Effect of Carbon Particles with Different Topological Shape on the Rheological Behavior of PVA Aqueous Dispersion

Qing-Sheng Ni; Miao Du; Guo-Rong Shan; Yi-Hu Song; Qiang Zheng

doi:10.1007/s10118-022-2777-2

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Effect of Carbon Particles with Different Topological Shape on the Rheological Behavior of PVA Aqueous Dispersion

RESEARCH ARTICLE | Updated：2022-10-25

- Effect of Carbon Particles with Different Topological Shape on the Rheological Behavior of PVA Aqueous Dispersion
- Effect of Carbon Particles with Different Topological Shape on the Rheological Behavior of PVA Aqueous Dispersion
- 高分子科学（英文版） 2022年40卷第11期页码：1402-1410
- Affiliations：
  
  a.State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
  b.Institute of Zhejiang University-Quzhou, Quzhou 324000, China
  c.Ministry of Education Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
- Author bio：
  
  dumiao@zju.edu.cn (M.D.)
  shangr@zju.edu.cn (G.R.S.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51873180, 52173024 and 51673172) and Zhejiang Provincial Natural Science Foundation of China (No. LGF20B040001).
- DOI：10.1007/s10118-022-2777-2
  中图分类号：
- 收稿：2022-02-18，
  
  修回：2022-4-11，
  
  录用：2022-4-23，
  
  网络首发：2022-07-20，
  
  纸质出版：2022-11-01
- Accepted：
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Ni, Q. S.; Du, M.; Shan, G. R.; Song, Y. H.; Zheng, Q. Effect of carbon particles with different topological shape on the rheological behavior of PVA aqueous dispersion. Chinese J. Polym. Sci. 2022, 40, 1402–1410

Qing-Sheng Ni, Miao Du, Guo-Rong Shan, et al. Effect of Carbon Particles with Different Topological Shape on the Rheological Behavior of PVA Aqueous Dispersion[J]. Chinese Journal of Polymer Science, 2022, 40(11): 1402-1410.
Ni, Q. S.; Du, M.; Shan, G. R.; Song, Y. H.; Zheng, Q. Effect of carbon particles with different topological shape on the rheological behavior of PVA aqueous dispersion. Chinese J. Polym. Sci. 2022, 40, 1402–1410 DOI： 10.1007/s10118-022-2777-2.

Qing-Sheng Ni, Miao Du, Guo-Rong Shan, et al. Effect of Carbon Particles with Different Topological Shape on the Rheological Behavior of PVA Aqueous Dispersion[J]. Chinese Journal of Polymer Science, 2022, 40(11): 1402-1410. DOI： 10.1007/s10118-022-2777-2.

摘要

In this work

carbon particles with different topological shapes were added into PVA aqueous dispersion to tune the steady and dynamic rheological behavior. 0D particle carbon black bring viscosity of PVA dispersion to increase monotonously. 1D particle CNTs make viscosity of PVA dispersion change as an N-shape. 2D particle GO make viscosity of PVA dispersion change as a U-shape. Shape and surface character of particle have synergistic effect on tuning viscosity of PVA dispersion.

Abstract

Poly(vinyl alcohol) (PVA) is usually processed and used in a form of aqueous dispersion. A large number of inter- and intramolecular hydrogen bonds make it very difficult to obtain suitable rheological behavior for processing. In this study

carbon particles with different topological shapes were added into PVA aqueous dispersion to tune the steady and dynamic rheological behavior. The results show that the zero-dimensional particles (carbon black

CB) increase monotonically the zero-shear viscosity of PVA dispersion

while the one-dimensional particles (carbon nanotubes

CNTs) make it first increase

and then decrease and rise again

like an N-shape

and the two-dimensional particles (graphene oxide

GO) can make it first decrease and then increase

exhibiting a U-shape. It is believed that the topological shape of the carbon particles brought about these discrepancies. The zero-dimensional particles mainly act as physical crosslinking points due to their small size. While at a certain content

both CNTs and GO can destroy the intermolecular hydrogen bonds between PVA chains because the PVA chains can twine around the slim CNTs and the large planar size of GO prevents the adsorbed PVA from forming hydrogen bond with other chains. The high hydroxyl value of carbon particle surface could strengthen this effect. It is expected that the viscosity of polymer dispersion can be regulated by particles with different topological shape and the surface characteristic

so as to widen the operable concentration range during preparing composite functional materials.

关键词

Keywords

references

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