Polar Phase Formation and Piezoelectricity of PVDF by Hot-pressing under Electrostatic Intermolecular Interactions

Jing-Hua Zhao; Bao-Sheng He; Ao-Shen Li; Chao-Nan Wang; Qing-Qing Li; Zhi-Jun Hu

doi:10.1007/s10118-022-2706-4

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Polar Phase Formation and Piezoelectricity of PVDF by Hot-pressing under Electrostatic Intermolecular Interactions

RESEARCH ARTICLE | Updated：2022-06-22

- Polar Phase Formation and Piezoelectricity of PVDF by Hot-pressing under Electrostatic Intermolecular Interactions
- Polar Phase Formation and Piezoelectricity of PVDF by Hot-pressing under Electrostatic Intermolecular Interactions
- Chinese Journal of Polymer Science 2022年40卷第7期页码：799-806
- Affiliations：
  
  a.Center for Soft Condensed Matter Physics and Interdisciplinary Research, Soochow University, Suzhou 215123, China
  b.School of Optoelectronics Science and Engineering & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou 215006, China
  c.Key Lab of Advanced Optical Manufacturing Technologies of Jiangsu Province & Key Lab of Modern Optical Technologies of Education Ministry of China, Soochow University, Suzhou 215006, China
- Author bio：
  
  zhijun.hu@suda.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51973150 and 21674076), the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (No. 19KJA320009), and a Project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).
- DOI：10.1007/s10118-022-2706-4
  中图分类号：
- 收稿：2021-12-17，
  
  修回：2022-1-18，
  
  录用：2022-1-28，
  
  网络首发：2022-04-01，
  
  纸质出版：2022-07-01
- Accepted：
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Zhao, J. H.; He, B. S.; Li, A. S.; Wang, C. N.; Li, Q. Q.; Hu, Z. J. Polar phase formation and piezoelectricity of PVDF by hot-pressing under electrostatic intermolecular interactions. Chinese J. Polym. Sci. 2022, 40, 799–806

Jing-Hua Zhao, Bao-Sheng He, Ao-Shen Li, et al. Polar Phase Formation and Piezoelectricity of PVDF by Hot-pressing under Electrostatic Intermolecular Interactions[J]. Chinese Journal of Polymer Science, 2022, 40(7): 799-806.
Zhao, J. H.; He, B. S.; Li, A. S.; Wang, C. N.; Li, Q. Q.; Hu, Z. J. Polar phase formation and piezoelectricity of PVDF by hot-pressing under electrostatic intermolecular interactions. Chinese J. Polym. Sci. 2022, 40, 799–806 DOI： 10.1007/s10118-022-2706-4.

Jing-Hua Zhao, Bao-Sheng He, Ao-Shen Li, et al. Polar Phase Formation and Piezoelectricity of PVDF by Hot-pressing under Electrostatic Intermolecular Interactions[J]. Chinese Journal of Polymer Science, 2022, 40(7): 799-806. DOI： 10.1007/s10118-022-2706-4.

摘要

Piezoelectricity can be obtained by directly hot pressing poly(vinylidene fluoride) films sandwiched between chitosan or cellulose films. The electrostatic interactions enable an exceptional high content of polar phases (- and -phases) up to 90% and a measured piezoelectric charge coefficient d33 of up to -30 pC/N.

Abstract

Piezoelectric poly(vinylidene fluoride) (PVDF) has received considerable attention due to its ability of interconverting mechanical into electric energies and potential applications in wearable electronics. To achieve piezoelectricity

it is important to simultaneously control the formation of polar phases

crystallinity

and dipole alignments in PVDF-based films. Here we demonstrate that piezoelectricity can be obtained by directly hot-pressing PVDF films sandwiched between chitosan or cellulose films. The electrostatic interactions between PVDF and chitosan or cellulose enabled an exceptional high content of polar phases (

- and

-phases) up to 90% and a measured piezoelectric charge coefficient

of up to −30 pC/N. This study provides a simple and low-cost approach for obtaining piezoelectric PVDF films used for sensors

actuators

and energy harvesters.

