Multistimuli Responsive and Thermoregulated Capability of Coaxial Electrospun Membranes with Core-sheath Structure and Functional Polypyrrole Layer

Meng-Hang Gao; Wen Feng; Xiao-Dong Qi; Yong Wang

doi:10.1007/s10118-022-2773-6

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Multistimuli Responsive and Thermoregulated Capability of Coaxial Electrospun Membranes with Core-sheath Structure and Functional Polypyrrole Layer

RESEARCH ARTICLE | Updated：2022-10-25

- Multistimuli Responsive and Thermoregulated Capability of Coaxial Electrospun Membranes with Core-sheath Structure and Functional Polypyrrole Layer
- Multistimuli Responsive and Thermoregulated Capability of Coaxial Electrospun Membranes with Core-sheath Structure and Functional Polypyrrole Layer
- 高分子科学（英文版） 2022年40卷第11期页码：1380-1388
- Affiliations：
  
  Key Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Materials Science & Engineering, Southwest Jiaotong University, Chengdu 610031, China
- Author bio：
  
  qxdjianhu@163.com (X.D.Q.)
  yongwang1976@swjtu.edu.cn (Y.W.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51803172 and 51673159), the Youth Science and Technology Innovation Team of Sichuan Province of Functional Polymer Composites (No. 2021JDTD0009) and the Key Research and Development Program of Sichuan Province (No. 2022YFG0281). SEM characterizations were supported by the Analytical and Testing Center of Southwest Jiaotong University.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-022-2773-6.
- DOI：10.1007/s10118-022-2773-6
  中图分类号：
- 收稿：2022-02-19，
  
  修回：2022-4-13，
  
  录用：2022-4-21，
  
  网络首发：2022-07-12，
  
  纸质出版：2022-11-01
- Accepted：
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Gao, M. H.; Feng, W.; Qi, X. D.; Wang, Y. Multistimuli responsive and thermoregulated capability of coaxial electrospun membranes with core-sheath structure and functional polypyrrole layer. Chinese J. Polym. Sci. 2022, 40, 1380–1388

Meng-Hang Gao, Wen Feng, Xiao-Dong Qi, et al. Multistimuli Responsive and Thermoregulated Capability of Coaxial Electrospun Membranes with Core-sheath Structure and Functional Polypyrrole Layer[J]. Chinese Journal of Polymer Science, 2022, 40(11): 1380-1388.
Gao, M. H.; Feng, W.; Qi, X. D.; Wang, Y. Multistimuli responsive and thermoregulated capability of coaxial electrospun membranes with core-sheath structure and functional polypyrrole layer. Chinese J. Polym. Sci. 2022, 40, 1380–1388 DOI： 10.1007/s10118-022-2773-6.

Meng-Hang Gao, Wen Feng, Xiao-Dong Qi, et al. Multistimuli Responsive and Thermoregulated Capability of Coaxial Electrospun Membranes with Core-sheath Structure and Functional Polypyrrole Layer[J]. Chinese Journal of Polymer Science, 2022, 40(11): 1380-1388. DOI： 10.1007/s10118-022-2773-6.

摘要

The layer of PPy has been uniformly deposited onto the PU@PEG coaxial electrospun membranes by electrochemical polymerization. Benefit from the outstanding light absorption and electrical conductivity of PPy

the PU@PEG-PPy membranes have good mechanical properties and respond quickly to sunlight or electric stimuli

displaying great application prospects in thermal management.

