Dry-spun Polyimide Fibers with Excellent Thermal Stability, Intrinsic Flame Retardancy and Ultralow Smoke Release

Han Dong; Yu-Ping Wang; Xiu-Ting Li; Xin Zhao; Jie Dong; Qing-Hua Zhang

doi:10.1007/s10118-022-2792-3

Your Location：

Home >

Browse articles >

Dry-spun Polyimide Fibers with Excellent Thermal Stability, Intrinsic Flame Retardancy and Ultralow Smoke Release

RESEARCH ARTICLE | Updated：2022-10-25

- Dry-spun Polyimide Fibers with Excellent Thermal Stability, Intrinsic Flame Retardancy and Ultralow Smoke Release
- Dry-spun Polyimide Fibers with Excellent Thermal Stability, Intrinsic Flame Retardancy and Ultralow Smoke Release
- 高分子科学（英文版） 2022年40卷第11期页码：1422-1431
- Affiliations：
  
  a.State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
  b.Jiangsu New Vision Advanced Functional Fiber Innovation Center Co., Ltd., Suzhou 215000, China
- Author bio：
  
  dj01@dhu.edu.cn (J.D.)
  qhzhang@dhu.edu.cn (Q.H.Z.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51903038 and 21975040), the Scientific Research Innovation Plan of Shanghai Education Commission (No. 2019-01-07-00-03-E00001), the Natural Science Foundation of Shanghai (No. 21ZR1400200) and the Project “Fiber materials and products for emergency support and public safety” from Jiangsu New Vision Advanced Functional Fiber Innovation Center Co., Ltd. (No. 2021-fx020204).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-022-2792-3.
- DOI：10.1007/s10118-022-2792-3
  中图分类号：
- 收稿：2022-03-06，
  
  修回：2022-4-25，
  
  录用：2022-5-30，
  
  网络首发：2022-08-17，
  
  纸质出版：2022-11-01
- Accepted：
Scan QR Code
Dong, H.; Wang, Y. P.; Li, X. T.; Zhao, X.; Dong, J.; Zhang, Q. H. Dry-spun polyimide fibers with excellent thermal stability, intrinsic flame retardancy and ultralow smoke release. Chinese J. Polym. Sci. 2022, 40, 1422–1431

Han Dong, Yu-Ping Wang, Xiu-Ting Li, et al. Dry-spun Polyimide Fibers with Excellent Thermal Stability, Intrinsic Flame Retardancy and Ultralow Smoke Release[J]. Chinese Journal of Polymer Science, 2022, 40(11): 1422-1431.
Dong, H.; Wang, Y. P.; Li, X. T.; Zhao, X.; Dong, J.; Zhang, Q. H. Dry-spun polyimide fibers with excellent thermal stability, intrinsic flame retardancy and ultralow smoke release. Chinese J. Polym. Sci. 2022, 40, 1422–1431 DOI： 10.1007/s10118-022-2792-3.

Han Dong, Yu-Ping Wang, Xiu-Ting Li, et al. Dry-spun Polyimide Fibers with Excellent Thermal Stability, Intrinsic Flame Retardancy and Ultralow Smoke Release[J]. Chinese Journal of Polymer Science, 2022, 40(11): 1422-1431. DOI： 10.1007/s10118-022-2792-3.

摘要

Polyimide fibers with an ultrahigh thermal stability

superior flame retardancy and low smoke release were prepared by dry spinning

thermal cyclization and hot-drawing and were used on a large scale in high temperature filtration

aerospace and thermal protection fields.

