Imparting Pulley Effect and Self-healability to Cathode Binder of Li-S Battery for Improvement of the Cycling Stability

Zhen-Hua Xie; Zi-Xin Huang; Ze-Ping Zhang; Min-Zhi Rong; Ming-Qiu Zhang

doi:10.1007/s10118-022-2820-3

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Imparting Pulley Effect and Self-healability to Cathode Binder of Li-S Battery for Improvement of the Cycling Stability

RESEARCH ARTICLE | Updated：2022-12-19

- Imparting Pulley Effect and Self-healability to Cathode Binder of Li-S Battery for Improvement of the Cycling Stability
- Imparting Pulley Effect and Self-healability to Cathode Binder of Li-S Battery for Improvement of the Cycling Stability
- 高分子科学（英文版） 2023年41卷第1期页码：95-107
- Affiliations：
  
  a.Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education, GD HPPC Lab, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, China
  b.Institute of High Energy Physics, Chinese Academy of Sciences (CAS), Beijing 100049, China
  c.Spallation Neutron Source Science Center, Dongguan 523803, China
- Author bio：
  
  zhangzp8@mail.sysu.edu.cn (Z.P.Z.)
  cesrmz@mail.sysu.edu.cn (M.Z.R.)
  ceszmq@mail.sysu.edu.cn (M.Q.Z.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 52033011, 51873235 and 51973237), Natural Science Foundation of Guangdong Province, China (Nos. 2019B1515120038 and 2021A1515010417), Science and Technology Planning Project of Guangdong Province (No. 2020B010179001), and Industry-University-Research Collaboration Project of Zhuhai City (No. ZH22017001200004PWC).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-022-2820-3.
- DOI：10.1007/s10118-022-2820-3
  中图分类号：
- 收稿：2022-04-18，
  
  修回：2022-5-17，
  
  录用：2022-6-2，
  
  网络首发：2022-09-26，
  
  纸质出版：2023-01-01
- Accepted：
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Xie, Z. H.; Huang, Z. X.; Zhang, Z. P.; Rong, M. Z.; Zhang, M. Q. Imparting pulley effect and self-healability to cathode binder of Li-S battery for improvement of the cycling stability. Chinese J. Polym. Sci. 2023, 41, 95–107

Zhen-Hua Xie, Zi-Xin Huang, Ze-Ping Zhang, et al. Imparting Pulley Effect and Self-healability to Cathode Binder of Li-S Battery for Improvement of the Cycling Stability[J]. Chinese Journal of Polymer Science, 2023, 41(1): 95-107.
Xie, Z. H.; Huang, Z. X.; Zhang, Z. P.; Rong, M. Z.; Zhang, M. Q. Imparting pulley effect and self-healability to cathode binder of Li-S battery for improvement of the cycling stability. Chinese J. Polym. Sci. 2023, 41, 95–107 DOI： 10.1007/s10118-022-2820-3.

Zhen-Hua Xie, Zi-Xin Huang, Ze-Ping Zhang, et al. Imparting Pulley Effect and Self-healability to Cathode Binder of Li-S Battery for Improvement of the Cycling Stability[J]. Chinese Journal of Polymer Science, 2023, 41(1): 95-107. DOI： 10.1007/s10118-022-2820-3.

摘要

Polyacrylic acid crosslinked by cationic hydroxypropyl polyrotaxane

via

dynamically reversible boronic ester bonds is used as a novel binder in sulfur cathode. The self-healable binder can effectively maintain structural integrity of the sulfur cathode and suppress the shuttle effect

and hence endows the sulfur cathode with superior electrochemical properties.

Abstract

To construct structurally stable sulfur cathode of Li-S battery with improved cycling performance

poly(acrylic acid) (PAA) crosslinked by cationic hydroxypropyl polyrotaxane (HPRN

)

via

dynamically reversible boronic ester bonds is synthesized and serves as the cathode binder. The smart polymer networks offer multifunction including buffering the volume change of the cathode during charge/discharge through the pulley effect of polyrotaxanes (PR)

suppressing the shuttle effect by adsorption of polysulfide using the plentiful carboxyl

hydroxyl and quaternary ammonium cationic groups

and self-healing the micro-damages to ensure stable conduction pathways of the electrode. As a result

the Li-S batteries based on this novel multifunctional binder and simple commercial sulfur/carbon composites cathode exhibit excellent specific capacity and cycling stability. In particular

the specific capacity decay per cycle of the cell is only 0.064% along with high Coulombic efficiency after 550 cycles at 1.0 C

which is superior to most of the reported binders. Even under high sulfur loading

moreover

the cathode can deliver superior areal capacity and cycling stability. This proposed binder provides a new way for the design of high-stability sulfur cathodes.