关键词

Keywords

references

Kawai, H . The piezoelectricity of poly(vinylidene fluoride) . Jan. J. Appl. Phys. , 1969 . 8 975 - 976 . DOI: 10.1143/JJAP.8.975 http://doi.org/10.1143/JJAP.8.975 .

Mahapatra, S. D.; Mohapatra, P. C.; Aria, A. I.; Christie, G.; Mishra, Y. K.; Hofmann, S.; Thakur, V. K . Piezoelectric materials for energy harvesting and sensing applications: roadmap for future smart materials . Adv. Sci. , 2021 . 8 e2100864 DOI: 10.1002/advs.202100864 http://doi.org/10.1002/advs.202100864 .

Barbara, S.; Martin, Z.; Mihai, I . Route towards sustainable smart sensors: ferroelectric polyvinylidene fluoride-based materials and their integration in flexible electronics . Chem. Soc. Rev. , 2019 . 48 1787 - 1825 . DOI: 10.1039/C8CS00928G http://doi.org/10.1039/C8CS00928G .

Soulestin, T.; Ladmiral, V.; Dos Santos, F. D.; Améduri, B. Vinylidene fluoride- and trifluoroethylene-containing fluorinated electroactive copolymers . How does chemistry impact properties . Prog. Polym. Sci. , 2017 . 72 16 - 60 . DOI: 10.1016/j.progpolymsci.2017.04.004 http://doi.org/10.1016/j.progpolymsci.2017.04.004 .

Martins, P.; Lopes, A. C.; Lanceros-Mendez, S . Electroactive phases of poly(vinylidene fluoride): determination, processing and applications . Prog. Polym. Sci. , 2014 . 39 683 - 706 . DOI: 10.1016/j.progpolymsci.2013.07.006 http://doi.org/10.1016/j.progpolymsci.2013.07.006 .

Bystrov, V. S.; Paramonova, E. V.; Bdikin, I. K.; Bystrova, A. V.; Pullar, R. C.; Kholkin, A. L . Molecular modeling of the piezoelectric effect in the ferroelectric polymer poly(vinylidene fluoride) (PVDF) . J. Mol. Model. , 2013 . 19 3591 - 3602 . DOI: 10.1007/s00894-013-1891-z http://doi.org/10.1007/s00894-013-1891-z .

Katsouras, I.; Asadi, K.; Li, M.; van Driel, T. B.; Kjaer, K. S.; Zhao, D.; Lenz, T.; Gu, Y.; Blom, P. W.; Damjanovic, D.; Nielsen, M. M.; de Leeuw, D. M . The negative piezoelectric effect of the ferroelectric polymer poly(vinylidene fluoride) . Nat. Mater. , 2016 . 15 78 - 84 . DOI: 10.1038/nmat4423 http://doi.org/10.1038/nmat4423 .

Mishra, S.; Unnikrishnan, L.; Nayak, S. K.; Mohanty, S . Advances in piezoelectric polymer composites for energy harvesting applications: a systematic review . Macromol. Mater. Eng. , 2019 . 304 1800463 DOI: 10.1002/mame.201800463 http://doi.org/10.1002/mame.201800463 .

Li, M.; Wondergem, H. J.; Spijkman, M. J.; Asadi, K.; Katsouras, I.; Blom, P. W.; de Leeuw, D. M . Revisiting the delta-phase of poly(vinylidene fluoride) for solution-processed ferroelectric thin films . Nat. Mater. , 2013 . 12 433 - 438 . DOI: 10.1038/nmat3577 http://doi.org/10.1038/nmat3577 .

Zheng, Y.; Zhang, J.; Sun, X.; Li, H.; Ren, Z.; Yan, S . Enhanced αγ ′ transition of poly(vinylidene fluoride) by step crystallization and subsequent annealing . Chinese J. Polym. Sci. , 2018 . 36 598 - 603 . DOI: 10.1007/s10118-018-2040-z http://doi.org/10.1007/s10118-018-2040-z .

Gomes, J.; Serrado Nunes, J.; Sencadas, V.; Lanceros-Mendez, S . Influence of the β -phase content and degree of crystallinity on the piezo- and ferroelectric properties of poly(vinylidene fluoride) . Smart Mater. Struct. , 2010 . 19 065010 DOI: 10.1088/0964-1726/19/6/065010 http://doi.org/10.1088/0964-1726/19/6/065010 .