Abstract

Developing thermal management fabrics with good energy storage and multistimuli responsive properties is important for regulating the body temperature in complex environment. Herein

the intelligent nonwoven membranes were fabricated

via

a coaxial electrospinning method

resulting in a core-sheath structure with poly(ethylene glycol) (PEG) as core and polyurethane (PU) as sheath. Additionally

polypyrrole (PPy) with good light absorption ability and electrical conductivity was deposited onto the surface of the PU@PEG electrospun fibers

via

electrochemical polymerization. The PPy layer enabled the membranes to respond quickly to sunlight and electrical stimuli. The membranes could heat up to 86 °C under simulated sunlight within 200 s or produce remarkable electrothermal effect under a low voltage input of only 1 V

exhibiting efficient energy conversion and storage performances. The photothermal and electrothermal conversion effect could be easily adjusted by controlling the polymerization time of PPy. Therefore

the multifunctional membranes with high latent heat

good mechanical properties as well as excellent photothermal/electrothermal conversion ability are promising in personal thermal management applications.

关键词

Keywords

references

Pakdel, E.; Naebe, M.; Sun, L.; Wang, X. G . Advanced functional fibrous materials for enhanced thermoregulating performance . ACS Appl. Mater. Interfaces , 2019 . 11 13039 - 13057 . DOI: 10.1021/acsami.8b19067 http://doi.org/10.1021/acsami.8b19067 .

Shi, S.; Han, Y. T.; Hu, J. L . Robust waterproof and self-adaptive breathable membrane with heat retention property for intelligent protective cloth . Prog. Org. Coat. , 2019 . 137 105303 DOI: 10.1016/j.porgcoat.2019.105303 http://doi.org/10.1016/j.porgcoat.2019.105303 .

Li, G. Y.; Hong, G.; Dong, D. P.; Song, W. H.; Zhang, X. T . Multiresponsive graphene-aerogel-directed phase-change smart fibers . Adv. Mater. , 2018 . 30 1801754 DOI: 10.1002/adma.201801754 http://doi.org/10.1002/adma.201801754 .

Zhang, K. M.; Wang, Z.; Liu, Y. T.; Zhao, H. Y.; Gao, C. H.; Wu, Y. M . Cephalopods-inspired repairable MWCNTs/PDMS conductive elastomers for sensitive strain sensor . Chinese J. Polym. Sci. , 2022 . 40 384 - 393 . DOI: 10.1007/s10118-022-2674-8 http://doi.org/10.1007/s10118-022-2674-8 .

Zuo, X. L.; Wang, S. F.; Le, X . X.; Lu, W.; Chen, T. Self-healing polymeric hydrogels: toward multifunctional soft smart materials . Chinese J. Polym. Sci. , 2021 . 39 1262 - 1280 . DOI: 10.1007/s10118-021-2612-1 http://doi.org/10.1007/s10118-021-2612-1 .

Wu, J.; Hu, R.; Zeng, S.; Xi, W.; Huang, S.; Deng, J.; Tao, G . Flexible and robust biomaterial microstructured colored textiles for personal thermoregulation . ACS Appl. Mater. Interfaces , 2020 . 12 19015 - 19022 . DOI: 10.1021/acsami.0c02300 http://doi.org/10.1021/acsami.0c02300 .

Yu, X.; Li, Y.; Yin, X.; Wang, X.; Han, Y.; Si, Y.; Yu, J.; Ding, B . Corncoblike, superhydrophobic, and phase-changeable nanofibers for intelligent thermoregulating and water-repellent fabrics . ACS Appl. Mater. Interfaces , 2019 . 11 39324 - 39333 . DOI: 10.1021/acsami.9b12934 http://doi.org/10.1021/acsami.9b12934 .

Zhang, W.; Zhang, X.; Xu, Y.; Xu, Y.; Qiao, J.; Shi, T.; Huang, Z.; Liu, Y . G.; Fang, M.; Min, X.; Wu, X. Flexible polyethylene glycol/polyvinylpyrrolidone composite phase change fibres: preparation, characterization, and thermal conductivity enhancement . Polymer , 2021 . 214 123258 DOI: 10.1016/j.polymer.2020.123258 http://doi.org/10.1016/j.polymer.2020.123258 .