关键词

Keywords

references

Huang, S.; Guan, R.; Wang, S.; Xiao, M.; Han, D.; Sun, L.; Meng, Y . Polymers for high performance Li-S batteries: material selection and structure design . Prog. Polym. Sci. , 2019 . 89 19 - 60 . DOI: 10.1016/j.progpolymsci.2018.09.005 http://doi.org/10.1016/j.progpolymsci.2018.09.005 .

Ely, T. O.; Kamzabek, D.; Chakraborty, D.; Doherty, M. F . Li-sulfur batteries: state of the art and future directions . ACS Appl. Energy Mater. , 2018 . 1 1783 - 1814 . DOI: 10.1021/acsaem.7b00153 http://doi.org/10.1021/acsaem.7b00153 .

Zhu, J.; Zhu, P.; Yan, C.; Dong, X.; Zhang, X . Recent progress in polymer materials for advanced lithium-sulfur batteries . Prog. Polym. Sci. , 2019 . 90 118 DOI: 10.1016/j.progpolymsci.2018.12.002 http://doi.org/10.1016/j.progpolymsci.2018.12.002 .

Li, X.; Lv, R.; Zou, S.; Na, B.; Liu, P.; Ma, Y.; Liu, H . Polyaniline nanopillars on surface cracked carbon fibers as an ultrahigh-performance cathode for a flexible rechargeable aqueous Zn-ion battery . Compos. Sci. Technol. , 2019 . 180 71 - 77 . DOI: 10.1016/j.compscitech.2019.05.016 http://doi.org/10.1016/j.compscitech.2019.05.016 .

Zhang, Q.; Cheng, X. B.; Huang, J. Q.; Peng, H. J.; Fei, W . Review of carbon materials for advanced lithium-sulfur batteries . New Carbon Mater. , 2015 . 81 850 - 850 . .

Zhao, H.; Deng, N.; Yan, J.; Kang, W.; Ju, J.; Ruan, Y.; Wang, X.; Zhuang, X.; Li, Q.; Cheng, B . A review on anode for lithium-sulfur batteries: progress and prospects . Chem. Eng. J. , 2018 . 347 343 - 365 . DOI: 10.1016/j.cej.2018.04.112 http://doi.org/10.1016/j.cej.2018.04.112 .

Barghamadi, M.; Best, A. S.; Bhatt, A. I.; Hollenkamp, A. F.; Musameh, M.; Rees, R. J.; Rüther, T . Lithium-sulfur batteries-the solution is in the electrolyte, but is the electrolyte a solution? . Energy Environ. Sci. , 2014 . 7 3902 - 3920 . DOI: 10.1039/C4EE02192D http://doi.org/10.1039/C4EE02192D .

Wang, L.; Ye, Y.; Chen, N.; Huang, Y.; Li, L.; Wu, F.; Chen, R . Development and challenges of functional electrolytes for high-performance lithium-sulfur batteries . Adv. Funct. Mater. , 2018 . 28 1800919 DOI: 10.1002/adfm.201800919 http://doi.org/10.1002/adfm.201800919 .

Deng, N.; Kang, W.; Liu, Y.; Ju, J.; Wu, D.; Li, L.; Hassan, B. S.; Cheng, B . A review on separators for lithiumsulfur battery: progress and prospects . J. Power Sources , 2016 . 331 132 - 155 . DOI: 10.1016/j.jpowsour.2016.09.044 http://doi.org/10.1016/j.jpowsour.2016.09.044 .

Huang, J.; Sun, Y.; Wang, Y.; Zhang, Q . Review on advanced functional separators for lithium-sulfur batteries . Acta Chim. Sin. , 2017 . 75 173 - 188 . DOI: 10.6023/A16080454 http://doi.org/10.6023/A16080454 .