Liu, J.; Zhao, Q.; Dong, Y.; Sun, X.; Hu, Z.; Dong, H.; Hu, W.; Yan, S . Self-polarized poly(vinylidene fluoride) ultrathin film and its piezo/ferroelectric properties . ACS Appl. Mater. Interfaces , 2020 . 12 29818 - 29825 . DOI: 10.1021/acsami.0c06809 http://doi.org/10.1021/acsami.0c06809 .

Kang, S. J.; Park, Y. J.; Hwang, J. Y.; Jeong, H. J.; Lee, J. S.; Kim, K. J.; Kim, H . C.; Huh, J.; Park, C. Localized pressure-induced ferroelectric pattern arrays of semicrystalline poly(vinylidene fluoride) by microimprinting . Adv. Mater. , 2007 . 19 581 - 586 . DOI: 10.1002/adma.200601474 http://doi.org/10.1002/adma.200601474 .

Huang, Z.; Wang, M.; Feng, Y.; Qu, J . β -Phase formation of polyvinylidene fluoride via hot pressing under cyclic pulsating pressure . Macromolecules , 2020 . 53 8494 - 8501 . DOI: 10.1021/acs.macromol.0c01609 http://doi.org/10.1021/acs.macromol.0c01609 .

Li, Q.; Ke, W.; Chang, T.; Hu, Z . A molecular ferroelectrics induced electroactive β -phase in solution processed PVDF films for flexible piezoelectric sensors . J. Mater. Chem. C , 2019 . 7 1532 - 1543 . DOI: 10.1039/C8TC05090B http://doi.org/10.1039/C8TC05090B .

Karan, S. K.; Maiti, S.; Agrawal, A. K.; Das, A. K.; Maitra, A.; Paria, S.; Bera, A.; Bera, R.; Halder, L.; Mishra, A. K.; Kim, J. K.; Khatua, B. B . Designing high energy conversion efficient bio-inspired vitamin assisted single-structured based self-powered piezoelectric/wind/acoustic multi-energy harvester with remarkable power density . Nano Energy , 2019 . 59 169 - 183 . DOI: 10.1016/j.nanoen.2019.02.031 http://doi.org/10.1016/j.nanoen.2019.02.031 .

Tadaki, D.; Ma, T.; Yamamiya, S.; Matsumoto, S.; Imai, Y.; Hirano-Iwata, A.; Niwano, M . Piezoelectric PVDF-based sensors with high pressure sensitivity induced by chemical modification of electrode surfaces . Sens. Actuator A Phys. , 2020 . 316 112424 DOI: 10.1016/j.sna.2020.112424 http://doi.org/10.1016/j.sna.2020.112424 .

Wu, Y.; Du, X.; Gao, R.; Li, J.; Li, W.; Yu, H.; Jiang, Z.; Wang, Z.; Tai, H . Self-polarization of PVDF Film triggered by hydrophilic treatment for pyroelectric sensor with ultra-low piezoelectric noise . Nanoscale Res. Lett. , 2019 . 14 72 DOI: 10.1186/s11671-019-2906-1 http://doi.org/10.1186/s11671-019-2906-1 .

Wang, T.; Li, H.; Yan, S . Effect of poly(butylene succinate) on the morphology evolution of poly(vinylidene fluoride) in their blends . Chinese J. Polym. Sci. , 2012 . 30 269 - 277 . DOI: 10.1007/s10118-012-1122-6 http://doi.org/10.1007/s10118-012-1122-6 .

Huang, Y.; Rui, G.; Li, Q.; Allahyarov, E.; Li, R.; Fukuto, M.; Zhong, G.; Xu, J.; Li, Z.; Taylor, P. L.; Zhu, L . Enhanced piezoelectricity from highly polarizable oriented amorphous fractions in biaxially oriented poly(vinylidene fluoride) with pure β crystals . Nat. Commun. , 2021 . 12 675 DOI: 10.1038/s41467-020-20662-7 http://doi.org/10.1038/s41467-020-20662-7 .

Liaw, C.; Chen, I . Poling of multiple PVDF films by moving corona discharge . Ferroelectrics , 1989 . 99 127 - 132 . DOI: 10.1080/00150198908221445 http://doi.org/10.1080/00150198908221445 .

