The Effect of Substrate on the Properties of Non-volatile Ferroelectric P(VDF-TrFE)/P3HT Memory Devices

Xiao Chu; Jia-Qian Kang; Ya Hong; Guo-Dong Zhu; Shou-Ke Yan; Xue-Yun Wang; Xiao-Li Sun

doi:10.1007/s10118-022-2733-1

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The Effect of Substrate on the Properties of Non-volatile Ferroelectric P(VDF-TrFE)/P3HT Memory Devices

RESEARCH ARTICLE | Updated：2022-05-24

- The Effect of Substrate on the Properties of Non-volatile Ferroelectric P(VDF-TrFE)/P3HT Memory Devices
- The Effect of Substrate on the Properties of Non-volatile Ferroelectric P(VDF-TrFE)/P3HT Memory Devices
- Chinese Journal of Polymer Science 2022年40卷第6期页码：692-699
- Affiliations：
  
  a.State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  b.School of Aerospace Engineering, Beijing Institute of Technology, Beijing 100081, China
  c.Department of Materials Science, Fudan University, Shanghai 200433, China
  d.Key Laboratory of Rubber-Plastics, Ministry of Education/Shandong Provincial Key Laboratory of Rubber-plastics, Qingdao University of Science & Technology, Qingdao 266042, China
- Author bio：
  
  skyan@mail.buct.edu.cn (S.K.Y.)
  xueyun@bit.edu.cn (X.Y.W.)
  xiaolisun@mail.buct.edu.cn (X.L.S.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 21774011, 22022501 and 22073006).
- DOI：10.1007/s10118-022-2733-1
  中图分类号：
- 收稿：2022-01-05，
  
  修回：2022-3-8，
  
  录用：2022-3-12，
  
  网络首发：2022-05-05，
  
  纸质出版：2022-06-01
- Accepted：
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Chu, X.; Kang, J. Q.; Hong, Y.; Zhu, G. D.; Yan, S. K.; Wang, X. Y.; Sun, X. L. The effect of substrate on the properties of non-volatile ferroelectric P(VDF-TrFE)/P3HT memory devices. Chinese J. Polym. Sci. 2022, 40, 692–699

Xiao Chu, Jia-Qian Kang, Ya Hong, et al. The Effect of Substrate on the Properties of Non-volatile Ferroelectric P(VDF-TrFE)/P3HT Memory Devices[J]. Chinese Journal of Polymer Science, 2022, 40(6): 692-699.
Chu, X.; Kang, J. Q.; Hong, Y.; Zhu, G. D.; Yan, S. K.; Wang, X. Y.; Sun, X. L. The effect of substrate on the properties of non-volatile ferroelectric P(VDF-TrFE)/P3HT memory devices. Chinese J. Polym. Sci. 2022, 40, 692–699 DOI： 10.1007/s10118-022-2733-1.

Xiao Chu, Jia-Qian Kang, Ya Hong, et al. The Effect of Substrate on the Properties of Non-volatile Ferroelectric P(VDF-TrFE)/P3HT Memory Devices[J]. Chinese Journal of Polymer Science, 2022, 40(6): 692-699. DOI： 10.1007/s10118-022-2733-1.

摘要

By employing sandwich structure constructed by silver electrode and P3HT/P(VDF-TrFE) blend film on graphene substrate

high performance ferroelectric memory devices have been obtained

which exhibit a great electrical switching behavior with high ON/ OFF ratio of about 1000 and low coercive voltage of approximately 5 V.

Abstract

Ferroelectric poly(vinylidene fluoride-trifluoroethylene) (P(VDF-TrFE))/semiconducting poly(3-hexyl thiophene) (P3HT) blend systems have drawn great attention with their potential use for electronic applications

particularly non-volatile memory devices. It is essential to grasp a full understanding of the crystallization habits of the two polymers on different substrates for purposeful control of the structures of the blend and therefore the properties of the devices. Here

the effects of structure and morphology of the blend films generated at different substrate surfaces on the ferroelectric and switching properties of related devices are reported. It is identified that P(VDF-TrFE)/P3HT blend films prepared on graphene substrate show not only an obvious optimization in the ferroelectric behavior of P(VDF-TrFE)

but also an enhancement of the charge transport within P3HT domains. By employing sandwich structure constructed by silver electrode and P3HT/P(VDF-TrFE) blend film on graphene substrate

high-performance ferroelectric memory devices have been obtained

which exhibit a great electrical switching behavior with high ON/OFF ratio of about 1000 and low coercive voltage of approximately 5 V. These findings provide useful guidance for fabricating high-performance ferroelectric memory devices.

