Environmentally Friendly Sizing Strategy for PBO Fiber-reinforced Composites through Building Carbon Nanosphere Coatings

Rong Ling; Shao-Hua Wu; Chun-Cheng Li; Yao-Nan Xiao; Jia-Jian Liu; Bo Zhang

doi:10.1007/s10118-022-2834-x

Your Location：

Home >

Browse articles >

Environmentally Friendly Sizing Strategy for PBO Fiber-reinforced Composites through Building Carbon Nanosphere Coatings

RESEARCH ARTICLE | Updated：2023-01-06

- Environmentally Friendly Sizing Strategy for PBO Fiber-reinforced Composites through Building Carbon Nanosphere Coatings
- Environmentally Friendly Sizing Strategy for PBO Fiber-reinforced Composites through Building Carbon Nanosphere Coatings
- 高分子科学（英文版） 2023年41卷第2期页码：306-314
- Affiliations：
  
  a.Beijing National Laboratory for Molecular Sciences, Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences (ICCAS), Beijing 100190, China
  b.University of the Chinese Academy of Sciences, Beijing 100049, China
- Author bio：
  
  wushaohua12@iccas.ac.cn (S.H.W.)
  lichch@iccas.ac.cn (C.C.L.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 51903237) and Beijing Natural Science Foundation (No. 2222091).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-022-2834-x.
- DOI：10.1007/s10118-022-2834-x
  中图分类号：
- 收稿：2022-05-09，
  
  修回：2022-6-22，
  
  录用：2022-6-29，
  
  网络首发：2022-10-08，
  
  纸质出版：2023-02-01
- Accepted：
Scan QR Code
Ling, R.; Wu, S. H.; Li, C. C.; Xiao, Y. N.; Liu, J. J.; Zhang, B. Environmentally friendly sizing strategy for PBO fiber-reinforced composites through building carbon nanosphere coatings. Chinese J. Polym. Sci. 2023, 41, 306–314

Rong Ling, Shao-Hua Wu, Chun-Cheng Li, et al. Environmentally Friendly Sizing Strategy for PBO Fiber-reinforced Composites through Building Carbon Nanosphere Coatings[J]. Chinese Journal of Polymer Science, 2023, 41(2): 306-314.
Ling, R.; Wu, S. H.; Li, C. C.; Xiao, Y. N.; Liu, J. J.; Zhang, B. Environmentally friendly sizing strategy for PBO fiber-reinforced composites through building carbon nanosphere coatings. Chinese J. Polym. Sci. 2023, 41, 306–314 DOI： 10.1007/s10118-022-2834-x.

Rong Ling, Shao-Hua Wu, Chun-Cheng Li, et al. Environmentally Friendly Sizing Strategy for PBO Fiber-reinforced Composites through Building Carbon Nanosphere Coatings[J]. Chinese Journal of Polymer Science, 2023, 41(2): 306-314. DOI： 10.1007/s10118-022-2834-x.

摘要

A functional carbon nanosphere coating with high activity was constructed on the surface of PBO fibers by treatment with an environmentally friendly and industrially scalable waterborne sizing agent. The sized PBO fibers not only show significantly improved interfacial properties

but also retain the excellent mechanical properties.

Abstract

Sizing treatment has shown great potential in improving the interfacial properties of poly(

-phenylene benzodioxazole) (PBO) fiber-reinforced composites

but is severely limited due to the use of flammable and explosive organic solvents. Herein

a new high-efficiency waterborne sizing agent has been developed by using functionalized carbon nanospheres (CNSs) as a nano-reinforcement. Due to abundant oxygen-containing groups

the CNSs greatly improves the surface activity

wettability

and roughness of the PBO fibers. As a result

the interfacial shear strength of the CNSs sized fiber-reinforced composite increases by 79.6% compared with that of the pristine fiber-reinforced composite. Moreover

the excellent mechanical and thermal properties of the PBO fibers remain almost unchanged after sizing treatment. Thus

this work provides an environmentally friendly and scalable method for constructing a strong interface between the PBO fibers and the matrix resins

which makes sense in promoting the application of PBO fiber-reinforced composites in aerospace and military industries.

关键词

Keywords

references

Chen, L.; Du, Y.; Huang, Y.; Ng, P. F.; Fei, B . Facile fabrication of hierarchically structured PBO-Ni(OH) 2 /NiOOH fibers for enhancing interfacial strength in PBO fiber/epoxy resin composites . Compos. Sci. Technol. , 2016 . 129 86 - 92 . DOI: 10.1016/j.compscitech.2016.04.013 http://doi.org/10.1016/j.compscitech.2016.04.013 .

