Polyurethane-polysiloxane Copolymer Compatibilized SiR/TPU TPV with Comfortable Human Touch Toward Wearable Devices

Hong-Fang Zhang; Qian Hao; Hong-Chi Tian; Peng-Jun Yao; Xue-Ying Liu; Bing Yu; Nan-Ying Ning; Ming Tian; Li-Qun Zhang

doi:10.1007/s10118-022-2827-9

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Polyurethane-polysiloxane Copolymer Compatibilized SiR/TPU TPV with Comfortable Human Touch Toward Wearable Devices

RESEARCH ARTICLE | Updated：2023-01-06

- Polyurethane-polysiloxane Copolymer Compatibilized SiR/TPU TPV with Comfortable Human Touch Toward Wearable Devices
- Polyurethane-polysiloxane Copolymer Compatibilized SiR/TPU TPV with Comfortable Human Touch Toward Wearable Devices
- 高分子科学（英文版） 2023年41卷第2期页码：258-266
- Affiliations：
  
  a.Key Laboratory of Carbon Fiber and Functional Polymers, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029, China
  b.Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  c.Shandong Dawn Polymer Material Co., Ltd., Longkou 265700, China
  d.Zhejiang Collaborative Innovation Center for High Value Utilization of Byproducts from Ethylene Project, Ningbo Polytechnic, Ningbo 315800, China
- Author bio：
  
  ningny@mail.buct.edu.cn (N.Y.N.)
  tianm@mail.buct.edu.cn (M.T.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51525301 and 51903009) and the National Key Research & Development Plan (No. 2017YFB0307003). Xueying Liu gratefully acknowledges Chinese Scholarship Council for supporting his PhD study in Chimie ParisTech-PSL Research University, France (No. 202106880002).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-022-2827-9.
- DOI：10.1007/s10118-022-2827-9
  中图分类号：
- 收稿：2022-05-20，
  
  修回：2022-6-13，
  
  录用：2022-6-22，
  
  网络首发：2022-09-26，
  
  纸质出版：2023-02-01
- Accepted：
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Zhang, H. F.; Hao, Q.; Tian, H. C.; Yao, P. J.; Liu, X. Y.; Yu, B.; Ning, N. Y.; Tian, M.; Zhang, L. Q. Polyurethane-polysiloxane copolymer compatibilized SiR/TPU TPV with comfortable human touch toward wearable devices. Chinese J. Polym. Sci. 2023, 41, 258–266

Hong-Fang Zhang, Qian Hao, Hong-Chi Tian, et al. Polyurethane-polysiloxane Copolymer Compatibilized SiR/TPU TPV with Comfortable Human Touch Toward Wearable Devices[J]. Chinese Journal of Polymer Science, 2023, 41(2): 258-266.
Zhang, H. F.; Hao, Q.; Tian, H. C.; Yao, P. J.; Liu, X. Y.; Yu, B.; Ning, N. Y.; Tian, M.; Zhang, L. Q. Polyurethane-polysiloxane copolymer compatibilized SiR/TPU TPV with comfortable human touch toward wearable devices. Chinese J. Polym. Sci. 2023, 41, 258–266 DOI： 10.1007/s10118-022-2827-9.

Hong-Fang Zhang, Qian Hao, Hong-Chi Tian, et al. Polyurethane-polysiloxane Copolymer Compatibilized SiR/TPU TPV with Comfortable Human Touch Toward Wearable Devices[J]. Chinese Journal of Polymer Science, 2023, 41(2): 258-266. DOI： 10.1007/s10118-022-2827-9.

摘要

Polyurethane-polysiloxane copolymer with high content of polysiloxane segment (PU-co-HPSi) shows good compatibilization effect on SiR/TPU blends

and the PU-co-HPSi compatibilized SiR/TPU TPV with comfortable human touch

a fine SiR dispersed phase and good mechanical performance was prepared

facilitating its application in wearable intelligent devices.

