Effects of Interface on the Dynamic Hysteresis Loss and Static Mechanical Properties of Illite Filled SBR Composites

Zhe-Peng Wang; Hao Zhang; Qiang Liu; Shao-Juan Wang; Shou-Ke Yan

doi:10.1007/s10118-022-2791-4

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Effects of Interface on the Dynamic Hysteresis Loss and Static Mechanical Properties of Illite Filled SBR Composites

RESEARCH ARTICLE | Updated：2022-10-25

- Effects of Interface on the Dynamic Hysteresis Loss and Static Mechanical Properties of Illite Filled SBR Composites
- Effects of Interface on the Dynamic Hysteresis Loss and Static Mechanical Properties of Illite Filled SBR Composites
- 高分子科学（英文版） 2022年40卷第11期页码：1493-1502
- Affiliations：
  
  a.Key Laboratory of Rubber-Plastics, Ministry of Education, Qingdao University of Science & Technology, Qingdao 266042, China
  b.State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
- Author bio：
  
  zhanghao@qust.edu.cn (H.Z.)
  skyan@buct.edu.cn skyan@qust.edu.cn (S.K.Y.)
- Funds：
  
  Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-022-2791-4.
- DOI：10.1007/s10118-022-2791-4
  中图分类号：
- 收稿：2022-03-08，
  
  修回：2022-4-22，
  
  录用：2022-5-12，
  
  网络首发：2022-08-17，
  
  纸质出版：2022-11-01
- Accepted：
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Wang, Z. P.; Zhang, H.; Liu, Q.; Wang, S. J.; Yan, S. K. Effects of interface on the dynamic hysteresis loss and static mechanical properties of illite filled SBR composites. Chinese J. Polym. Sci. 2022, 40, 1493–1502

Zhe-Peng Wang, Hao Zhang, Qiang Liu, et al. Effects of Interface on the Dynamic Hysteresis Loss and Static Mechanical Properties of Illite Filled SBR Composites[J]. Chinese Journal of Polymer Science, 2022, 40(11): 1493-1502.
Wang, Z. P.; Zhang, H.; Liu, Q.; Wang, S. J.; Yan, S. K. Effects of interface on the dynamic hysteresis loss and static mechanical properties of illite filled SBR composites. Chinese J. Polym. Sci. 2022, 40, 1493–1502 DOI： 10.1007/s10118-022-2791-4.

Zhe-Peng Wang, Hao Zhang, Qiang Liu, et al. Effects of Interface on the Dynamic Hysteresis Loss and Static Mechanical Properties of Illite Filled SBR Composites[J]. Chinese Journal of Polymer Science, 2022, 40(11): 1493-1502. DOI： 10.1007/s10118-022-2791-4.

摘要

Development of alternative reinforcement fillers for carbon black has attracted widespread attention. Her

the reinforcement of illite modified by organic silane on styrene butadiene rubber (SBR) was explored. The increment of tensile strength and modulus at 300% strain of more than 7 times demonstrates its potential application as reinforcing filler for SBR.

Abstract

Despite growing interest in nano-sized fillers

micro-sized fillers with desired compatibility are still used for reinforcing rubbers

owing to their lower production cost and easier processing relative to nano-sized fillers. Especially

the abundant and eco-friendly clay minerals are recognized as the materials of the twenty-first century. Herein

illite

a naturally occurring clay having dimension in micrometric scale

has been selected as filler to reinforce the SBR. To improve the compatibility of illite with SBR

the illite was modified by either bis[3-(triethoxysilyl)propyl] tetrasulfide (Si69-illite) or 3-mercaptopropyltriethoxysilane (KH580-illite). The interfacial interactions of SBR composites filled with pristine illite (illite/SBR) and Si69-illite (Si69-illite/SBR)

or KH580-illite (KH580-illite/SBR) were characterized by bound rubber content and Payne effect measurements

while dynamic hysteresis losses of these uncured and cured composites were also analyzed under various strain amplitudes. It was found that the filler-rubber interactions were greatly improved for Si69-illite/SBR and KH580-illite/SBR systems compared to the illite/SBR composite. This leads to an increment of modulus at 300% strain of the composites from 3.46 MPa for illite/SBR to 7.70 MPa for Si69-illite/SBR and 12.96 MPa for KH580-illite/SBR. Moreover

lower rolling resistance and better wear resistance without compromising wet traction of Si69-illite/SBR and KH580-illite/SBR have been achieved. This demonstrates the high possibility of Si69 and KH580 modified illites as promising alternative fillers for reinforcing rubbers.

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