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references

Zhang, Z. C.; Wang, X.; Tan, S. B.; Wang, Q . Superior electrostrictive strain achieved under low electric fields in relaxor ferroelectric polymers . J. Mater. Chem. A , 2019 . 7 5201 - 5208 . DOI: 10.1039/C8TA11938D http://doi.org/10.1039/C8TA11938D .

Meng, N.; Ren, X. T.; Santagiuliana, G.; Ventura, L.; Zhang, H.; Wu, J. Y.; Yan, H. X.; Reece, M. J.; Bilotti, E . Ultrahigh β -phase content poly(vinylidene fluoride) with relaxor-like ferroelectricity for high energy density capacitors . Nat. Commun. , 2019 . 10 4535 - 4543 . DOI: 10.1038/s41467-019-12391-3 http://doi.org/10.1038/s41467-019-12391-3 .

Hicks, J. C.; Jones, T. E.; Logan, J. C . Ferroelectric properties of poly(vinylidene fluoridetetrafluoroethylene) . J. Appl. Phys. , 1978 . 49 6092 - 6096 . DOI: 10.1063/1.324528 http://doi.org/10.1063/1.324528 .

Hong, H.; Song, S. A.; Kim, S. S . Phase transformation of poly (vinylidene fluoride)/TiO 2 nanocomposite film prepared by microwave-assisted solvent evaporation: an experimental and molecular dynamics study . Compos. Sci. Technol. , 2020 . 199 108375 - 108385 . DOI: 10.1016/j.compscitech.2020.108375 http://doi.org/10.1016/j.compscitech.2020.108375 .

Liu, J. M.; Zhao, Q.; Dong, Y. F.; Sun, X. L.; Hu, Z. J.; Dong, H. L.; Hu W. Q.; Yan, S. K . Self-polarized poly(vinylidene fluoride) ultrathin film and its piezo/ferroelectric properties . ACS Appl. Mater. Interfaces. , 2020 . 12 29818 - 29825 . .

Mi, C.; Gao, N.; Li, H. H.; Liu J. T.; Sun, X. L.; Yan, S. K . The Effect of poly(vinyl phenol) on the ferroelectric performance of poly(vinylidene fluoride-trifluoroethylene) . ACS Appl. Polym. Mater. , 2019 . 1 1971 - 1978 . DOI: 10.1021/acsapm.9b00060 http://doi.org/10.1021/acsapm.9b00060 .

Gong, H. H.; Zhang, Y.; Cheng, Y. P.; Lei, M. X.; Zhang, Z. C . The application of controlled/living radical polymerization in modification of PVDF-based fluoropolymer . Chinese J. Polym. Sci. , 2021 . 39 1110 - 1126 . DOI: 10.1007/s10118-021-2616-x http://doi.org/10.1007/s10118-021-2616-x .

Song, T. T.; Wang, S. J.; Wang, H. J.; Sun, X. L.; Li, H. H.; Yan, S. K . The effect of illite on the crystallization of poly(vinylidene fluoride) . Ind. Eng. Chem. Res. , 2020 . 59 3438 - 3445 . DOI: 10.1021/acs.iecr.9b06432 http://doi.org/10.1021/acs.iecr.9b06432 .

Tang, Z. H.; Yang, S. H.; Wang, H. J.; Sun, X. L.; Ren, Z. J.; Li, H. H.; Yan, S. K . Phase transition behavior of poly(vinylidene fluoride) in a blend with poly(butylene adipate) at high temperature . Polymer , 2020 . 194 122409 - 11418 . DOI: 10.1016/j.polymer.2020.122409 http://doi.org/10.1016/j.polymer.2020.122409 .

Wang, M. Y.; Wang, S. J.; Hu, J.; Li, H. H.; Ren, Z. J.; Sun, X. L.; Wang, H. J.; Yan, S. K . Taming the phase transition ability of poly(vinylidene fluoride) from α to γ ’ phase . Macromolecules , 2020 . 53 5971 - 5979 . DOI: 10.1021/acs.macromol.0c01106 http://doi.org/10.1021/acs.macromol.0c01106 .

