An Alternative Technique for Compounding and Fabrication of Lithium Ion Conductive PVB Films with Enhanced Thermal Properties and Electrochromic Performance

Mohammad Hossein Azarian; Jatuphorn Wootthikanokkhan

doi:10.1007/s10118-022-2729-x

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An Alternative Technique for Compounding and Fabrication of Lithium Ion Conductive PVB Films with Enhanced Thermal Properties and Electrochromic Performance

RESEARCH ARTICLE | Updated：2022-09-23

- An Alternative Technique for Compounding and Fabrication of Lithium Ion Conductive PVB Films with Enhanced Thermal Properties and Electrochromic Performance
- An Alternative Technique for Compounding and Fabrication of Lithium Ion Conductive PVB Films with Enhanced Thermal Properties and Electrochromic Performance
- Chinese Journal of Polymer Science 2022年40卷第10期页码：1213-1222
- Affiliations：
  
  Materials Technology Program, School of Energy, Environment and Materials, King Mongkut’s University of Technology Thonburi, Bangkok 10140,Thailand
- Author bio：
  
  Jatuphorn.woo@kmutt.ac.th
- Funds：
  
  The authors are grateful to support by the “Thailand Science Research and Innovation (TSRI) under Fundamental Fund 2022 (Sustainable Energy & Environment Theme).
- DOI：10.1007/s10118-022-2729-x
  中图分类号：
- 收稿：2021-12-04，
  
  修回：2022-2-7，
  
  录用：2022-3-1，
  
  网络首发：2022-05-27，
  
  纸质出版：2022-10-01
- Accepted：
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Azarian, M. H.; Wootthikanokkhan, J. An alternative technique for compounding and fabrication of lithium ion conductive PVB films with enhanced thermal properties and electrochromic performance. Chinese J. Polym. Sci. 2022, 40, 1213–1222

Mohammad Hossein Azarian, Jatuphorn Wootthikanokkhan. An Alternative Technique for Compounding and Fabrication of Lithium Ion Conductive PVB Films with Enhanced Thermal Properties and Electrochromic Performance[J]. Chinese Journal of Polymer Science, 2022, 40(10): 1213-1222.
Azarian, M. H.; Wootthikanokkhan, J. An alternative technique for compounding and fabrication of lithium ion conductive PVB films with enhanced thermal properties and electrochromic performance. Chinese J. Polym. Sci. 2022, 40, 1213–1222 DOI： 10.1007/s10118-022-2729-x.

Mohammad Hossein Azarian, Jatuphorn Wootthikanokkhan. An Alternative Technique for Compounding and Fabrication of Lithium Ion Conductive PVB Films with Enhanced Thermal Properties and Electrochromic Performance[J]. Chinese Journal of Polymer Science, 2022, 40(10): 1213-1222. DOI： 10.1007/s10118-022-2729-x.

摘要

A pilot electrochromic cell with a configuration of ITO/PVB electrolyte/WO

/ITO was prepared

via

the laminating of PVB solid electrolyte film between ITO and ITO/WO

substrates

at 100 °C using heat gun and pressing them with clamps. The WO

thin film was firstly deposited on ITO glasses by sol-gel technique via spin-coating method.

Abstract

This research concerns the development of lithium ions conductive electrolyte from poly(vinyl butyral) (PVB) resin for use as a special interlayer film in electrochromic glass. To obtain the final PVB film with high ionic conductivity and thermal stability

a masterbatch was firstly prepared by mixing of PVB resin with lithium salt (LiClO

) and additives in an aqueous ethanol solution. After this

the dried masterbatch were converted into final films by an extrusion process. In this study

PVB film with the highest ionic conductivity value of 4.85×10

−6

was obtained when the masterbatch was diluted with the neat PVB resin at the weight ratio of 2:1 in the extruder prior to fabrication. The results from cyclic voltammetry over 100 cycles

showed that performance of the electrochromic device (ITO/WO

/PVB electrolyte/ITO) fabricated by using the above PVB film is stable and reversible. In overall

this work demonstrates that ion conductive PVB films with compromised ionic conductivity and thermal stability can be prepared

via

an extrusion process without the need to modify chemical structure of PVB. This was carried out through the masterbatch approach

by introducing LiClO

salts into the plasticized PVB

via

a solution mixing process prior to converting it into a final film

via

the extrusion process.

关键词

Keywords

references

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