Hao, X.; Zhu, J.; Jiang, X.; Wu, H.; Qiao, J.; Sun, W.; Wang, Z.; Sun, K . Ultrastrong polyoxyzole nanofiber membranes for dendrite-proof and heat-resistant battery separators . Nano Lett. , 2016 . 16 2981 - 2987 . DOI: 10.1021/acs.nanolett.5b05133 http://doi.org/10.1021/acs.nanolett.5b05133 .

Luo, L.; Hong, D.; Zhang, L.; Cheng, Z.; Liu, X . Surface modification of PBO fibers by direct fluorination and corresponding chemical reaction mechanism . Compos. Sci. Technol. , 2018 . 165 106 - 114 . DOI: 10.1016/j.compscitech.2018.06.014 http://doi.org/10.1016/j.compscitech.2018.06.014 .

Yu, Z.; Wu, S.; Li, C.; Xiao, Y.; Zheng, L.; Liu, J.; Zhang, B . Ultra-low dielectric constant fluorinated graphene/polybenzoxazole composite films with excellent thermal stabilities and mechanical properties . Compos. Part A-Appl. Sci. Manuf. , 2021 . 145 106387 DOI: 10.1016/j.compositesa.2021.106387 http://doi.org/10.1016/j.compositesa.2021.106387 .

Lu, K.; Ge, X.; Wei, Z.; Li, G.; Yang, X.; Liu, H . Synergistically enhanced ultraviolet aging resistance and interfacial adhesion of poly( p -phenylene benzobisoxazole) fiber with soluble naphthalimide sizing . Polym. Compos. , 2021 . 42 2122 - 2134 . DOI: 10.1002/pc.25964 http://doi.org/10.1002/pc.25964 .

Liu, Z.; Zhang, J.; Tang, Y.; Xu, J.; Ma, J.; Kong, J.; Gu, J . Optimization of PBO fibers/cyanate ester wave-transparent laminated composites via incorporation of a fluoride-containing linear interfacial compatibilizer . Compos. Sci. Technol. , 2021 . 210 108838 DOI: 10.1016/j.compscitech.2021.108838 http://doi.org/10.1016/j.compscitech.2021.108838 .

Chen, L.; Hu, Z.; Wu, Z.; Wu, G.; Ma, L.; Zhang, C.; Huang, Y . POSS-bound ZnO nanowires as interphase for enhancing interfacial strength and hydrothermal aging resistance of PBO fiber/epoxy resin composites . Compos. Part A-Appl. Sci. Manuf. , 2017 . 96 1 - 8 . DOI: 10.1016/j.compositesa.2017.02.013 http://doi.org/10.1016/j.compositesa.2017.02.013 .

Tang, L.; Zhang, J.; Wu, C.; Tang, Y.; Ma, H.; Kong, J.; Gu, J . UV etched random copolymer membrane coated PBO fibers/cyanate ester wave-transparent laminated composites . Compos. Part B-Eng. , 2021 . 212 108680 DOI: 10.1016/j.compositesb.2021.108680 http://doi.org/10.1016/j.compositesb.2021.108680 .

Song, B.; Liu, Z.; Pan, D.; Wang, T.; Wang, L.; Dong, B.; Guo, Z . Layer-by-layer constructing interface with rigid-flexible transition structure for improving interfacial adhesion of PBO fiber composites . Compos. Commun. , 2020 . 22 100466 DOI: 10.1016/j.coco.2020.100466 http://doi.org/10.1016/j.coco.2020.100466 .

Liu, Z.; Fan, X.; Cheng, L.; Zhang, J.; Tang, L.; Tang, Y.; Kong, J.; Gu, J . Hybrid polymer membrane functionalized PBO fibers/cyanate esters wave-transparent laminated composites . Adv. Fiber Mater. , 2022 . 4 520 - 531 . DOI: 10.1007/s42765-021-00125-4 http://doi.org/10.1007/s42765-021-00125-4 .

Chen, L.; Du, Y.; Huang, Y.; Wu, F.; Cheng, H. M.; Fei, B.; Xin, J. H . Hierarchical poly(p-phenylene benzobisoxazole)/graphene oxide reinforcement with multifunctional and biomimic middle layer . Compos. Part A-Appl. Sci. Manuf. , 2016 . 88 123 - 130 . DOI: 10.1016/j.compositesa.2016.05.017 http://doi.org/10.1016/j.compositesa.2016.05.017 .

Chen, Y.; Zhang, S.; Liu, X.; Pei, Q.; Qian, J.; Zhuang, Q.; Han, Z . Preparation of solution-processable reduced graphene oxide/polybenzoxazole nanocomposites with improved dielectric properties . Macromolecules , 2015 . 48 365 - 372 . DOI: 10.1021/ma502326v http://doi.org/10.1021/ma502326v .

