Rapid Self-healing and Strong Adhesive Elastomer <italic style="font-style: italic">via</italic> Supramolecular Aggregates from Core-shell Micelles of Silicon Hydroxyl-functionalized <italic style="font-style: italic">cis</italic>-Polybutadiene

Ying-Ying Zheng; Han Zhu; Yi Tan; Feng-Yi-Qi Liu; Yi-Xian Wu

doi:10.1007/s10118-022-2808-z

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Rapid Self-healing and Strong Adhesive Elastomer via Supramolecular Aggregates from Core-shell Micelles of Silicon Hydroxyl-functionalized cis-Polybutadiene

RESEARCH ARTICLE | Updated：2022-12-19

- Rapid Self-healing and Strong Adhesive Elastomer via Supramolecular Aggregates from Core-shell Micelles of Silicon Hydroxyl-functionalized cis-Polybutadiene
- Rapid Self-healing and Strong Adhesive Elastomer via Supramolecular Aggregates from Core-shell Micelles of Silicon Hydroxyl-functionalized cis-Polybutadiene
- 高分子科学（英文版） 2023年41卷第1期页码：84-94
- Affiliations：
  
  State Key Laboratory of Chemical Resource Engineering, Beijing Advanced innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
- Author bio：
  
  zhuhan@mail.buct.edu.cn (H.Z.)
  wuyx@mail.buct.edu.cn (Y.X.W.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (NSFC) (Nos. 21634002, 51790501 and 51521062) and the Fundamental Research Funds for the Central Universities (Nos. XK1802-2 and XK1802-1).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-022-2808-z.
- DOI：10.1007/s10118-022-2808-z
  中图分类号：
- 收稿：2022-04-20，
  
  修回：2022-5-11，
  
  录用：2022-5-22，
  
  网络首发：2022-09-30，
  
  纸质出版：2023-01-01
- Accepted：
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Zheng, Y. Y.; Zhu, H.; Tan, Y.; Liu, F. Y. Q.; Wu, Y. X. Rapid self-healing and strong adhesive elastomer via supramolecular aggregates from core-shell micelles of silicon hydroxyl-functionalized cis-polybutadiene. Chinese J. Polym. Sci. 2023, 41, 84–94

Ying-Ying Zheng, Han Zhu, Yi Tan, et al. Rapid Self-healing and Strong Adhesive Elastomer via Supramolecular Aggregates from Core-shell Micelles of Silicon Hydroxyl-functionalized cis-Polybutadiene[J]. Chinese Journal of Polymer Science, 2023, 41(1): 84-94. DOI: 10.1007/s10118-022-2808-z.
Zheng, Y. Y.; Zhu, H.; Tan, Y.; Liu, F. Y. Q.; Wu, Y. X. Rapid self-healing and strong adhesive elastomer via supramolecular aggregates from core-shell micelles of silicon hydroxyl-functionalized cis-polybutadiene. Chinese J. Polym. Sci. 2023, 41, 84–94 DOI： 10.1007/s10118-022-2808-z.

Ying-Ying Zheng, Han Zhu, Yi Tan, et al. Rapid Self-healing and Strong Adhesive Elastomer via Supramolecular Aggregates from Core-shell Micelles of Silicon Hydroxyl-functionalized cis-Polybutadiene[J]. Chinese Journal of Polymer Science, 2023, 41(1): 84-94. DOI: 10.1007/s10118-022-2808-z. DOI：

摘要

An approach was developed for

in situ

preparation of core-shell micelles by combination of hydrolysis and self-assembly at interface of hexane/water. The giant supramolecular aggregates are formed by hydrogen bonding or O-Si-O chemical bonds between the micellar surfaces. The

cis

-PB-Si(OH)3-based elastomer exhibit strong adhesion property for glass and excellent self-healing property.

Abstract

Liquid trimethoxy silane-functionalized

cis

-polybutadiene (

cis

-PB-Si(OMe)

)

possessing number-average molecular weights of

cis

-PB segments (

) ranging from 1800 g/mol to 5400 g/mol

with

cis

-1

4 content of

ca.

80% and high functionality (

96%) could be synthesized by coordination copolymerization of living

cis

-PB chain ends with ethenyltrimethoxy-silane with neodymium-based catalytic system. The silicon hydroxyl-functionalized

cis

-polybutadiene (

cis

-PB-Si(OH)

)-based micelles in water have been achieved by

in situ

hydrolysis of

cis

-PB-Si(OMe)

in hexane/water mixture (pH=6.8) at 70 °C and by sequential removal of residue hexane. The size of the above micelles with soft elastic

cis

-PB cores could be remarkably enlarged by loading SiO

nanoparticles on their surfaces

via

hydrogen bonding interaction. Giant supramolecular long chain aggregates or networks formed by hydrogen bonding interaction and possible O―Si―O chemical bonds between

cis

-PB-Si(OH)

-based micellar surfaces had relatively large size and thus precipitated from water after several months of storage

leading to production of

cis

-PB-Si(OH)

solid elastomer with extremely low

at −107.0 °C. The left

cis

-PB-Si(OH)

-based micelles in water with relatively small size gradually formed the water-insoluble

cis

-PB-Si(OH)

-based supramolecular aggregates or networks. The

cis

-PB-Si(OH)

-based supramolecular elastomer exhibited excellent self-healing property within 60 s at 25 °C. The elastomer (20 mg) in a joint of 25 mm × 30 mm (2.7 mg/cm

) provided very strong adhesion for two pieces of glass and the bound glass keep unchanged at room temperature for 98 h even hung with 100 g of steel column below. The

cis

-PB-Si(OH)

-based supramolecular elastomer would have potential applications in adhesives

self-healing materials

damping materials and elastic materials.

关键词

Keywords

references

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Rapid Self-healing and Strong Adhesive Elastomer via Supramolecular Aggregates from Core-shell Micelles of Silicon Hydroxyl-functionalized cis-Polybutadiene

Rapid Self-healing and Strong Adhesive Elastomer via Supramolecular Aggregates from Core-shell Micelles of Silicon Hydroxyl-functionalized cis-Polybutadiene

DOI：10.1007/s10118-022-2808-z

摘要

Abstract

关键词

Keywords

references