Su, Y.; Li, Q.; Amagat, J.; Chen, M . 3D spring-based piezoelectric energy generator . Nano Energy , 2021 . 90 106578 DOI: 10.1016/j.nanoen.2021.106578 http://doi.org/10.1016/j.nanoen.2021.106578 .

Fu, Z.; Xia, W.; Chen, W.; Weng, J.; Zhang, J.; Zhang, J.; Jiang, Y.; Zhu, G . Improved thermal stability of ferroelectric phase in epitaxially grown P(VDF-TrFE) thin films . Macromolecules , 2016 . 49 3818 - 3825 . DOI: 10.1021/acs.macromol.6b00532 http://doi.org/10.1021/acs.macromol.6b00532 .

Eom, K.; Shin, Y. E.; Kim, J. K.; Joo, S. H.; Kim, K.; Kwak, S. K.; Ko, H.; Jin, J.; Kang, S. J . Tailored poly(vinylidene fluoride- co -trifluoroethylene) crystal orientation for a triboelectric nanogenerator through epitaxial growth on a chitin nanofiber film . Nano Lett. , 2020 . 20 6651 - 6659 . DOI: 10.1021/acs.nanolett.0c02488 http://doi.org/10.1021/acs.nanolett.0c02488 .

Zhao, C.; Hong, Y.; Chu, X.; Dong, Y.; Hu, Z.; Sun, X.; Yan, S . Enhanced ferroelectric properties of P(VDF-TrFE) thin film on single-layer graphene simply adjusted by crystallization condition . Mater. Today Energy , 2021 . 20 100678 DOI: 10.1016/j.mtener.2021.100678 http://doi.org/10.1016/j.mtener.2021.100678 .

Hu, Z.; Tian, M.; Nysten, B.; Jonas, A.M . Regular arrays of highly ordered ferroelectric polymer nanostructures for non-volatile low-voltage memories . Nat. Mater. , 2009 . 8 62 - 67 . DOI: 10.1038/nmat2339 http://doi.org/10.1038/nmat2339 .

Wang, J.; Li, H.; Liu, J.; Duan, Y.; Jiang, S.; Yan, S . On the α → β transition of carbon-coated highly oriented PVDF ultrathin film induced by melt recrystallization . J. Am. Chem. Soc. , 2003 . 125 1496 - 1497 . DOI: 10.1021/ja029352r http://doi.org/10.1021/ja029352r .

Yan, S . Origin of oriented recrystallization of carbon-coated preoriented ultrathin polymer films . Macromolecules , 2003 . 36 339 - 345 . DOI: 10.1021/ma021387o http://doi.org/10.1021/ma021387o .

Tashiro, K.; Takano, K.; Kobayashi, M.; Chatani, Y.; Tadokoro, H . Phase transition at a temperature immediately below the melting point of poly(vinylidene fluoride) form I: a proposition for the ferroelectric Curie point . Polymer , 1983 . 24 199 - 204 . DOI: 10.1016/0032-3861(83)90133-7 http://doi.org/10.1016/0032-3861(83)90133-7 .

Yagi, T.; Tatemoto, M.; Sako, J . Transition behavior and dielectric properties in trifluoroethylene and vinylidene fluoride copolymers . Polym. J. , 1980 . 12 209 - 223 . DOI: 10.1295/polymj.12.209 http://doi.org/10.1295/polymj.12.209 .

Kargarzadeh, H.; Mariano, M.; Gopakumar, D.; Ahmad, I.; Thomas, S.; Dufresne, A.; Huang, J.; Lin, N . Advances in cellulose nanomaterials . Cellulose , 2018 . 25 2151 - 2189 . DOI: 10.1007/s10570-018-1723-5 http://doi.org/10.1007/s10570-018-1723-5 .

Bakshi, P . S.; Selvakumar, D.; Kadirvelu, K.; Kumar, N.S. Chitosan as an environment friendly biomaterial−a review on recent modifications and applications . Int. J. Biol. Macromol. , 2020 . 150 1072 - 1083 . DOI: 10.1016/j.ijbiomac.2019.10.113 http://doi.org/10.1016/j.ijbiomac.2019.10.113 .