Yuan, H.; Huang, J. Q.; Peng, H. J.; Titirici, M. M.; Xiang, R.; Chen, R.; Liu, Q.; Zhang, Q . A review of functional binders in lithium-sulfur batteries . Adv. Energy Mater. , 2018 . 8 1802107 DOI: 10.1002/aenm.201802107 http://doi.org/10.1002/aenm.201802107 .

Lopez, J.; Mackanic, D. G.; Cui, Y.; Bao, Z . Designing polymers for advanced battery chemistries . Nat. Rev. Mater. , 2019 . 4 312 - 330 . DOI: 10.1038/s41578-019-0103-6 http://doi.org/10.1038/s41578-019-0103-6 .

Wang, Y. L. ; Liu, B. X. ; Tian, G. F. ; Qi, S. L. ; Wu, D. Z . Research progress of cathode binder for high performance lithium-ion battery . Acta Polymerica Sinica (in Chinese) , 2020 . 51 326 - 337 . DOI: 10.3866/PKU.WHXB20100205 http://doi.org/10.3866/PKU.WHXB20100205 .

Feng, J., Yi, H., Lei, Z, Wang, J., Zeng, H., Deng, Y., Wang, C . A three-dimensional crosslinked chitosan sulfate network binder for high-performance Li-S batteries . J. Energy Chem. , 2021 . 56 171 - 178 . DOI: 10.1016/j.jechem.2020.07.060 http://doi.org/10.1016/j.jechem.2020.07.060 .

Zeng, F.; Wang, W.; Wang, A.; Yuan, K.; Jin, Z.; Yang, Y. S . Multidimensional polycation β -cyclodextrin polymer as an effective aqueous binder for high sulfur loading cathode in lithium-sulfur batteries . ACS Appl. Mater. Interfaces , 2015 . 7 26257 - 26265 . DOI: 10.1021/acsami.5b08537 http://doi.org/10.1021/acsami.5b08537 .

Liao, J.; Ye, Z . Quaternary ammonium cationic polymer as a superior bifunctional binder for lithium-sulfur batteries and effects of counter anion . Electrochim. Acta , 2018 . 259 626 - 636 . DOI: 10.1016/j.electacta.2017.10.194 http://doi.org/10.1016/j.electacta.2017.10.194 .

H . Wang, M. Ling, Y. Bai, S. Chen, Y. Yuan, G. Liu, C. Wu, F. Wu, Cationic polymer binder inhibit shuttle effects through electrostatic confinement in lithium sulfur batteries . J. Mater. Chem. A , 2018 . 6 6959 - 6966 . DOI: 10.1039/C7TA10239A http://doi.org/10.1039/C7TA10239A .

Tu, S., Chen, X., Zhao, X., Cheng, M., Xiong, P., He, Y., Zhang, Q., Xu, Y . A polysulfide-immobilizing polymer retards the shuttling of polysulfide intermediates in lithium-sulfur batteries . Adv. Mater. , 2018 . 30 1804581 DOI: 10.1002/adma.201804581 http://doi.org/10.1002/adma.201804581 .

Liu, J.; Galpaya, D. G.; Yan, L.; Sun, M.; Lin, Z.; Yan, C.; Liang, C.; Zhang, S . Exploiting a robust biopolymer network binder for an ultrahigh-areal-capacity Li-S battery . Energy Environ. Sci. , 2017 . 10 750 - 755 . DOI: 10.1039/C6EE03033E http://doi.org/10.1039/C6EE03033E .

Chen, W.; Qian, T.; Xiong, J.; Xu, N.; Liu, X.; Liu, J.; Zhou, J.; Shen, X.; Yang, T.; Chen, Y . A new type of multifunctional polar binder: toward practical application of high energy lithium sulfur batteries . Adv. Mater. , 2017 . 29 1605160 DOI: 10.1002/adma.201605160 http://doi.org/10.1002/adma.201605160 .

Yan, L.; Gao, X.; Wahid-Pedro, F.; Quinn, J. T. E.; Meng, Y. Y . Li, A novel epoxy resin-based cathode binder for low cost, long cycling life, and high-energy lithium-sulfur batteries . J. Mater. Chem. A , 2018 . 6 14315 - 14323 . DOI: 10.1039/C8TA04450C http://doi.org/10.1039/C8TA04450C .