Abstract

Polymer fiber with an ultrahigh thermal stability

superior flame retardancy and low smoke release during combustion is urgently needed and a crucial challenge for developing advanced fireproof textiles. In this study

a series of high-performance polyimide fibers are synthesized by copolymerizing 4

4'-diaminodiphenylmethane (MDA) into the pyromellitic dianhydride-

-phenylenediamine (PMDA-PDA) backbone for synergistically solving the technical challenge of poor fiber processing ability of these polyimides with a high inherent molecular rigidity. The glass transition temperature (

) of resultant fibers with the PDA molar ratio over 50 mol% reaches above 420 °C and their 10 wt% weight loss temperature (

10%

) is within 543−633 °C. For the typical fiber containing 80 mol% of PDA

the limiting oxygen index (LOI) reaches 39% and exhibits a rapid self-extinguishing performance after deviating from the flame. Meanwhile

this fiber exhibits the minimum heat release rate of 14.1 kW/m

in a long ignition time of 813 s during combustion

revealing its better flame retardancy than the well-known Nomex fiber with a heat release rate of 140.6 kW/m

during the 120 s ignition. Meanwhile

the total smoke production of this polyimide fiber is only 1/9 of the Nomex fiber. Accordingly

the excellent flame retardancy of polyimide fibers indicating them more attractive as the fireproof materials in the field of emergency protection.

关键词

Keywords

references

He, W. T.; Song, P. A; Yu, B.; Fang, Z. P.; Wang, H . Flame retardant polymeric nanocomposites through the combination of nanomaterials and conventional flame retardants . Prog. Mater. Sci. , 2020 . 114 100687 DOI: 10.1016/j.pmatsci.2020.100687 http://doi.org/10.1016/j.pmatsci.2020.100687 .

Liu W.; Zhang, S.; Chen, X. S.; Yu, L. H.; Zhu, X. J.; Feng, Q. L . Thermal behavior and fire performance of nylon-6,6 fabric modified with acrylamide by photografting . Polym. Degrad. Stabil. , 2010 . 95 1842 - 1848 . DOI: 10.1016/j.polymdegradstab.2010.04.023 http://doi.org/10.1016/j.polymdegradstab.2010.04.023 .

Yu, S. R.; Xia, Z. Y.; Kiratitanavit, W.; Thota, S.; Kumar, J.; Mosurkal, R.; Nagarajan, R . Unusual role of labile phenolics in imparting flame resistance to polyamide . Polym. Degrad. Stabil. , 2020 . 175 109103 DOI: 10.1016/j.polymdegradstab.2020.109103 http://doi.org/10.1016/j.polymdegradstab.2020.109103 .

Jiang, P.; Zhao, Q.; Zhang, S.; Gu, X. Y.; Hu, Z. W.; Xu, G. Z . Flammability and char formation of polyamide 66 fabric: chemical grafting versus pad-dry process . Ind. Eng. Chem. Res. , 2015 . 54 6085 - 6092 . DOI: 10.1021/acs.iecr.5b01104 http://doi.org/10.1021/acs.iecr.5b01104 .

Kim, I.; Thompson, A. L.; Kim, S. C.; Hamins, A.; Bundy, M.; Nazaré, S.; Davis, R.D.; Zammarano, M . Demonstration of an all-in-one solution for fire safe upholstery furniture: a benign backcoating for smoldering and flame-resistant cover fabrics . Fire Mater. , 2022 . 46 677 - 693 . DOI: 10.1002/fam.3015 http://doi.org/10.1002/fam.3015 .

Li, Y.; Li, X.; Pan, Y. T.; Xu, X.; Song, Y.; Yang, R . Mitigation the release of toxic PH3 and the fire hazard of PA6/AHP composite by MOFs . J. Hazard. Mater. , 2020 . 395 122604 DOI: 10.1016/j.jhazmat.2020.122604 http://doi.org/10.1016/j.jhazmat.2020.122604 .

Norouzi, M.; Zare, Y.; Kiany, P . Nanoparticles as effective flame retardants for natural and synthetic textile polymers: application, mechanism, and optimization . Polym. Rev. , 2015 . 55 531 - 560 . DOI: 10.1080/15583724.2014.980427 http://doi.org/10.1080/15583724.2014.980427 .