Mi, C.; Ren, Z. J.; Li, H. H.; Yan, S. K.; Sun, X. L . Synergistic effect of hydrogen bonds and diffusion on the β -crystallization of poly(vinylidene fluoride) on poly(methyl methacrylate) interface . Ind. Eng. Chem. Res. , 2019 . 58 7389 - 7396 . DOI: 10.1021/acs.iecr.8b05545 http://doi.org/10.1021/acs.iecr.8b05545 .

Wang, J. J.; Li, H. H.; Liu, J. C.; Duan, Y. X.; Jiang, S. D.; Yan, S. K . On the α→β transition of carbon coated highly oriented PVDF ultra-thin film induced by melt recrystallization . J. Am. Chem. Soc. , 2003 . 125 1496 - 1497 . DOI: 10.1021/ja029352r http://doi.org/10.1021/ja029352r .

Naber, R. C. G.; Tanase, C.; Blom, P. W. M.; Gelinck, G. H.; Marsman, A. W.; Touwslager, F. J.; Setayesh, S.; de Leeuw, D. M . High-performance solution-processed polymer ferroelectric field-effect transistors . Nat. Mater. , 2005 . 4 243 - 248 . DOI: 10.1038/nmat1329 http://doi.org/10.1038/nmat1329 .

Jung, H. J.; Chang, J.; Park, Y. J.; Kang, S . J.; Lotz, B.; Huh, J.; Park, C. Shear-induced ordering of ferroelectric crystals in spin-coated thin poly(vinylidene fluoride-co-trifluoroethylene) films . Macromolecules , 2009 . 42 4148 - 4154 . DOI: 10.1021/ma900422n http://doi.org/10.1021/ma900422n .

Lee, J. S.; Prabu, A. A.; Kim, K. J . Annealing effect upon chain orientation, crystalline morphology, and polarizability of ultra-thin P(VDF-TrFE) film for nonvolatile polymer memory device . Polymer , 2010 . 51 6319 - 6333 . DOI: 10.1016/j.polymer.2010.10.053 http://doi.org/10.1016/j.polymer.2010.10.053 .

Zeng, Z. G.; Zhu, G. D.; Zhang, L.; Yan, X. J . Effect of crystallinity on polarization fatigue of ferroelectric P(VDF-TrFE) copolymer films . Chinese J. Polym. Sci. , 2009 . 27 479 - 485 . DOI: 10.1142/S025676790900414X http://doi.org/10.1142/S025676790900414X .

Wang, J.; Li, Z.; Yan, Y.; Wang, X.; Xie, Y. C.; Zhang, Z. C . Improving ferro- and piezo- electric properties of hydrogenized poly(vinylidene fluoride-trifluoroethylene) films by annealing at elevated temperatures . Chinese J. Polym. Sci. , 2016 . 34 649 - 658 . DOI: 10.1007/s10118-016-1782-8 http://doi.org/10.1007/s10118-016-1782-8 .

Zhang, Q. P.; Xia, W. M.; Zhu, Z. G.; Zhang, Z. C . Crystal phase of poly(vinylidene fluoride- co -trifluoroethylene) synthesized via hydrogenation of poly(vinylidene fluoride- co -chlorotrifluoroethylene) . J. Appl. Polym. Sci. , 2013 . 127 3002 - 3008 . DOI: 10.1002/app.37975 http://doi.org/10.1002/app.37975 .

Wu, Y. J.; Li, X. H.; Weng, Y. Y.; Hu, Z. J.; Jonas, A. M . Orientation of lamellar crystals and its correlation with switching behavior in ferroelectric P(VDF-TrFE) ultra-thin films . Polymer , 2014 . 55 970 - 977 . DOI: 10.1016/j.polymer.2014.01.004 http://doi.org/10.1016/j.polymer.2014.01.004 .

Naber, R. C. G.; Asadi, K.; Blom, P. W. M.; de Leeuw, D. M.; de Boer, B . Organic nonvolatile memory devices based on ferroelectricity . Adv. Mater. , 2010 . 22 933 - 945 . DOI: 10.1002/adma.200900759 http://doi.org/10.1002/adma.200900759 .