Zhang, H.; Hu, X.; Zhang, Y.; Wang, S.; Xin, F.; Chen, X.; Yu, D . 3D-crosslinked tannic acid/poly (ethylene oxide) complex as a three-in-one multifunctional binder for high-sulfur-loading and high-stability cathodes in lithium-sulfur batteries . Energy Storage Mater. , 2019 . 17 293 - 299 . .

Fu, X.; Scudiero, L.; Zhong, W. H . A robust and ion-conductive protein-based binder enabling strong polysulfide anchoring for high-energy lithium-sulfur batteries . J. Mater. Chem. A , 2018 . 7 1835 - 1848 . .

Jie, L.; Sun, M.; Zhang, Q.; Dong. F.; Kaghazchi, P.; Fang, Y.; Zhang, S.; Lin. Z . A robust network binder with dual functions of Cu 2+ ions as ionic crosslinking and chemical binding agents for highly stable Li-S batteries . J. Mater. Chem. A , 2018 . 6 7382 - 7388 . DOI: 10.1039/C8TA01138A http://doi.org/10.1039/C8TA01138A .

Mai, W.; Yu, Q.; Han, C.; Kang, F.; Li, B . Self-healing materials for energy-storage devices . Adv. Funct. Mater. , 2020 . 30 1909912 .

Wang, H.; Wang, Y.; Zheng, P.; Yang, Y.; Chen, Y.; Cao, Y.; Deng, Y.; Wang, C . Self-healing double-cross-linked supramolecular binders of a polyacrylamide-grafted soy protein isolate for Li-S batteries . ACS Sustain. Chem. Eng. , 2020 . 8 12799 - 12808 . DOI: 10.1021/acssuschemeng.0c02477 http://doi.org/10.1021/acssuschemeng.0c02477 .

Chu, Y.; Cui, X.; Pan, Q . Realizing high-performance sulfur cathodes through a self-healing and confining strategy . ACS Appl. Energy Mater. , 2018 . 1 6919 DOI: 10.1021/acsaem.8b01324 http://doi.org/10.1021/acsaem.8b01324 .

Xu, G.; Yan, Q. B.; Kushima, A.; Zhang, X.; Pan, J.; Li, J . Conductive graphene oxide-polyacrylic acid (GOPAA) binder for lithium-sulfur battery . Nano Energy , 2017 . 31 568 - 574 . .

Kim, S.; Cho, M.; Chanthad, M.; Lee, Y.; Chanthad C . New redox-mediating polymer binder for enhancing performance of Li-S batteries . J. Energy Chem. , 2020 . 44 154 - 161 . DOI: 10.1016/j.jechem.2019.09.001 http://doi.org/10.1016/j.jechem.2019.09.001 .

Choi, S.; Kwon, T. W.; Coskun, A.; Choi, J. W . Highly elastic binders integrating polyrotaxanes for silicon microparticle anodes in lithium ion batteries . Science , 2017 . 357 279 - 283 . DOI: 10.1126/science.aal4373 http://doi.org/10.1126/science.aal4373 .

Xie, Z. H.; Rong, M. Z.; Zhang, M. Q.; Liu, D . Implementation of the pulley effect of polyrotaxane in transparent bulk polymer for simultaneous strengthening and toughening . Macromol. Rapid Commun. , 2020 . 41 2000371 .

Yoo, D. J.; Elabd, A.; Choi, S.; Cho, Y.; Kim, J.; Lee, S. J.; Choi, S. H.; Kwon, T. W.; Char, K.; Kim, K. J.; Coskun, A.; Choi, J. W . Highly elastic polyrotaxane binders for mechanically stable lithium hosts in lithium-metal batteries . Adv. Mater. , 2019 . 31 1901645 DOI: 10.1002/adma.201901645 http://doi.org/10.1002/adma.201901645 .

Röttger, M.; Domenech, T.; van der Weegen, R.; Breuillac, A.; Nicolaÿ, R.; Leibler, L . High-performance vitrimers from commodity thermoplastics through dioxaborolane metathesis . Science , 2017 . 356 62 - 65 . DOI: 10.1126/science.aah5281 http://doi.org/10.1126/science.aah5281 .

Xie, Z. H.; Huang, Z. X.; Rong, M. Z.; Zhang, M. Q . Imparting high robustness and suppression ability of shuttle effect to sulfur cathode in Li-S battery via a novel multifunctional binder . Mater. Today Energy , 2020 . 18 100555 .