Wang, X.; Kalali, E. N.; Wan, J. T.; Wang, D. Y . Carbon-family materials for flame retardant polymeric materials . Polym. Sci. , 2017 . 69 22 - 46 . DOI: 10.1016/j.progpolymsci.2017.02.001 http://doi.org/10.1016/j.progpolymsci.2017.02.001 .

Meng, D.; Guo, J.; Wang, A. J.; Gu, X. Y.; Wang, Z. W.; Jiang, S. L.; Zhang, S . The fire performance of polyamide 66 fabric coated with soybean protein isolation . Prog. Org. Coat. , 2020 . 148 105835 DOI: 10.1016/j.porgcoat.2020.105835 http://doi.org/10.1016/j.porgcoat.2020.105835 .

Zhou, Q.; Wu, W.; Zhou, S.; Xing, T.; Sun, G.; Chen, G . Polydopamine-induced growth of mineralized γ -FeOOH nanorods for construction of silk fabric with excellent superhydrophobicity, flame retardancy and UV resistance . Chem. Eng. J. , 2020 . 382 122988 DOI: 10.1016/j.cej.2019.122988 http://doi.org/10.1016/j.cej.2019.122988 .

Breuer, R.; Zhang, Y. X.; Erdmann, R.; Hernandez, O. E. V . Development and processing of flame retardant cellulose acetate compounds for foaming applications . J. Mater. Sci. , 2020 . 137 48863 DOI: 10.1002/app.48863 http://doi.org/10.1002/app.48863 .

Li, P.; Wang, B.; Xu, Y. J.; Jiang, Z.; Dong, C.; Liu, Y.; Zhu, P . Ecofriendly flame-retardant cotton fabrics: preparation, flame retardancy, thermal degradation properties, and mechanism . ACS Sustainable Chem. Eng. , 2019 . 7 19246 - 19256 . DOI: 10.1021/acssuschemeng.1c00220 http://doi.org/10.1021/acssuschemeng.1c00220 .

Zhang, Y.; Tian, W.; Liu, L.; Cheng, W.; Wang, W.; Liew, K. M.; Wang, B.; Hu, Y . Eco-friendly flame retardant and electromagnetic interference shielding cotton fabrics with multi-layered coatings . Chem. Eng. J. , 2019 . 372 1077 - 1090 . DOI: 10.1016/j.cej.2019.05.012 http://doi.org/10.1016/j.cej.2019.05.012 .

Liu, Y.; Pan, Y. T.; Wang, X.; Acuña, P.; Zhu, P.; Wagenknecht, U.; Heinrich, G.; Zhang, X. Q.; Wang, R.; Wang, D.Y . Effect of phosphorus-containing inorganic–organic hybrid coating on the flammability of cotton fabrics: Synthesis, characterization and flammability . Chem. Eng. J. , 2016 . 294 167 - 175 . DOI: 10.1016/j.cej.2016.02.080 http://doi.org/10.1016/j.cej.2016.02.080 .

Maddalena, L.; Carosio, F.; Gomez, J.; Saracco, G.; Fine, A . Layer-by-layer assembly of efficient flame retardant coatings based on high aspect ratio graphene oxide and chitosan capable of preventing ignition of PU foam . Polym. Degrad. Stabil. , 2019 . 152 1 - 9 . DOI: 10.1016/j.polymdegradstab.2018.03.013 http://doi.org/10.1016/j.polymdegradstab.2018.03.013 .

Qiu, X.; Li, Z.; Li, X.; Zhang, Z . Flame retardant coatings prepared using layer by layer assembly . Chem. Eng. J. , 2018 . 334 108 - 122 . DOI: 10.1016/j.cej.2017.09.194 http://doi.org/10.1016/j.cej.2017.09.194 .

Zhang, X.; Shi, M . Flame retardant vinylon/poly (m-phenylene isophthalamide) blended fibers with synergistic flame retardancy for advanced fireproof textiles . J. Hazard. Mater. , 2019 . 365 9 - 15 . DOI: 10.1016/j.jhazmat.2018.10.091 http://doi.org/10.1016/j.jhazmat.2018.10.091 .