Asadi, K.; de Leeuw, D. M.; de Boer, B.; Blom, P. W. M . Organic non-volatile memories from ferroelectric phase-separated blends . Nat. Mater. , 2008 . 7 547 - 550 . DOI: 10.1038/nmat2207 http://doi.org/10.1038/nmat2207 .

Li, M. Y.; Stingelin, N.; Michels, J. J.; Spijkman, M.; Asadi, K.; Beerends, R.; Biscarini, F.; Blom, P. W. M.; de Leeuw, D. M . Processing and low voltage switching of organic ferroelectric phase-separated bistable diodes . Adv. Funct. Mater. , 2012 . 22 2750 - 2757 . DOI: 10.1002/adfm.201102898 http://doi.org/10.1002/adfm.201102898 .

Breemen, A . V.; Zaba, T.; Khikhlovskyi, V.; Michels, J.; Janssen, R.; Kemerink, M.; Gelinck, G. Surface directed phase separation of semiconductor ferroelectric polymer blends and their use in non-volatile memories . Adv. Funct. Mater. , 2015 . 25 278 - 286 . DOI: 10.1002/adfm.201401896 http://doi.org/10.1002/adfm.201401896 .

Sung, S. H.; Boudouris, B. W . Systematic control of the nanostructure of semiconducting-ferroelectric polymer composites in thin film memory devices . ACS Macro Lett. , 2015 . 4 293 - 297 . DOI: 10.1021/mz5007766 http://doi.org/10.1021/mz5007766 .

Su, G. M.; Lim, E.; Jacobs, A. R.; Kramer, E. J.; Chabinyc, M. L . Polymer side chain modification alters phase separation in ferroelectric-semiconductor polymer blends for organic memory . ACS Macro Lett. , 2014 . 3 1244 - 1248 . DOI: 10.1021/mz5005647 http://doi.org/10.1021/mz5005647 .

Gutieŕrez-Fernańdez, E.; Rebollar, E.; Cui, J.; Ezquerra, T. A.; Nogales, A . Morphology and ferroelectric properties of semiconducting/ferroelectric polymer bilayers . Macromolecules , 2019 . 52 7396 - 7402 . DOI: 10.1021/acs.macromol.9b00859 http://doi.org/10.1021/acs.macromol.9b00859 .

Hwang, S. K.; Bae, I.; Kim, R. H.; Park, C . Flexible non-volatile ferroelectric polymer memory with gate-controlled multilevel operation . Adv. Mater. , 2012 . 24 5910 - 5914 . DOI: 10.1002/adma.201201831 http://doi.org/10.1002/adma.201201831 .

Serrano-Garcia, W.; Bonadies, I.; Thomas, S.; Guarino, V . P3HT loaded piezoelectric electrospun fibers for tunable molecular adsorption . Mater. Lett. , 2020 . 266 127458 - 127461 . DOI: 10.1016/j.matlet.2020.127458 http://doi.org/10.1016/j.matlet.2020.127458 .

Asadi, K.; Wondergem, H. J.; Moghaddam, R. S.; McNeill, C. R.; Stingelin, N.; Noheda, B.; Blom, P. W. M.; de Leeuw, D. M . Spinodal decomposition of blends of semiconducting and ferroelectric polymers . Adv. Funct. Mater. , 2011 . 21 1887 - 1894 . DOI: 10.1002/adfm.201001505 http://doi.org/10.1002/adfm.201001505 .

Asadi, K.; de Boer, T. G.; Blom, P. W. M.; de Leeuw, D. M . Tunable injection barrier in organic resistive switches based on phase-separated ferroelectric-semiconductor blends . Adv. Funct. Mater. , 2009 . 19 3173 - 3178 . DOI: 10.1002/adfm.200900383 http://doi.org/10.1002/adfm.200900383 .

Zhao, C.; Hong, Y.; Chu, X.; Dong, Y. F.; Hu, Z. J.; Sun, X. L.; Yan, S. K . Enhanced ferroelectric properties of P(VDF-TrFE) thin film on single-layer graphene simply adjusted by crystallization condition . Mater. Today Energy. , 2021 . 20 100678 - 100684 . DOI: 10.1016/j.mtener.2021.100678 http://doi.org/10.1016/j.mtener.2021.100678 .