Lin, L.; Choi, Y.; Chen, T.; Kim, H.; Lee, K. S.; Kang, J. M.; Lyu, L.; Gao, J. F.; Piao, Y . Superhydrophobic and wearable TPU based nanofiber strain sensor with outstanding sensitivity for high-quality body motion monitoring . Chem. Eng. J. , 2021 . 419 129513 DOI: 10.1016/j.cej.2021.129513 http://doi.org/10.1016/j.cej.2021.129513 .

Huang, X. B.; Chen, X.; Li, A.; Atinafu, D.; Gao, H. Y.; Dong, W. J.; Wang, G . Shape-stabilized phase change materials based on porous supports for thermal energy storage applications . Chem. Eng. J. , 2019 . 356 641 - 661 . DOI: 10.1016/j.cej.2018.09.013 http://doi.org/10.1016/j.cej.2018.09.013 .

Xia, W.; Fei, X.; Wang, Q. Q.; Lu, Y. Y.; Innocent, M. T.; Zhou, J. L.; Yu, S. L.; Xiang, H. X.; Zhu, M. F. Nano-hybridized form-stable ester@F-SiO 2 phase change materials for melt-spun PA6 fibers engineered towards smart thermal management fabrics. Chem. Eng. J. 2021, 403 .126369.

Yang, J.; Tang, L. S.; Bai, L.; Bao, R. Y.; Liu, Z. Y.; Xie, B. H.; Yang, M. B.; Yang, W . High-performance composite phase change materials for energy conversion based on macroscopically three-dimensional structural materials . Mater. Horiz. , 2019 . 6 250 - 273 . DOI: 10.1039/C8MH01219A http://doi.org/10.1039/C8MH01219A .

Shi, J. M.; Qin, M. L.; Aftab, W.; Zou, R. Q . Flexible phase change materials for thermal energy storage . Energy Storage Mater. , 2021 . 41 321 - 342 . DOI: 10.1016/j.ensm.2021.05.048 http://doi.org/10.1016/j.ensm.2021.05.048 .

Hu, W. W.; Shi, X. Y.; Gao, M. H.; Huang, C. H.; Huang, T.; Zhang, N.; Yang, J. H.; Qi, X. D.; Wang, Y . Light-actuated shape memory and self-healing phase change composites supported by MXene/waterborne polyurethane aerogel for superior solar-thermal energy storage . Compos. Commun. , 2021 . 28 100980 DOI: 10.1016/j.coco.2021.100980 http://doi.org/10.1016/j.coco.2021.100980 .

Pantoja, M.; Alvarado, T.; Cakmak, M.; Cavicchi, K. A . Stearic acid infused polyurethane shape memory foams . Polymer , 2018 . 153 131 - 138 . DOI: 10.1016/j.polymer.2018.08.002 http://doi.org/10.1016/j.polymer.2018.08.002 .

Wu, Y.; Chen, C. Z.; Jia, Y. F.; Wu, J.; Huang, Y.; Wang, L. G . Review on electrospun ultrafine phase change fibers (PCFs) for thermal energy storage . Appl. Energy , 2018 . 210 167 - 181 . DOI: 10.1016/j.apenergy.2017.11.001 http://doi.org/10.1016/j.apenergy.2017.11.001 .

Yuan, M. J.; Hu, Z. Y.; Fang, H.; Li, S. J.; Guo, H. T.; Hu, R. B.; Jiang, S. H.; Liu, K. M.; Hou, H. Q . High performance electrospun polynaphthalimide nanofibrous membranes with excellent resistance to chemically harsh conditions . Chinese J. Polym. Sci. , 2021 . 39 1634 - 1644 . DOI: 10.1007/s10118-021-2634-8 http://doi.org/10.1007/s10118-021-2634-8 .

Feng, W.; Zhang, Y. S.; Shao, Y. W.; Huang, T.; Zhang, N.; Yang, J. H.; Qi, X. D.; Wang, Y . Coaxial electrospun membranes with thermal energy storage and shape memory functions for simultaneous thermal/moisture management in personal cooling textiles . Eur. Polym. J. , 2021 . 145 110245 DOI: 10.1016/j.eurpolymj.2020.110245 http://doi.org/10.1016/j.eurpolymj.2020.110245 .