Prado, H. J.; Matulewicz, M. C . Cationization of polysaccharides: A path to greener derivatives with many industrial applications . Eur. Polym. J. , 2014 . 52 53 - 75 . DOI: 10.1016/j.eurpolymj.2013.12.011 http://doi.org/10.1016/j.eurpolymj.2013.12.011 .

Zhang, Z. P.; Rong, M. Z.; Zhang, M. Q . Mechanically robust, self-healable, and highly stretchable “living” crosslinked polyurethane based on a reversible C-C bond . Adv. Funct. Mater. , 2018 . 28 1706050 DOI: 10.1002/adfm.201706050 http://doi.org/10.1002/adfm.201706050 .

Li, H.; Tang, W.; Huang, Y.; Ruan, W.; Zhang, M . Nanopore separator of cross-linked poly(propylene glycol)- co -pentaerythritol triacrylate for effectively suppressing polysulfide shuttling in Li-S batteries . Polym. Chem. , 2019 . 10 2697 - 2705 . DOI: 10.1039/C9PY00206E http://doi.org/10.1039/C9PY00206E .

Chen, W.; Lei, T.; Qian, T.; Lv, W.; He, W.; Wu, C.; Liu, X.; Liu, J.; Chen, B.; Yan, C . A new hydrophilic binder enabling strongly anchoring polysulfides for high-performance sulfur electrodes in lithium-sulfur battery . Adv. Energy Mater. , 2018 . 8 1702889 DOI: 10.1002/aenm.201702889 http://doi.org/10.1002/aenm.201702889 .

Okumura, Y.; Ito, K . The polyrotaxane gel: a topological gel by figure-of-eight cross-links . Adv. Mater. , 2001 . 13 485 - 487 . DOI: 10.1002/1521-4095(200104)13:7<485::AID-ADMA485>3.0.CO;2-T http://doi.org/10.1002/1521-4095(200104)13:7<485::AID-ADMA485>3.0.CO;2-T .

Tang, C.; Inomata, A.; Sakai, Y.; Yokoyama, H.; Miyoshi, T.; Ito, K . Effects of chemical modification on the molecular dynamics of complex polyrotaxanes investigated by solid-state NMR . Macromolecules , 2013 . 46 6898 - 6907 . DOI: 10.1021/ma401476g http://doi.org/10.1021/ma401476g .

Wu, B. Y.; Xu, Y. W.; Le, X. X.; Jian, Y. K.; Lu, W.; Zhang, J. W.; Chen, T . Smart hydrogel actuators assembled via dynamic boronic ester bonds . Acta Polym. Sin. , 2019 . 5 496 - 504 . .

Peng, W. L.; You, Y.; Xie, P.; Rong, M. Z.; Zhang, M. Q . Adaptable interlocking macromolecular networks with homogeneous architecture made from immiscible single networks . Macromolecules , 2020 . 53 584 - 593 . DOI: 10.1021/acs.macromol.9b02307 http://doi.org/10.1021/acs.macromol.9b02307 .

You, Y.; Peng, W. L.; Xie, P.; Rong, M. Z.; Zhang, M. Q.; Liu, D . Topological rearrangement-derived homogeneous polymer networks capable of reversibly interlocking: from phantom to reality and beyond . Mater. Today , 2020 . 33 45 - 55 . DOI: 10.1016/j.mattod.2019.09.005 http://doi.org/10.1016/j.mattod.2019.09.005 .

Ye, H.; Lei, D.; Shen, L.; Ni, B.; Li, B.; Kang, F.; He, Y. B . In situ polymerized cross-linked binder for cathode in lithium-sulfur batteries . Chin. Chem. Lett. , 2019 . 31 570 - 574 . .

Frischmann, P. D.; Hwa, Y.; Cairns, E. J.; Helms, B. A . Redox-active supramolecular polymer binders for lithium-sulfur batteries that adapt their transport properties in operando . Chem. Mater. , 2016 . 28 7414 - 7421 . DOI: 10.1021/acs.chemmater.6b03013 http://doi.org/10.1021/acs.chemmater.6b03013 .