Kim, K. L.; Lee W.; Hwang, S. K.; Joo, S. H.; Cho, S. M.; Song, G.; Cho, S. H.; Jeong, B.; Hwang, I.; Ahn, J.; Yu, Y.; Shin, T. J.; Kwak, S. K.; Kang, S. J.; Park, C . Epitaxial growth of thin ferroelectric polymer films on graphene layer for fully transparent and flexible nonvolatile memory . Nano Lett. , 2016 . 16 334 - 340 . DOI: 10.1021/acs.nanolett.5b03882 http://doi.org/10.1021/acs.nanolett.5b03882 .

Skrypnychuk, V.; Boulanger, N.; Yu, V.; Hilke, M.; Mannsfeld, S. C. B.; Toney, M. F.; Barbero, D. R . Enhanced vertical charge transport in a semiconducting P3HT thin film on single layer graphene . Adv. Funct. Mater. , 2014 . 25 653 - 659 . .

Tashiro, K.; Kobayashi, M.; Tadokoro, H.; Fukadalb, E . Calculation of elastic and piezoelectric constants of polymer crystals by a point charge model: application to poly(vinylidene fluoride) form I . Macromolecules , 1980 . 13 691 - 698 . DOI: 10.1021/ma60075a040 http://doi.org/10.1021/ma60075a040 .

Gomes, J.; Nunes, J . S.; Sencadas, V.; Lanceros-Mendez, S. Influence of the β -phase content and degree of crystallinity on the piezo- and ferroelectric properties of poly(vinylidene fluoride) . Smart Mater. Struct. , 2010 . 19 065010 - 065016 . DOI: 10.1088/0964-1726/19/6/065010 http://doi.org/10.1088/0964-1726/19/6/065010 .

Zhang, L.; Li, Y.; Shi, J.; Shi, G. Q.; Cao, S. K . Nonvolatile rewritable memory device based on solution-processable graphene/poly(3-hexylthiophene) nanocomposite . Mater. Chem. Phys. , 2013 . 142 626 - 632 . DOI: 10.1016/j.matchemphys.2013.08.007 http://doi.org/10.1016/j.matchemphys.2013.08.007 .

Liu, G.; Zhuang, X. D.; Chen, Y.; Zhang, B.; Zhu, J. H.; Zhu, C. X.; Neoh, K. G.; Kang, E. T . Bistable electrical switching and electronic memory effect in a solution-processable graphene oxide-donor polymer complex . Appl. Phys. Lett. , 2009 . 95 253301 - 253303 . DOI: 10.1063/1.3276556 http://doi.org/10.1063/1.3276556 .

Zhuang, X. D.; Chen, Y.; Liu, G.; Li, P. P.; Zhu, C. X.; Kang, E. T.; Noeh, K. G.; Zhang, B.; Zhu, J. H.; Li, Y. X . Conjugated-polymer-functionalized graphene oxide: synthesis and nonvolatile rewritable memory effect . Adv. Mater. , 2010 . 22 1731 - 1735 . DOI: 10.1002/adma.200903469 http://doi.org/10.1002/adma.200903469 .

Chen, Y.; Zhang, B.; Lin, G.; Zhuang, X.; Kang, E. T . Graphene and its derivatives: switching ON and OFF . Chem. Soc. Rev. , 2012 . 41 4688 - 4707 . DOI: 10.1039/c2cs35043b http://doi.org/10.1039/c2cs35043b .

Zhang, B.; Chen, Y.; Liu, G.; Xu, L. Q.; Chen, J.; Zhu, C. X.; Neoh, K. G.; Kang, E. T . Push-pull archetype of reduced graphene oxide functionalized with polyfluorene for nonvolatile rewritable memory . J. Polym. Sci., Part A: Polym. Chem. , 2012 . 50 378 - 387 . DOI: 10.1002/pola.25043 http://doi.org/10.1002/pola.25043 .

Jin, Y.; Yu, F.; Kuppa, V. K . Three-fold improvement in the performance of all-polymer photovoltaic devices with graphene . Mater. Lett. , 2015 . 156 161 - 164 . DOI: 10.1016/j.matlet.2015.04.103 http://doi.org/10.1016/j.matlet.2015.04.103 .

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