Li, Y. W.; Zhao, F.; Song, Y. J.; Li, J.; Hu, Z.; Huang, Y. D . Interfacial microstructure and properties of poly(phenylene benzobisoxazole) fiber grafted with graphene oxide via solvothermal method . Appl. Surf. Sci. , 2013 . 266 306 - 312 . DOI: 10.1016/j.apsusc.2012.12.016 http://doi.org/10.1016/j.apsusc.2012.12.016 .

Song, B.; Liu, Z.; Chen, L.; Ma, L.; Huang, Y . Poly( p -phenylene benzobisoxazole) fiber/epoxy composites reinforced with carbon nanotubes and graphene oxide for enhanced interfacial adhesion and mechanical strength . ACS Appl. Nano Mater. , 2021 . 4 12158 - 12169 . DOI: 10.1021/acsanm.1c02679 http://doi.org/10.1021/acsanm.1c02679 .

Wang, M.; Wang, C.; Song, Y.; Zhang, C.; Shao, L.; Jiang, Z.; Huang, Y . Facile method to functionalize graphene oxide nanoribbons and its application to poly( p -phenylene benzobisoxazole) composite . Compos. Sci. Technol. , 2018 . 165 124 - 130 . DOI: 10.1016/j.compscitech.2018.03.043 http://doi.org/10.1016/j.compscitech.2018.03.043 .

Song, B.; Liu, Z.; Wang, T.; Wang, L . Grafting of CNTs onto the surface of PBO fibers at high-density for enhancing interfacial adhesion, mechanical properties and stability of composites . J. Colloid Interface Sci. , 2021 . 598 113 - 125 . DOI: 10.1016/j.jcis.2021.04.021 http://doi.org/10.1016/j.jcis.2021.04.021 .

Guo, J.; Mao, B.; Li, J.;Wang, X.; Yang, X . Rethinking the reaction pathways of chemical reduction of graphene oxide . Carbon , 2021 . 171 963 - 967 . DOI: 10.1016/j.carbon.2020.09.049 http://doi.org/10.1016/j.carbon.2020.09.049 .

Hu, Z.; Lu, F.; Liu, Y.; Zhao, L.; Yu, L.; Xu, X.; Yuan, W.; Zhang, Q.; Huang, Y . Construction of anti-ultraviolet "shielding clothes" on poly( p -phenylene benzobisoxazole) fibers: metal organic framework-mediated absorption strategy . ACS Appl. Mater. Interfaces , 2018 . 10 43262 - 43274 . DOI: 10.1021/acsami.8b16845 http://doi.org/10.1021/acsami.8b16845 .

Liu, Z.; Song, B.; Wang, T.; Wang, L . Significant improved interfacial properties of PBO fibers composites by in-situ constructing rigid dendritic polymers on fiber surface . Appl. Surf. Sci. , 2020 . 512 145719 DOI: 10.1016/j.apsusc.2020.145719 http://doi.org/10.1016/j.apsusc.2020.145719 .

Liu, R.; Han, Z.; Li, W.; Li, X.; Zhuang, Q . Improvement of the interfacial shear strength of poly( p -phenylene benzobisoxazole) fiber/epoxy resin composite via a novel surface coating agent . Polym. Compos. , 2016 . 37 1198 - 1205 . DOI: 10.1002/pc.23284 http://doi.org/10.1002/pc.23284 .

Tang, L.; Yang, Z.; Tang, Y.; Zhang, J.; Kong, J.; Gu, J . Facile functionalization strategy of PBO fibres for synchronous improving the mechanical and wave-transparent properties of the PBO fibres/cyanate ester laminated composites . Compos. Part A-Appl. Sci. Manuf. , 2021 . 150 106622 DOI: 10.1016/j.compositesa.2021.106622 http://doi.org/10.1016/j.compositesa.2021.106622 .

Tang, Y.; Dong, W.; Tang, L.; Zhang, Y.; Kong, J.; Gu, J . Fabrication and investigations on the polydopamine/KH-560 functionalized PBO fibers/cyanate ester wave-transparent composites . Compos. Commun. , 2018 . 8 36 - 41 . DOI: 10.1016/j.coco.2018.03.006 http://doi.org/10.1016/j.coco.2018.03.006 .