Wang, B.; Li, P.; Xu, Y. J.; Jiang, Z. M.; Dong, C. H.; Liu, Y.; Zhu, P . Bio-based, nontoxic and flame-retardant cotton/alginate blended fibres as filling materials: thermal degradation properties, flammability and flame-retardant mechanism . Compos. Part B: Eng. , 2020 . 194 108038 DOI: 10.1016/j.compositesb.2020.108038 http://doi.org/10.1016/j.compositesb.2020.108038 .

Carosio, F.; Blasio, A. D.; Cuttica, F.; Alongi, J.; Malucelli, G . Flame retardancy of polyester and polyester-cotton blends treated with caseins . Ind. Eng. Chem. Res. , 2014 . 53 3917 - 3923 . DOI: 10.1021/ie404089t http://doi.org/10.1021/ie404089t .

Zhang, Q. H.; Dong, J.; Wu, D. Z.; Yang, S. Y. in Advanced Polyimide Fibers . Elsevier, Inc., Oxford, 2018 , p. 67−92.

Bhat, G.; Schwanke, R. . Thermal properties of a polyimide fiber . J. Therm. Anal. Calorim. , 1997 . 49 399 - 405 . DOI: 10.1007/bf01987463 http://doi.org/10.1007/bf01987463 .

Imura, Y.; Hogan, R.; Jaffe, M. in Advances in Filament Yarn Spinning of Textiles and Polymers . Elsevier, Oxford, 2014 , p. 187−202.

Snyder, R. W.; Thomson, B.; Bartges, B. Czerniawski, D.; Painter, P. C . FTIR studies of polyimides: thermal curing . Macromolecules , 1989 . 22 4166 - 4172 . DOI: 10.1021/ma00201a006 http://doi.org/10.1021/ma00201a006 .

Bao, F.; Zhang, R.; Dong, Z. X.; Qi, F. L.; Cai, Y. C.; Dai, X. M.; Ji, X. L.; Qiu, X. P . Comparison of high-performance polyimide copolymer fibers containing pyrimidine moieties based on coplanar structures . Polymer , 2021 . 231 124113 DOI: 10.1016/j.jmrt.2021.03.056 http://doi.org/10.1016/j.jmrt.2021.03.056 .

He, W. J.; Kong, C.; Cai, Y. D.; Ye, L.; Chen, S.T.; Li, S. H.; Zhao, X. W . Thermal stability enhancement of oriented polyethylene by formation of epitaxial shish-kebab crystalline structure . Polym. Degrad. Stabil. , 2022 . 195 109771 .

Wang, Q. Z.; Liu, C.; Xu, Y. J.; Liu, Y.; Zhu, P.; Wang, Y. Z . Highly efficient flame retardation of polyester fabrics via novel DOPO-modified sol-gel coatings . Polymer , 2021 . 226 123761 DOI: 10.1016/j.polymer.2021.123761 http://doi.org/10.1016/j.polymer.2021.123761 .

Sonnier, R.; Viretto, A.; Dumazert, L.; Gallard, B . A method to study the two-step decomposition of binary blends in cone calorimeter . Combust. Flame , 2016 . 169 1 - 10 . DOI: 10.1016/j.combustflame.2016.04.016 http://doi.org/10.1016/j.combustflame.2016.04.016 .

Gu, W. W.; Dong, Z. F.; Zhang, A. Y.; Ma, T. Y.; Hu, Q.; Wei, J. F.; Wang, R . Functionalization of PET with carbon dots as copolymerizable flame retardants for the excellent smoke suppressants and mechanical properties . Polym. Degrad. Stabil. , 2022 . 195 109766 DOI: 10.1016/j.polymdegradstab.2021.109766 http://doi.org/10.1016/j.polymdegradstab.2021.109766 .

Ding, Y.; Stoliarov, S. I.; Kraemer, R. H . Pyrolysis model development for a polymeric material containing multiple flame retardants: relationship between heat release rate and material composition . Combust. Flame , 2019 . 202 43 - 57 . DOI: 10.1016/j.combustflame.2019.01.003 http://doi.org/10.1016/j.combustflame.2019.01.003 .