Lu, Y.; Xiao, X. D.; Mo, J. M.; Huan, C. M.; Qi, S.; Zhan, Y. J.; Zhu, Y. Q.; Xu, G . Green nano-encapsulation technique for preparation of phase change nanofibers mats with core-sheath structure . Colloid Surf. A-Physicochem. Eng. Asp. , 2018 . 555 501 - 506 . DOI: 10.1016/j.colsurfa.2018.07.030 http://doi.org/10.1016/j.colsurfa.2018.07.030 .

McCann, J. T.; Marquez, M.; Xia, Y. N . Melt coaxial electrospinning: a versatile method for the encapsulation of solid materials and fabrication of phase change nanofibers . Nano Lett. , 2006 . 6 2868 - 2872 . DOI: 10.1021/nl0620839 http://doi.org/10.1021/nl0620839 .

Lu, Y.; Xiao, X. D.; Fu, J.; Huan, C. M.; Qi, S.; Zhan, Y. J.; Zhu, Y. Q.; Xu, G . Novel smart textile with phase change materials encapsulated core-sheath structure fabricated by coaxial electrospinning . Chem. Eng. J. , 2019 . 355 532 - 539 . DOI: 10.1016/j.cej.2018.08.189 http://doi.org/10.1016/j.cej.2018.08.189 .

Li, S. Q.; Wang, H. X.; Mao, H. Q.; Li, J.; Shi, H. F . Light-to-thermal conversion and thermoregulated capability of coaxial fibers with a combined influence from comb-like polymeric phase change material and carbon nanotube . ACS Appl. Mater. Interfaces , 2019 . 11 14150 - 14158 . DOI: 10.1021/acsami.9b02387 http://doi.org/10.1021/acsami.9b02387 .

Niu, Z. X.; Yuan, W. Z . Smart nanocomposite nonwoven wearable fabrics embedding phase change materials for highly efficient energy conversion-storage and use as a stretchable conductor . ACS Appl. Mater. Interfaces , 2021 . 13 4508 - 4518 . DOI: 10.1021/acsami.0c19674 http://doi.org/10.1021/acsami.0c19674 .

Ke, H. Z.; Ghulam, M. U. H.; Li, Y. G.; Wang, J.; Peng, B.; Cai, Y. B.; Wei, Q. F . Ag-coated polyurethane fibers membranes absorbed with quinary fatty acid eutectics solid-liquid phase change materials for storage and retrieval of thermal energy . Renew. Energy , 2016 . 99 1 - 9 . DOI: 10.1016/j.renene.2016.06.033 http://doi.org/10.1016/j.renene.2016.06.033 .

Du, J.; Liu, D.; Zhang, Z.; Yao, X.; Wan, D.; Pu, H.; Lu, Z . Dual-responsive triple-shape memory polyolefin elastomer/stearic acid composite . Polymer , 2017 . 126 206 - 210 . DOI: 10.1016/j.polymer.2017.08.039 http://doi.org/10.1016/j.polymer.2017.08.039 .

Hu, L. C.; Li, X.; Ding, L.; Chen, L. Y.; Zhu, X. Y.; Mao, Z. P.; Feng, X. L.; Sui, X. F.; Wang, B. J . Flexible textiles with polypyrrole deposited phase change microcapsules for efficient photothermal energy conversion and storage . Sol. Energy Mater. Sol. Cells , 2021 . 224 110985 DOI: 10.1016/j.solmat.2021.110985 http://doi.org/10.1016/j.solmat.2021.110985 .

