Thiazole-Flanked Thiazoloisoindigo as a Monomer for Balanced Ambipolar Polymeric Field-effect Transistors

Si-Yu Lv; Qi-Yi Li; Bo-Wen Li; Jie-Yu Wang; You-Bing Mu; Liang Li; Jian Pei; Xiao-Bo Wan

doi:10.1007/s10118-022-2731-3

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Thiazole-Flanked Thiazoloisoindigo as a Monomer for Balanced Ambipolar Polymeric Field-effect Transistors

RESEARCH ARTICLE | Updated：2022-09-23

- Thiazole-Flanked Thiazoloisoindigo as a Monomer for Balanced Ambipolar Polymeric Field-effect Transistors
- Thiazole-Flanked Thiazoloisoindigo as a Monomer for Balanced Ambipolar Polymeric Field-effect Transistors
- Chinese Journal of Polymer Science 2022年40卷第10期页码：1131-1140
- Affiliations：
  
  a.Key Laboratory of Optoelectronic Chemical Materials and Devices, Ministry of Education, School of Optoelectronic Materials & Technology, Jianghan University, Wuhan 430056, China
  b.Beijing National Laboratory for Molecular Sciences, the Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
  c.School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan 430205, China
- Author bio：
  
  libw@jhun.edu.cn (B.W.L.)
  muyb@jhun.edu.cn (Y.B.M.)
  jianpei@pku.edu.cn (J.P.)
  wanxb@jhun.edu.cn (X.B.W.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 22075105 and 22102086) and the start-up funding from Jianghan University. We thank Prof. Chunming Yang and Prof. Xichang Bao and Shanghai Synchrotron Radiation Facility for GIWAXS test and analysis.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-022-2731-3.
- DOI：10.1007/s10118-022-2731-3
  中图分类号：
- 收稿：2022-01-11，
  
  修回：2022-2-28，
  
  录用：2022-3-7，
  
  网络首发：2022-06-17，
  
  纸质出版：2022-10-01
- Accepted：
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Lv, S. Y.; Li, Q. Y.; Li, B. W.; Wang, J. Y.; Mu, Y. B.; Li, L.; Pei, J.; Wan, X. B. Thiazole-flanked thiazoloisoindigo as a monomer for balanced ambipolar polymeric field-effect transistors. Chinese J. Polym. Sci. 2022, 40, 1131–1140

Si-Yu Lv, Qi-Yi Li, Bo-Wen Li, et al. Thiazole-Flanked Thiazoloisoindigo as a Monomer for Balanced Ambipolar Polymeric Field-effect Transistors[J]. Chinese Journal of Polymer Science, 2022, 40(10): 1131-1140.
Lv, S. Y.; Li, Q. Y.; Li, B. W.; Wang, J. Y.; Mu, Y. B.; Li, L.; Pei, J.; Wan, X. B. Thiazole-flanked thiazoloisoindigo as a monomer for balanced ambipolar polymeric field-effect transistors. Chinese J. Polym. Sci. 2022, 40, 1131–1140 DOI： 10.1007/s10118-022-2731-3.

Si-Yu Lv, Qi-Yi Li, Bo-Wen Li, et al. Thiazole-Flanked Thiazoloisoindigo as a Monomer for Balanced Ambipolar Polymeric Field-effect Transistors[J]. Chinese Journal of Polymer Science, 2022, 40(10): 1131-1140. DOI： 10.1007/s10118-022-2731-3.

摘要

The copolymerization of Thiazole-flanked thiazoloisoindigo with thiophene resulted in a conjugated polymer with balanced hole and electron mobility.

Abstract

Electron-rich thiophene-flanked thiazoloisoindigo (Th-TzII) has been reported as a building block for ambipolar polymeric field-effect transistors however with preferable hole transport. Here

we report that by using an electron deficient thiazole as the flanked moiety

the corresponding thiazoloisoindigo (Tz-TzII) can still be synthesized

although in a more sinuous way. Theoretical calculation and experimental results demonstrate that Tz-TzII is more electron-deficient than Th-TzII

and the corresponding polymer P(TzII-Tz-T-Tz) exhibits high and balanced hole/electron mobility of 0.70/0.64 cm

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references

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