Zhang, F. Q.; Wang, B.; Xu, Y. J.; Li, P.; Liu, Y.; Zhu, P . Convenient blending of alginate fibers with polyamide fibers for flame-retardant non-woven fabrics . Cellulose , 2020 . 27 8341 - 8349 . DOI: 10.1007/s10570-020-03331-2 http://doi.org/10.1007/s10570-020-03331-2 .

Zhang, S.; Fan, X.; Xu, C.; Ji, P.; Wang, C.; Wang, H . An inherently flame-retardant polyamide 6 containing a phosphorus group prepared by transesterification polymerization . Polymer , 2020 . 207 122890 DOI: 10.1016/j.polymer.2020.122890 http://doi.org/10.1016/j.polymer.2020.122890 .

Li, P.; Wang, Q. Z.; Wang, B.; Liu, Y. Y.; Xu, Y. J.; Liu, Y.; Zhu, P . Blending alginate fibers with polyester fibers for flame-retardant filling materials: Thermal decomposition behaviors and fire performance . Polym. Degrad. Stabil. , 2021 . 183 109470 DOI: 10.1016/j.polymdegradstab.2020.109470 http://doi.org/10.1016/j.polymdegradstab.2020.109470 .

Peng, H.; Wang, D.; Fu, S . Tannic acid-assisted green exfoliation and functionalization of MoS 2 nanosheets: Significantly improve the mechanical and flame-retardant properties of polyacrylonitrile composite fibers . Chem. Eng. J. , 2020 . 384 123288 DOI: 10.1016/j.cej.2019.123288 http://doi.org/10.1016/j.cej.2019.123288 .

Jung, D.; Bhattacharyya, D . Keratinous fiber based intumescent flame retardant with controllable functional compound loading . ACS Sustainable Chem. Eng. , 2018 . 6 13177 - 13184 . DOI: 10.1021/acssuschemeng.8b02756 http://doi.org/10.1021/acssuschemeng.8b02756 .

Peng, H.; Wang, D.; Li, M.; Zhang, L.; Liu, M.; Fu, S . NP-Zn-containing 2D supermolecular networks grown on MoS 2 nanosheets for mechanical and flame-retardant reinforcements of polyacrylonitrile fiber . Chem. Eng. J. , 2019 . 372 873 - 885 . DOI: 10.1016/j.cej.2019.04.209 http://doi.org/10.1016/j.cej.2019.04.209 .

Zhu, H. Q.; Zhao, H. R.; Wei, H. Y.; Wang, W.; Wang, H. R.; Li, K.; Lu, X. X.; Tan, B . Investigation into the thermal behavior and FTIR micro-characteristics of re-oxidation coal . Combust. Flame , 2020 . 216 354 - 368 . DOI: 10.1016/j.combustflame.2020.03.007 http://doi.org/10.1016/j.combustflame.2020.03.007 .

浏览量

239

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Synthesis, Characterization of Phosphorus Containing Diamide-diimidetetraamines Based on L-Tryptophan Amino Acid and Their Effect on Flame Retardancy of Epoxy Resins

Construction of Zinc Ion-reinforced Melamine Phosphate Flame Retardant for Synergistic Enhancement of Flame Retardancy and Energy Absorption in Ethylene-Vinyl Acetate Foams

Ingenious Engineering of Phosphorus and Nitrogen-enriched Nickel/Iron Bimetallic Phyllosilicates: Forging Multifunctional Epoxy Composites with Excellent Toughness, Self-lubrication, Wear Resistance and Flame Retardancy

Transparent UV-cured Phosphorus/Nitrogen Hybrid Coating for Simultaneously Enhancing Flame Retardancy and Surface Hardness of Polycarbonate

Preparation and Chiral Recognition Ability of Crystalline Cellulose Phenylcarbamate