Crystalline, Rheological and Mechanical Enhancement in PBAT/PPC/Silica Nanocomposites with Double Percolation Network

You-Mei Ma; Feng-Xiang Gao; Shu-Ling Zhang

doi:10.1007/s10118-022-2753-x

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Crystalline, Rheological and Mechanical Enhancement in PBAT/PPC/Silica Nanocomposites with Double Percolation Network

RESEARCH ARTICLE | Updated：2022-10-25

- Crystalline, Rheological and Mechanical Enhancement in PBAT/PPC/Silica Nanocomposites with Double Percolation Network
- Crystalline, Rheological and Mechanical Enhancement in PBAT/PPC/Silica Nanocomposites with Double Percolation Network
- 高分子科学（英文版） 2022年40卷第11期页码：1482-1492
- Affiliations：
  
  a.College of Chemistry, Jilin University, Changchun 130012, China
  b.Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
- Author bio：
  
  zsl@jlu.edu.cn
- Funds：
  
  This work was financially supported by Jilin Province Industrial Technology Research and Development Project (No. 2021C036-1), and Jilin Province Science and Technology Development Program of China (No. 20200501004GX). The authors will thank Changchun Institute of Applied Chemistry, CAS for great help in experiments.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-022-2753-x.
- DOI：10.1007/s10118-022-2753-x
  中图分类号：
- 收稿：2022-02-28，
  
  修回：2022-3-20，
  
  录用：2022-4-5，
  
  网络首发：2022-06-24，
  
  纸质出版：2022-11-01
- Accepted：
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Ma, Y. M.; Gao, F. X.; Zhang, S. L. Crystalline, rheological and mechanical enhancement in PBAT/PPC/silica nanocomposites with double percolation network. Chinese J. Polym. Sci. 2022, 40, 1482–1492

You-Mei Ma, Feng-Xiang Gao, Shu-Ling Zhang. Crystalline, Rheological and Mechanical Enhancement in PBAT/PPC/Silica Nanocomposites with Double Percolation Network[J]. Chinese Journal of Polymer Science, 2022, 40(11): 1482-1492.
Ma, Y. M.; Gao, F. X.; Zhang, S. L. Crystalline, rheological and mechanical enhancement in PBAT/PPC/silica nanocomposites with double percolation network. Chinese J. Polym. Sci. 2022, 40, 1482–1492 DOI： 10.1007/s10118-022-2753-x.

You-Mei Ma, Feng-Xiang Gao, Shu-Ling Zhang. Crystalline, Rheological and Mechanical Enhancement in PBAT/PPC/Silica Nanocomposites with Double Percolation Network[J]. Chinese Journal of Polymer Science, 2022, 40(11): 1482-1492. DOI： 10.1007/s10118-022-2753-x.

摘要

The percolation threshold of silica was reduced to as low as 5 wt%. The crystalline

rheological and mechanical properties of PPC composites were improved which should attribute to the formation of double percolation structure.

Abstract

Nanocomposites of blends of biodegradable poly(butylene adipate-

-terephthalate) (PBAT) and sustainable poly(propylene carbonate) (PPC) with nanosilica were prepared by melt compounding method. PBAT/PPC blend was partially miscible system with sea-island structure

and nanosilica particles were selectively dispersed in the continuous phase PBAT matrix to form the double percolation network. The introduction of nanosilica into PBAT/PPC blend reduced the size of dispersed PPC phase

promoted the crystallization of PBAT in the nanocomposites

and increased the storage modulus of the nanocomposites. The study of rheological behaviors indicated that the double percolation network was formed at the nanosilica loading of 5 wt%

as a result

the nanocomposites exhibited the solid-like viscoelastic behavior and their relaxation time was extended. With the increase of the nanosilica content

the PBAT/PPC/silica nanocomposites displayed increased Young’s modulus and yield strength.

关键词

Keywords

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