Vizintin, A.; Guterman, R.; Schmidt, J.; Antonietti, M.; Dominko, R . Linear and cross-linked ionic liquid polymers as binders in lithium-sulfur batteries . Chem. Mater. , 2018 . 30 5444 - 5450 . DOI: 10.1021/acs.chemmater.8b02357 http://doi.org/10.1021/acs.chemmater.8b02357 .

Zhang, Z. P.; Rong, M. Z.; Zhang, M. Q . Polymer engineering based on reversible covalent chemistry: a promising innovative pathway towards new materials and new functionalities . Prog. Polym. Sci. , 2018 . 80 39 - 93 . DOI: 10.1016/j.progpolymsci.2018.03.002 http://doi.org/10.1016/j.progpolymsci.2018.03.002 .

Li, G.; Ling, M.; Ye, Y.; Li, Z.; Guo, J.; Yao, Y.; Zhu, J.; Lin, Z.; Zhang, S . Acacia senegal-inspired bifunctional binder for longevity of lithium-sulfur batteries . Adv. Energy Mater. , 2015 . 5 1500878 DOI: 10.1002/aenm.201500878 http://doi.org/10.1002/aenm.201500878 .

Hwa, Y.; Frischmann, P. D.; Helms, B. A.; Cairns, E. J . Aqueous-processable redox-active supramolecular polymer binders for advanced lithium/sulfur cells . Chem. Mater. , 2018 . 30 685 - 691 . DOI: 10.1021/acs.chemmater.7b03870 http://doi.org/10.1021/acs.chemmater.7b03870 .

Pan, J.; Xu, G.; Ding, B.; Han, J.; Dou, H.; Zhang, X . Enhanced electrochemical performance of sulfur cathodes with a water-soluble binder . RSC Adv. , 2015 . 5 13709 - 13714 . DOI: 10.1039/C4RA15303K http://doi.org/10.1039/C4RA15303K .

Hernández, G.; Lago, N.; Shanmukaraj, D.; Armand, M.; Mecerreyes, D . Polyimide-polyether binders-diminishing the carbon content in lithium sulfur batteries . Mater. Today Energy , 2017 . 6 264 - 270 . DOI: 10.1016/j.mtener.2017.11.001 http://doi.org/10.1016/j.mtener.2017.11.001 .

Yi, H.; Lan, T.; Yang, Y.; Lei, Z.; Zeng, H.; Tang, T.; Wang, C.; Deng, Y . Aqueous-processable polymer binder with strong mechanical and polysulfide-trapping properties for high performance of lithium-sulfur batteries . J. Mater. Chem. A , 2018 . 6 18660 - 18668 . DOI: 10.1039/C8TA07194B http://doi.org/10.1039/C8TA07194B .

Yi, H.; Lan, T.; Yang, Y.; Zeng, H.; Zhang, T.; Tang, T.; Wang, C.; Deng, Y . A robust aqueous-processable polymer binder for long-life, high-performance lithium sulfur battery . Energy Stor. Mater. , 2019 . 21 61 - 68 . DOI: 10.1016/j.ensm.2018.12.009 http://doi.org/10.1016/j.ensm.2018.12.009 .

Qi, Q.; Deng, Y.; Gu, S.; Gao, M.; Hasegawa, J. Y.; Zhou, G.; Lv, X.; Lv, W.; Yang, Q. H . l-Cysteine-modified acacia gum as a multifunctional binder for lithium-sulfur batteries . ACS Appl. Mater. Interfaces , 2019 . 11 47956 - 47962 . .

Zhong, L.; Mo, Y.; Deng, K.; Wang, S.; Han, D.; Ren, S.; Xiao, M.; Meng, Y . Lithium borate containing bifunctional binder to address both ion transporting and polysulfide trapping for high-performance Li-S batteries . ACS Appl. Mater. Interfaces , 2019 . 11 28968 - 28977 . DOI: 10.1021/acsami.9b09604 http://doi.org/10.1021/acsami.9b09604 .

Luo, X.; Lu, X.; Chen, X.; Chen, Y.; Yu, C.; Su, D.; Wang, G.; Cui, L . A functional hyperbranched binder enabling ultra-stable sulfur cathode for high-performance lithium-sulfur battery . J. Energy Chem. , 2020 . 50 63 - 72 . DOI: 10.1016/j.jechem.2020.02.041 http://doi.org/10.1016/j.jechem.2020.02.041 .