Abstract

Because of its softness

wear resistance

biocompatibility

extremely comfortable human touch

thermoplastic vulcanizate (TPV) comprised of silicone rubber (SiR) and thermoplastic polyurethane (TPU) (SiR/TPU TPV) is especially suitable for wearable intelligent devices. Nevertheless

developing good compatibilizer is still required to prepare high performance SiR/TPU TPV. In this study

three kinds of polyurethane-polysiloxane copolymer (PU

-co-

PSi) with different contents of polysiloxane segment were selected

and their compatibilization effect on SiR/TPU blends was studied using nanomechanical mapping technique of AFM. The results show that using PU

-co-

PSi with the highest content of polysiloxane segment (PU

-co-

HPSi)

the interface thickness largely increases

and the average size of SiR dispersed phase largely decreases

indicating its good compatibilization effect. By using PU

-co-

HPSi as compatibilizer

SiR/TPU TPV with a fine SiR dispersed phase and good mechanical performance were successfully prepared. The mechanism on the compatibilization effect of these PU

-co-

PSi on SiR/TPU TPVs was revealed.

关键词

Keywords

references

Shit, S. C.; Shah, P . A review on silicone rubber . Natl. Acad. Sci. Lett. , 2013 . 36 355 - 365 . DOI: 10.1007/s40009-013-0150-2 http://doi.org/10.1007/s40009-013-0150-2 .

Ning, N.; Li, S.; Wu, H.; Tian, H.; Yao, P.; HU, G . H.; Tian, M.; Zhang, L. Preparation, microstructure, and microstructure-properties relationship of thermoplastic vulcanizates (TPVs): a review . Prog. Polym. Sci. , 2018 . 79 61 - 97 . DOI: 10.1016/j.progpolymsci.2017.11.003 http://doi.org/10.1016/j.progpolymsci.2017.11.003 .

Xu, C.; Wang, Y.; Lin, B.; Liang, X.; Chen, Y . Thermoplastic vulcanizate based on poly(vinylidene fluoride) and methyl vinyl silicone rubber by using fluorosilicone rubber as interfacial compatibilizer . Mater. Des. , 2015 . 88 170 - 176 . DOI: 10.1016/j.matdes.2015.08.116 http://doi.org/10.1016/j.matdes.2015.08.116 .

Basuli, U.; Chaki, T. K.; Naskar, K . Influence of Engage® copolymer type on the properties of Engage®/silicone rubber-based thermoplastic dynamic vulcanizates . Express Polym. Lett. , 2008 . 2 846 - 854 . DOI: 10.3144/expresspolymlett.2008.99 http://doi.org/10.3144/expresspolymlett.2008.99 .

El-Hag, A. H.; Simon, L. C.; Jayaram, S. H.; Cherney, E. A . Erosion resistance of nano-filled silicone rubber . IEEE Trans. Dielectr. Electr. Insul. , 2006 . 13 122 - 128 . DOI: 10.1109/TDEI.2006.1593410 http://doi.org/10.1109/TDEI.2006.1593410 .

Huang, C.; Chen, R.; Ke, Q.; Morsi, Y.; Zhang, K.; Mo, X . Electrospun collagen-chitosan-tpu nanofibrous scaffolds for tissue engineered tubular grafts . Colloids Surf. B Biointerfaces , 2011 . 82 307 - 315 . DOI: 10.1016/j.colsurfb.2010.09.002 http://doi.org/10.1016/j.colsurfb.2010.09.002 .

Xu, R.; Luo, G.; Xia, H.; He, W.; Zhao, J.; Liu, B.; Tan, J.; Zhou, J.; Liu, D.; Wang, Y.; Yao, Z.; Zhan, R.; Yang, S.; Wu, J . Novel bilayer wound dressing composed of silicone rubber with particular micropores enhanced wound re-epithelialization and contraction . Biomaterials , 2015 . 40 1 - 11 . DOI: 10.1016/j.biomaterials.2014.10.077 http://doi.org/10.1016/j.biomaterials.2014.10.077 .

Li, Y.; Zhou, B.; Zheng, G.; Liu, X.; Li, T.; Yan, C.; Cheng, C.; Dai, K.; Liu, C.; Shen, C.; Guo, Z . Continuously prepared highly conductive and stretchable SWNT/MWNT synergistically composited electrospun thermoplastic polyurethane yarns for wearable sensing . J. Mater. Chem. C , 2018 . 6 2258 - 2269 . DOI: 10.1039/c7tc04959e http://doi.org/10.1039/c7tc04959e .