Han, X. S.; Lv, L. L.; Yu, D. Y.; Wu, X. C.; Li, C. X . Conductive core-shell aramid nanofibrils: compromising conductivity with mechanical robustness for organic wearable sensing . ACS Appl. Mater. Interfaces , 2019 . 11 3466 - 3473 . DOI: 10.1021/acsami.8b18472 http://doi.org/10.1021/acsami.8b18472 .

Zhang, X. Y.; Duan, C. T.; Zhao, N.; Xiao, H.; Shi, M. W.; Zhang, X. l.; Xu, J . Facile fabrication of large scale microtubes with a natural template kapok fiber . Chinese J. Polym. Sci. , 2010 . 28 841 - 847 . DOI: 10.1007/s10118-010-0044-4 http://doi.org/10.1007/s10118-010-0044-4 .

Xiao, P.; Gu, J. C.; Zhang, C.; Ni, F.; Liang, Y.; He, J.; Zhang, L.; Ouyang, J. Y.; Kuo, S. W.; Chen, T . A scalable, low-cost and robust photo-thermal fabric with tunable and programmable 2D/3D structures towards environmentally adaptable liquid/solid-medium water extraction . Nano Energy , 2019 . 65 104002 DOI: 10.1016/j.nanoen.2019.104002 http://doi.org/10.1016/j.nanoen.2019.104002 .

Gao, Q.; Kopera, B. A. F.; Zhu, J.; Liao, X . J.; Gao, C.; Retsch, M.; Agarwal, S.; Greiner, A. Breathable and flexible polymer membranes with mechanoresponsive electric resistance . Adv. Funct. Mater. , 2020 . 30 1907555 DOI: 10.1002/adfm.201907555 http://doi.org/10.1002/adfm.201907555 .

Lai, W. C.; Chang, C. W.; Hsueh, C. Y . Shape-stabilized poly(ethylene glycol) phase change materials with self-assembled network scaffolds for thermal energy storage . Polymer , 2021 . 213 123196 DOI: 10.1016/j.polymer.2020.123196 http://doi.org/10.1016/j.polymer.2020.123196 .

Zhang, F. H.; Xia, Y. L.; Wang, L. L.; Liu, L. W.; Liu, Y. J.; Leng, J. S . Conductive shape memory microfiber membranes with core-shell structures and electroactive performance . ACS Appl. Mater. Interfaces , 2018 . 10 35526 - 35532 . DOI: 10.1021/acsami.8b12743 http://doi.org/10.1021/acsami.8b12743 .

Zhang, Q.; Wang, Q.; Wang, G. Y.; Zhang, Z. L.; Xia, S.; Gao, G. H . Ultrathin and highly tough hydrogel films for multifunctional strain sensors . ACS Appl. Mater. Interfaces , 2021 . 13 50411 - 50421 . DOI: 10.1021/acsami.1c15784 http://doi.org/10.1021/acsami.1c15784 .

Lin, F.; Zhang, X.; Liu, X.; Xu, Y.; Sun, Z.; Zhang, L.; Huang, Z.; Mi, R.; Min, X . Polyethylene glycol/modified carbon foam composites for efficient light-thermal conversion and storage . Polymer , 2021 . 228 123894 DOI: 10.1016/j.polymer.2021.123894 http://doi.org/10.1016/j.polymer.2021.123894 .

Wang, X.; Liu, Q. C.; Wu, S. Y.; Xu, B. X.; Xu, H. X . Multilayer polypyrrole nanosheets with self-organized surface structures for flexible and efficient solar-thermal energy conversion . Adv. Mater. , 2019 . 31 1807716 .

Li, J. Y.; Zhou, X.; Mu, P.; Wang, F.; Sun, H. X.; Zhu, Z. Q.; Zhang, J. W.; Li, W. W.; Li, A . Ultralight biomass porous foam with aligned hierarchical channels as salt-resistant solar steam generators . ACS Appl. Mater. Interfaces , 2020 . 12 798 - 806 . DOI: 10.1021/acsami.9b18398 http://doi.org/10.1021/acsami.9b18398 .

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