Zheng, M.; Cai, X.; Tan, Y.; Wang, W.; Wang, D.; Fei, H.; Saha, P.; Wang, G . A high-resilience and conductive composite binder for lithium-sulfur batteries . Chem. Eng. J. , 2020 . 389 124404 DOI: 10.1016/j.cej.2020.124404 http://doi.org/10.1016/j.cej.2020.124404 .

Yu, Z.; Gao, T.; Le, T.; Wang, W.; Wang, L.; Yang, Y . A homemade self-healing material utilized as multi-functional binder for long-lifespan lithium-sulfur batteries . J. Mater. Sci. Mater. Electron. , 2019 . 30 5536 - 5543 . DOI: 10.1007/s10854-019-00847-7 http://doi.org/10.1007/s10854-019-00847-7 .

Chua, Y.; Chen, N.; Cui, X.; Liu, A.; Zhen, L.; Pan, Q . A multi-functional binder for high loading sulfur cathode . J. Energy Chem. , 2020 . 46 99 - 104 . DOI: 10.1016/j.jechem.2019.10.020 http://doi.org/10.1016/j.jechem.2019.10.020 .

Liu, Z.; He, X.; Fang, C.; Camacho-orero, L. E.; Liu, G . Reversible crosslinked polymer binder for recyclable Lithium-Sulfur batteries with high performance . Adv. Funct. Mater. , 2020 . 30 2003605 DOI: 10.1002/adfm.202003605 http://doi.org/10.1002/adfm.202003605 .

Jin, B.; Yang, L.; Zhang, J.; Cai, Y.; Zhu, J.; Lu, J.; Hou, Y.; He, Q.; Xing, H.; Zhan, X . Bioinspired binders actively controlling ion migration and accommodating volume change in high sulfur loading lithium-sulfur batteries . Adv. Energy Mater. , 2019 . 9 1902938 DOI: 10.1002/aenm.201902938 http://doi.org/10.1002/aenm.201902938 .

Guo, R.; Wang, J.; Zhang, S.; Han, W. Q . Multifunctional cross-linked polymer-laponite nanocomposite binder for lithium-sulfur batteries . Chem. Eng. J. , 2020 . 388 124316 DOI: 10.1016/j.cej.2020.124316 http://doi.org/10.1016/j.cej.2020.124316 .

Jeon, J.; Yoo, J. K.; Yim, S.; Jeon, K.; Jung, Y. S . Natural wood-derived lignosulfonate ionomer as multifunctional binder for high-performance lithium-sulfur battery . ACS Sustain. Chem. Eng. , 2019 . 21 17580 - 17586 . .

Xu, H.; Zou, Z.; Tang, B.; Chen, Z.; Zhang, H.; Chen, J.; Cui, G. . The study on the application of pectin binder in lithium-sulfur batteries . Acta Polymerica Sinica (in Chinese) , 2021 . 52 166 - 175 . DOI: 10.11777/j.issn1000-3304.2020.20157 http://doi.org/10.11777/j.issn1000-3304.2020.20157 .

Eom, J. Y.; Kim, S. I.; Ri, V.; Kim, C . The effect of polymeric binders in the sulfur cathode on the cycling performance for lithium-sulfur batteries . Chem. Commun. , 2019 . 55 14609 - 14612 . DOI: 10.1039/C9CC07061C http://doi.org/10.1039/C9CC07061C .

Feng, J.; Yi, H.; Lei, Z.; Wang, J.; Zeng, H.; Deng, Y.; Wang, C . A three-dimensional crosslinked chitosan sulfate network binder for high-performance Li-S batteries . J. Energy Chem. , 2020 . 56 171 - 178 . .

Wang, S.; Xue, L. L.; Zhou, X. Z.; Cui, J. X . “Solid-liquid” vitrimers based on dynamic boronic ester networks . Chinese J. Polym. Sci. , 2021 . 39 1292 - 1298 . .

Li, Z.; Zhou, H. Y.; Zhao, F. L.; Wang, T. X.; Ding, X. S.; Han, B. H.; Feng, W . Three-dimensional covalent organic frameworks as host materials for lithium-sulfur batteries . Chinese J. Polym. Sci. , 2020 . 38 550 - 557 . DOI: 10.1007/s10118-020-2384-z http://doi.org/10.1007/s10118-020-2384-z .

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