Dong, M.; Li, Q.; Liu, H.; Liu, C.; Wujcik, E . K.; Shao, Q.; Ding, T.; Mai, X.; Shen, C.; Guo, Z. Thermoplastic polyurethane-carbon black nanocomposite coating: fabrication and solid particle erosion resistance . Polymer , 2018 . 158 381 - 390 . DOI: 10.1016/j.polymer.2018.11.003 http://doi.org/10.1016/j.polymer.2018.11.003 .

Liu, G.; Xiangli, F.; Wei, W.; Liu, S.; Jin, W . Improved performance of PDMS/ceramic composite pervaporation membranes by ZSM-5 homogeneously dispersed in PDMS via a surface graft/coating approach . Chem. Eng. J. , 2011 . 174 495 - 503 . DOI: 10.1016/j.cej.2011.06.004 http://doi.org/10.1016/j.cej.2011.06.004 .

Wei, W. C.; Deng, C.; Huang, S. C.; Wei, Y. X.; Wang, Y. Z . Nickel-Schiff base decorated graphene for simultaneously enhancing the electroconductivity, fire resistance, and mechanical properties of a polyurethane elastomer . J. Mater. Chem. A , 2018 . 6 8643 - 8654 . DOI: 10.1039/c8ta01287c http://doi.org/10.1039/c8ta01287c .

Kaur, B.; Kumar, S.; Mondal, T.; Phukan, M.; Saxena, A.; Dalavoy, T.; Bhowmick, A. K.; Bhat, S . Controlled methodology for development of a polydimethylsiloxane-polytetrafluoroethylene-based composite for enhanced chemical resistance: a structure-property relationship study . ACS Omega , 2020 . 5 22482 - 22493 . DOI: 10.1021/acsomega.0c02585 http://doi.org/10.1021/acsomega.0c02585 .

Yang, Z.; Peng, H.; Wang, W.; Liu, T . Crystallization behavior of poly( ε -caprolactone)/layered double hydroxide nanocomposites . J. Appl. Polym. Sci. , 2010 . 116 2658 - 2667 . DOI: 10.1002/app http://doi.org/10.1002/app .

Ma, P.; Xu, P.; Zhai, Y.; Dong, W.; Zhang, Y.; Chen, M . Biobased poly(lactide)/ethylene- co -vinyl acetate thermoplastic vulcanizates: morphology evolution, superior properties, and partial degradability . ACS Sustain. Chem. Eng. , 2015 . 3 2211 - 2219 . DOI: 10.1021/acssuschemeng.5b00462 http://doi.org/10.1021/acssuschemeng.5b00462 .

Yao, J.; Liu, X.; Sun, H.; Liu, S.; Jiang, Y.; Yu, B.; Ning, N.; Tian, M.; Zhang, L . Thermoplastic polyurethane dielectric elastomers with high actuated strain and good mechanical strength by introducing ester group grafted polymethylvinylsiloxane . Ind. Eng. Chem. Res. , 2021 . 60 4883 - 4891 . DOI: 10.1021/acs.iecr.1c00362 http://doi.org/10.1021/acs.iecr.1c00362 .

Antunes, C. F.; Van Duin, M.; MacHado, A. V . Morphology and phase inversion of EPDM/PP blends-effect of viscosity and elasticity . Polym. Test. , 2011 . 30 907 - 915 . DOI: 10.1016/j.polymertesting.2011.08.013 http://doi.org/10.1016/j.polymertesting.2011.08.013 .

Wu, H.; Tian, M.; Zhang, L.; Tian, H.; Wu, Y.; Ning, N.; Chan, T. W . New understanding of morphology evolution of thermoplastic vulcanizate (TPV) during dynamic vulcanization . ACS Sustain. Chem. Eng. , 2015 . 3 26 - 32 . DOI: 10.1021/sc500391g http://doi.org/10.1021/sc500391g .

Wu, H.; Tian, M.; Zhang, L.; Tian, H.; Wu, Y.; Ning, N . New understanding of microstructure formation of the rubber phase in thermoplastic vulcanizates (TPV) . Soft Matter , 2014 . 10 1816 - 1822 . DOI: 10.1039/c3sm52375f http://doi.org/10.1039/c3sm52375f .