Yu, L.; Lu, F.; Huang, X.; Liu, Y.; Li, M.; Pan, H.; Wu, L.; Huang, Y.; Hu, Z . Facile interface design strategy for improving the uvioresistant and self-healing properties of poly( p -phenylene benzobisoxazole) fibers . ACS Appl. Mater. Interfaces , 2019 . 11 39292 - 39303 . DOI: 10.1021/acsami.9b11595 http://doi.org/10.1021/acsami.9b11595 .

Wu, S.; Li, C.; Yu, Z.; Ling, R.; Xiao, Y.; Zheng, L.; Liu, J.; Zhang, B . Nondestructive strategy to effectively enhance the interfacial adhesion of PBO/epoxy composites . ACS Appl. Mater. Interfaces , 2020 . 12 45383 - 45393 . DOI: 10.1021/acsami.0c14975 http://doi.org/10.1021/acsami.0c14975 .

Tang, L.; Fan, X.; Tang, Y.; Zhang, J.; Kong, J.; Gu, J . Calcia-doped ceria hybrid coating functionalized PBO fibers with excellent UV resistance and improved interfacial compatibility with cyanate ester resins . Appl. Surf. Sci. , 2021 . 569 151124 DOI: 10.1016/j.apsusc.2021.151124 http://doi.org/10.1016/j.apsusc.2021.151124 .

Liu, J.; Liu, X.; Wang, D.; Wang, H . An important factor affecting the UV aging resistance of PBO fiber foped with nano-TiO 2 : the number of amorphous regions . Polymers , 2019 . 11 869 DOI: 10.3390/polym11050869 http://doi.org/10.3390/polym11050869 .

Steinke, K.; Sodano, H. A . Enhanced interfacial shear strength in ultra-high molecular weight polyethylene epoxy composites through a zinc oxide nanowire interphase . Compos. Sci. Technol. , 2022 . 219 109218 DOI: 10.1016/j.compscitech.2021.109218 http://doi.org/10.1016/j.compscitech.2021.109218 .

Zhu, P.; Liu, B.; Bao, L . Preparation of a sub-100 nm-thick polyetherimide coating layer with nano-TiO 2 particles on poly( p -phenylene benzobisoxazole) fiber surface . J. Appl. Polym. Sci. , 2018 . 135 46852 DOI: 10.1002/app.46852 http://doi.org/10.1002/app.46852 .

Liu, X.; Vadiyar, M. M.; Oh, J. K.; Ye, Z . Designing ultrasmall carbon nanospheres with tailored sizes and textural properties for high-rate high-energy supercapacitors . ACS Appl. Mater. Interfaces , 2021 . 13 32916 - 32929 . DOI: 10.1021/acsami.1c05816 http://doi.org/10.1021/acsami.1c05816 .

Zhu, R.; Li, L.; Wang, Z.; Zhang, S.; Dang, J.; Liu, X.; Wang, H . Adjustable dimensionality of microaggregates of silicon in hollow carbon nanospheres: an efficient pathway for high-performance lithium-ion batteries . ACS Nano , 2022 . 16 1119 - 1133 . DOI: 10.1021/acsnano.1c08866 http://doi.org/10.1021/acsnano.1c08866 .

Zhang, R.; Shi, X.; Tang, L.; Liu, Z.; Zhang, J.; Guo, Y.; Gu, J . Thermally conductive and insulating epoxy composites by synchronously incorporating Si-sol functionalized glass fibers and boron nitride fillers . Chinese J. Polym. Sci. , 2020 . 38 730 - 739 . DOI: 10.1007/s10118-020-2391-0 http://doi.org/10.1007/s10118-020-2391-0 .

Gu, J.; Xu, S.; Zhuang, Q.; Tang, Y.; Kong, J . Hyperbranched polyborosilazane and boron nitride modified cyanate ester composite with low dielectric loss and desirable thermal conductivity . IEEE T. Dielect. El. In. , 2017 . 24 784 - 790 . DOI: 10.1109/TDEI.2017.006299 http://doi.org/10.1109/TDEI.2017.006299 .

浏览量

143

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Durable Anti-fogging and Abrasion-resistant Coatings Based on Polyoxometalates-Hydrophilic Resin Composites with Enhanced Cohesion and Adhesion

From Molecular Defect to Macroscopic Performance: Manipulating Dichroism and Mechanics in Iodine-doped Poly(vinyl alcohol) via Ethylene Incorporation

End-to-End Neuron-inspired Signal Transduction Using Organic Electrochemical Transistors

Epoxy-functionalized Cyclohexane-based Ricinoleate Plasticizer: Synthesis, Performance Evaluation, and Plasticizing Mechanism

One-handed Helical Poly(m-terphenyl acetylene)s with Broad Optical Activity Range from Ultraviolet-Visible to Near-infrared Regions