Fractal Growth of Giant Amphiphiles in Langmuir-Blodgett Films

Wei-Jie Wang; Xian Xu; Yu Shao; Jian-Wen Liao; Han-Xin Jian; Bing Xue; Shu-Guang Yang

doi:10.1007/s10118-022-2722-4

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Fractal Growth of Giant Amphiphiles in Langmuir-Blodgett Films

REVIEW | Updated：2022-05-24

- Fractal Growth of Giant Amphiphiles in Langmuir-Blodgett Films
- Fractal Growth of Giant Amphiphiles in Langmuir-Blodgett Films
- Chinese Journal of Polymer Science 2022年40卷第6期页码：556-566
- Affiliations：
  
  a.State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-dimension Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
  b.Beijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Center for Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
- Author bio：
  
  shgyang@dhu.edu.cn
- Funds：
  
  This work was financially supported by the Research Fund Program of Guangdong Provincial Key Laboratory of Function and Intelligent Hybrid Materials and Devices (No. 2019B121203003). Authors thank Prof. W. B. Zhang at Peking University for his valuable discussion and suggestions.
- DOI：10.1007/s10118-022-2722-4
  中图分类号：
- 收稿：2022-01-26，
  
  修回：2022-2-17，
  
  录用：2022-2-22，
  
  网络首发：2022-04-25，
  
  纸质出版：2022-06-01
- Accepted：
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Wang, W. J.; Xu, X.; Shao, Y.; Liao, J. W.; Jian, H. X.; Xue, B.; Yang, S. G. Fractal growth of giant amphiphiles in langmuir-blodgett films. Chinese J. Polym. Sci. 2022, 40, 556–566

Wei-Jie Wang, Xian Xu, Yu Shao, et al. Fractal Growth of Giant Amphiphiles in Langmuir-Blodgett Films[J]. Chinese Journal of Polymer Science, 2022, 40(6): 556-566.
Wang, W. J.; Xu, X.; Shao, Y.; Liao, J. W.; Jian, H. X.; Xue, B.; Yang, S. G. Fractal growth of giant amphiphiles in langmuir-blodgett films. Chinese J. Polym. Sci. 2022, 40, 556–566 DOI： 10.1007/s10118-022-2722-4.

Wei-Jie Wang, Xian Xu, Yu Shao, et al. Fractal Growth of Giant Amphiphiles in Langmuir-Blodgett Films[J]. Chinese Journal of Polymer Science, 2022, 40(6): 556-566. DOI： 10.1007/s10118-022-2722-4.

摘要

LB films of giant amphiphiles composed of poly(ethylene oxide) (PEO) and polyhedral oligomeric silsesquioxanes (POSS) derivatives present fractal growth patterns. POSS modification

PEO chain length

molecular topology

and surface pressure affect the fractal growth patterns.

Abstract

Fractal structures have attracted considerable scientific interest

and fractal geometry is an effective tool to study the complicated structure and dynamic processes

such as dilation symmetry of disorder structure

percolation

gelation

and metal-insulator transition. Here

we summarized our findings of fractal growth of giant amphiphiles in Langmuir-Blodgett (LB) film. Giant amphiphiles composed of polyhedral oligomeric silsesquioxanes (POSS) derivatives and poly(ethylene oxide) (PEO)

with structural diversities of POSS head modification

POSS head number

PEO chain length

are precisely synthesized. The effect of molecular structures and operation parameters on the fractal growth patterns are discussed

in addition

other fractal growth patterns in LB films and in Langmuir films are included

aiming to understand the basic molecular principle of fractal growth in LB system.

关键词

Keywords

references

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