Joubert, C.; Cassagnau, P.; Michel, A.; Choplin, L . Influence of the processing conditions on a two-phase reactive blend system: EVA/PP thermoplastic vulcanizate . Polym. Eng. Sci. , 2002 . 42 2222 - 2233 . DOI: 10.1002/pen.11112 http://doi.org/10.1002/pen.11112 .

Gong, K.; Tian, H.; Liu, H.; Liu, X.; Hu, G . H.; Yu, B.; Ning, N.; Tian, M.; Zhang, L. Grafting of isobutylene-isoprene rubber with glycidyl methacrylate and its reactive compatibilization effect on isobutylene-isoprene rubber/polyamides 12 blends . Ind. Eng. Chem. Res. , 2021 . 60 16258 - 16266 . DOI: 10.1021/acs.iecr.1c03207 http://doi.org/10.1021/acs.iecr.1c03207 .

Hu, J.; Lv, G.; Ning, N.; Yu, B.; Tian, M.; Zhang, L . Comfort fitting shape memory elastomer with constructed strong interface based on amphiphilic hybrid Janus prticles . Compos. Part B Eng. , 2022 . 236 109828 DOI: 10.1016/j.compositesb.2022.109828 http://doi.org/10.1016/j.compositesb.2022.109828 .

Hu, J.; Song, Y.; Ning, N.; Zhang, L.; Yu, B.; Tian, M . An effective strategy for improving the interface adhesion of the immiscible methyl vinyl silicone elastomer/thermoplastic polyurethane blends via developing a hybrid Janus particle with amphiphilic brush . Polymer , 2021 . 214 23375 DOI: 10.1016/j.polymer.2020.123375 http://doi.org/10.1016/j.polymer.2020.123375 .

Yao, N.; Wang, H.; Zhang, L.; Yue, D.; Tian, M . One-pot solvothermal synthesis of silane-functionalized carbon nanodots as compatibilizers for the immiscible TPU/MVQ bends . Appl. Surf. Sci. , 2020 . 530 147124 DOI: 10.1016/j.apsusc.2020.147124 http://doi.org/10.1016/j.apsusc.2020.147124 .

Lei, C. H.; Li, S. L.; Xu, R. J.; Xu, Y. Q . Thermoplastic vulcanizates based on compatibilized polyurethane and silicone rubber blend . J. Elastomers Plast. , 2012 . 44 563 - 574 . DOI: 10.1177/0095244312441730 http://doi.org/10.1177/0095244312441730 .

Santra, R. N.; Roy, S.; Tikku, V. K.; Nando, G. B . In-situ compatibilization of thermoplastic polyurethane and polydimethyl siloxane rubber by using ethylene methyl acrylate copolymer as a reactive polymeric compatibilizer . Adv. Polym. Technol. , 1995 . 14 59 - 66 . DOI: 10.1002/adv.1995.060140106 http://doi.org/10.1002/adv.1995.060140106 .

Rajan, K. P.; Al-Ghamdi, A.; Ramesh, P.; Nando, G. B . Blends of thermoplastic polyurethane (TPU) and polydimethyl siloxane rubber (PDMS), Part-I: assessment of compatibility from torque rheometry and mechanical properties . J. Polym. Res. , 2012 . 19 9872 DOI: 10.1007/s10965-012-9872-y http://doi.org/10.1007/s10965-012-9872-y .

Caihong, L.; Ruijie, X.; Xiaogang, L.; Jiayi, X . Improving properties of dynamic vulcanized polyurethane and silicone rubber elastomer through controlling interphase layer . Polym. Plast. Technol. Eng. , 2018 . 57 ( 14 ): 1496 - 1505 . DOI: 10.1080/03602559.2017.1410837 http://doi.org/10.1080/03602559.2017.1410837 .

Hu, Y.; Wang, Y. L.; Gong, X. L.; Gong, X. Q.; Zhang, X. Z.; Jiang, W. Q.; Zhang, P. Q.; Chen, Z. Y . New magnetorheological elastomers based on polyurethane/Si-rubber hybrid . Polym. Test. , 2005 . 24 324 - 329 . DOI: 10.1016/j.polymertesting.2004.11.003 http://doi.org/10.1016/j.polymertesting.2004.11.003 .

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