Structure and Morphology of Poly(<italic style="font-style: italic">ε</italic>-caprolactone) Heterogeneous Shish-Kebab Structure Induced by Poly(lactic acid) Nanofibers

Zhong-Hua Chang; Dong-Fang Wang; Yi-Yang Xu; Meng-Yuan Zhang; Qian Li

doi:10.1007/s10118-022-2747-8

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Structure and Morphology of Poly(ε-caprolactone) Heterogeneous Shish-Kebab Structure Induced by Poly(lactic acid) Nanofibers

RESEARCH ARTICLE | Updated：2022-09-23

- Structure and Morphology of Poly(ε-caprolactone) Heterogeneous Shish-Kebab Structure Induced by Poly(lactic acid) Nanofibers
- Structure and Morphology of Poly(ε-caprolactone) Heterogeneous Shish-Kebab Structure Induced by Poly(lactic acid) Nanofibers
- Chinese Journal of Polymer Science 2022年40卷第10期页码：1223-1232
- Affiliations：
  
  a.School of Mechanics and Safety Engineering, Zhengzhou University, Zhengzhou 450001, China
  b.National Center for International Research of Micro-Nano Molding Technology, Zhengzhou University, Zhengzhou 450001, China
  c.School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China
- Author bio：
  
  qianli@zzu.edu.cn
- Funds：
  
  The authors affiliated with the Zhengzhou University acknowledge the research facility, the financial support from the National Center for International Joint Research of Micro-Nano Molding Technology in China, the International Science & Technology Cooperation Program of China (No. 2015DFA30550).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-022-2747-8.
- DOI：10.1007/s10118-022-2747-8
  中图分类号：
- 收稿：2022-01-08，
  
  修回：2022-3-17，
  
  录用：2022-3-29，
  
  网络首发：2022-07-20，
  
  纸质出版：2022-10-01
- Accepted：
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Chang, Z. H.; Wang, D. F.; Xu, Y. Y.; Zhang, M. Y.; Li, Q. Structure and morphology of poly(ε-caprolactone) heterogeneous shish-kebab structure induced by poly(lactic acid) nanofibers. Chinese J. Polym. Sci. 2022, 40, 1223–1232

Zhong-Hua Chang, Dong-Fang Wang, Yi-Yang Xu, et al. Structure and Morphology of Poly(ε-caprolactone) Heterogeneous Shish-Kebab Structure Induced by Poly(lactic acid) Nanofibers[J]. Chinese Journal of Polymer Science, 2022, 40(10): 1223-1232. DOI: 10.1007/s10118-022-2747-8.
Chang, Z. H.; Wang, D. F.; Xu, Y. Y.; Zhang, M. Y.; Li, Q. Structure and morphology of poly(ε-caprolactone) heterogeneous shish-kebab structure induced by poly(lactic acid) nanofibers. Chinese J. Polym. Sci. 2022, 40, 1223–1232 DOI： 10.1007/s10118-022-2747-8.

Zhong-Hua Chang, Dong-Fang Wang, Yi-Yang Xu, et al. Structure and Morphology of Poly(ε-caprolactone) Heterogeneous Shish-Kebab Structure Induced by Poly(lactic acid) Nanofibers[J]. Chinese Journal of Polymer Science, 2022, 40(10): 1223-1232. DOI: 10.1007/s10118-022-2747-8. DOI：

摘要

The hydrogen bonding interfacial interaction between PCL and PLA nanofibers modified by sodium hydroxide provides the driving force for the formation of the PLA/PCL heterogeneous shish-kebab structure. The heterogeneous structure provides a way to combine two poorly compatible polyester polymers.

Abstract

In recent years

the hybrid shish-kebab structure with excellent physical properties and functionalities has attracted much attention because it provides a way of blending nanofibers with different properties into polymer matrix in a regular arrangement. It is often not easy to induce the formation of the hierarchically ordered structure for the semi-crystalline polymer in heterogeneous shish-kebab structure. A poly(lactic acid) (PLA)/poly(

-caprolactone) (PCL) heterogeneous shish-kebab structure

i.e.

the PCL crystals periodically crystallized onto PLA nanofibers

was successfully created and the interfacial crystal morphology of the PLA/PCL heterogeneous shish-kebab structure was observed using scanning electron microscopy and atomic force microscopy. NaOH aqueous solution was applied to modify the surface of the PLA nanofibers to produce adsorption sites and carboxyl groups. The total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) and X-ray diffraction (XRD) results demonstrated that the formation of the heterogeneous shish-kebab structure was mainly due to the hydrogen bonding interaction between the kebab and shish interface

and the growth process of the kebab crystals also promoted the crystallization of the shish fibers. This heterogeneous nanostructure of biodegradable polymers will have great applications in tissue engineering and regenerative medicine.

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references

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DOI：10.1007/s10118-022-2747-8

摘要

Abstract

关键词

Keywords

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