Hybrid Janus Nanotubes with Tunable Internal Pore Size Disassembled from Mesoporous Block Copolymer-based Hybrid Scaffolds

Chang-Xu Liu; Li-Jie Duan; Nan Yan; Wei Jiang

doi:10.1007/s10118-022-2704-6

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Hybrid Janus Nanotubes with Tunable Internal Pore Size Disassembled from Mesoporous Block Copolymer-based Hybrid Scaffolds

RESEARCH ARTICLE | Updated：2022-09-23

- Hybrid Janus Nanotubes with Tunable Internal Pore Size Disassembled from Mesoporous Block Copolymer-based Hybrid Scaffolds
- Hybrid Janus Nanotubes with Tunable Internal Pore Size Disassembled from Mesoporous Block Copolymer-based Hybrid Scaffolds
- Chinese Journal of Polymer Science 2022年40卷第10期页码：1165-1172
- Affiliations：
  
  a.State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
  b.School of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, China
- Author bio：
  
  duanlijie@ccut.edu.cn (L.J.D.)
  nyan@ciac.ac.cn (N.Y.)
  wjiang@ciac.ac.cn (W.J.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China for General Program (No. 22072143) and Major Program (No. 51433009).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-022-2704-6.
- DOI：10.1007/s10118-022-2704-6
  中图分类号：
- 收稿：2022-01-17，
  
  修回：2022-1-24，
  
  录用：2022-1-25，
  
  网络首发：2022-02-21，
  
  纸质出版：2022-10-01
- Accepted：
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Liu, C. X.; Duan, L. J.; Yan, N.; Jiang, W. Hybrid Janus nanotubes with tunable internal pore size disassembled from mesoporous block copolymer-based hybrid scaffolds. Chinese J. Polym. Sci. 2022, 40, 1165–1172

Chang-Xu Liu, Li-Jie Duan, Nan Yan, et al. Hybrid Janus Nanotubes with Tunable Internal Pore Size Disassembled from Mesoporous Block Copolymer-based Hybrid Scaffolds[J]. Chinese Journal of Polymer Science, 2022, 40(10): 1165-1172.
Liu, C. X.; Duan, L. J.; Yan, N.; Jiang, W. Hybrid Janus nanotubes with tunable internal pore size disassembled from mesoporous block copolymer-based hybrid scaffolds. Chinese J. Polym. Sci. 2022, 40, 1165–1172 DOI： 10.1007/s10118-022-2704-6.

Chang-Xu Liu, Li-Jie Duan, Nan Yan, et al. Hybrid Janus Nanotubes with Tunable Internal Pore Size Disassembled from Mesoporous Block Copolymer-based Hybrid Scaffolds[J]. Chinese Journal of Polymer Science, 2022, 40(10): 1165-1172. DOI： 10.1007/s10118-022-2704-6.

摘要

We have proposed a universal strategy to design the novel inorganic/organic hybrid Janus nanotubes with tunable inner pore size based on the hexagonally-packed mesoporous block copolymer template.

Abstract

The hybrid Janus nanomaterials have captured considerable attention since the asymmetric structure can combine the properties of each component and display synergistic applications. However

the precise design of the specific hybrid Janus nanostructures still remains a formidable challenge. Here

we for the first time report the fabrication of novel and highly uniform inorganic/organic hybrid Janus nanotubes

via

disassembling the mesoporous inorganic nanoparticles (NPs)/polystyrene-block-poly(4-vinylpyridine) (PS-

-P4VP) hybrid sheets

which are generated through the

in situ

reduction of functional metal precursors on the prepared PS-

-P4VP mesoporous scaffolds. More importantly

the internal pore size of the hybrid Janus nanotubes can be precisely tuned by readily controlling the swelling time of the PS-

-P4VP sheet-like assemblies in a selective solvent for P4VP domains

thus generating the particular inorganic/organic hybrid Janus nanotubes with adjustable inner diameter size. We believe that our finding will provide an efficient and universal route to fabricate the particular inorganic/organic hybrid nanotubes for hierarchical functional devices and nanomaterials.

关键词

Keywords

references

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