Singh, D.; Choudhary, A.; Garg, A . Flexible and robust piezoelectric polymer nanocomposites based energy harvesters . ACS Appl. Mater. Interfaces , 2018 . 10 2793 - 2800 . DOI: 10.1021/acsami.7b16973 http://doi.org/10.1021/acsami.7b16973 .

Lins, L. C.; Livi, S.; Maréchal, M.; Duchet-Rumeau, J.; Gérard, J. F . Structural dependence of cations and anions to building the polar phase of PVDF . Eur. Polym. J. , 2018 . 107 236 - 248 . DOI: 10.1016/j.eurpolymj.2018.08.022 http://doi.org/10.1016/j.eurpolymj.2018.08.022 .

Yang, S.; Wang, F.; Li, X.; Wu, Y.; Chang, T.; Hu, Z.; An, G . Immobilized ionic liquid induced electroactive β -phase in poly(vinylidene fluoride) thin films . Polymer , 2019 . 181 121784 DOI: 10.1016/j.polymer.2019.121784 http://doi.org/10.1016/j.polymer.2019.121784 .

Mandal, D.; Henkel, K.; Schmeißer, D . Improved performance of a polymer nanogenerator based on silver nanoparticles doped electrospun P(VDF-HFP) nanofibers . Phys. Chem. Chem. Phys. , 2014 . 16 10403 - 10407 . DOI: 10.1039/c3cp55238a http://doi.org/10.1039/c3cp55238a .

Bodkhe, S.; Rajesh, P. S . M.; Kamle, S.; Verma, V. Beta-phase enhancement in polyvinylidene fluoride through filler addition: comparing cellulose with carbon nanotubes and clay . J. Polym. Res. , 2014 . 21 434 DOI: 10.1007/s10965-014-0434-3 http://doi.org/10.1007/s10965-014-0434-3 .

Cai, X.; Lei, T.; Sun, D.; Lin, L . A critical analysis of the α, β and γ phases in poly(vinylidene fluoride) using FTIR . RSC Adv. , 2017 . 7 15382 - 15389 . DOI: 10.1039/C7RA01267E http://doi.org/10.1039/C7RA01267E .

Gregorio, Jr. R.; Cestari, M . Effect of crystallization temperature on the crystalline phase content and morphology of poly(vinylidene fluoride) . J. Polym. Sci., Part B: Polym. Phys. , 1994 . 32 859 - 870 . DOI: 10.1002/polb.1994.090320509 http://doi.org/10.1002/polb.1994.090320509 .

Gregorio, Jr. R. . Determination of the α, β , and γ crystalline phases of poly(vinylidene fluoride) films prepared at different conditions . J. Appl. Polym. Sci. , 2006 . 100 3272 - 3279 . DOI: 10.1002/app.23137 http://doi.org/10.1002/app.23137 .

Esterly, D. M.; Love, B. J . Phase transformation to β -poly(vinylidene fluoride) by milling . J. Polym. Sci., Part B: Polym. Phys. , 2004 . 42 91 - 97 . DOI: 10.1002/polb.10613 http://doi.org/10.1002/polb.10613 .

Li, X.; Wang, Y.; Lu, X.; Xiao, C . Morphology changes of polyvinylidene fluoride membrane under different phase separation mechanisms . J. Membr. Sci. , 2008 . 320 477 - 482 . DOI: 10.1016/j.memsci.2008.04.033 http://doi.org/10.1016/j.memsci.2008.04.033 .

Uchino, K . Piezoelectric energy harvesting systems—essentials to successful developments . Energy Technol. , 2018 . 6 829 - 848 . DOI: 10.1002/ente.201700785 http://doi.org/10.1002/ente.201700785 .

Shepelin, N. A.; Glushenkov, A. M.; Lussini, V. C.; Fox, P. J.; Dicinoski, G. W.; Shapter, J. G.; Ellis, A. V . New developments in composites, copolymer technologies and processing techniques for flexible fluoropolymer piezoelectric generators for efficient energy harvesting . Energy Environ. Sci. , 2019 . 12 1143 - 1176 . DOI: 10.1039/C8EE03006E http://doi.org/10.1039/C8EE03006E .

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