainen,J.;Brinke,G.T.;Ikkala,O.Mesomorphicstructuresinflexiblepolymer-surfactantsystemsduetohydrogenbonding:poly(4-vinylpyridine)-pentadecylphenol.Macromolecules1996,29,3409−3415..

Luyten,M.C.;Serimaa,R.;Brinke,G.T.;Ruokolainen,J.;Ikkala,O.;Crystallizationandcocrystallizationinsupramolecularcombcopolymer-likesystems:blendsofpoly(4-vinylpyridine)andpentadecylphenol.Macromolecules1999,32,4404−4410..

Ikkala,O.;Ruokolainen,J.;Brinke,G.T.;Torkkeli,M.;Serimaa,R.Mesomorphicstateofpoly(vinylpyridine)-dodecylbenzene-sulfonicacidcomplexesinbulkandinxylenesolution.Macromolecules1995,28,7088−7094..

Hofman,A.H.;Chen,Y.;Brinke,G.T.;Loos,K.Interactionstrengthinpoly(4-vinylpyridine)-n-alkylphenolsupramolecularcomb-shapedcopolymers.Macromolecules2015,48,1554−1562..

Faber,M.;Hofman,A.H.;Polushkin,E.;vanEkenstein,G.A.;Seitsonen,J.;Ruokolainen,J.;Loos,K.;Brinke,G.T.Hierarchicalself-assemblyinsupramoleculardouble-combdiblockcopolymercomplexes.Macromolecules2013,46,500−517..

Xiong,B.J.;Chen,Z.X.;Kang,J.Micro-macroscalerelationshipincreepdeformationofultrahighmolecularweightpolyethylene.Chinese J. Polym. Sci.2021,39,1665−1672..

Hofman,A.H.;Reza,M.;Ruokolainen,J.;Brinke,G.T.;Loos,K.Hierarchicalself-assemblyofsymmetricsupramoleculardouble-combdiblockcopolymers:acombdensitystudy.Macromolecules2014,47,5913−5925..

Nandan,B.;Lee,C.H.;Chen,H.L.;Chen,W.C.Moleculararchitectureeffectonmicrophaseseparationinsupramolecularcomb-coilcomplexesofpolystyrene-block-poly(2-vinylpyridine)withdodecylbenzenesulfonicacid:AnBnheteroarmstarcopolymer.Macromolecules2006,39,4460−4468..

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Self-assembled Conformations of a Core-shell Comb-like Chain with Adjustable Architectural Parameters

Azobenzene Based Photo-responsive Mechanical Actuator Fabricated by Intermolecular H-bond Interaction

Supramolecular Polymer Emulsifiers for One-step Complex Emulsions

Surfactant Mediated Microphase Separation in Miscible Block Copolymer of Poly(4-vinyl pyridine-b-hydroxybutylacrylate)

Surfactant Mediated Microphase Separation in Miscible Block Copolymer of Poly(4-vinyl pyridine-b-hydroxybutylacrylate)

DOI：10.1007/s10118-022-2876-0

摘要

Abstract

关键词

Keywords

references