Effect of Solvent Viscosity on the Driven Translocation of Charged Polymers through Nanopores

Han-Xian Hu; Fan Wu; Xiao Yang; Chao Wang; Meng-Bo Luo

doi:10.1007/s10118-022-2696-2

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Effect of Solvent Viscosity on the Driven Translocation of Charged Polymers through Nanopores

RESEARCH ARTICLE | Updated：2022-04-26

- Effect of Solvent Viscosity on the Driven Translocation of Charged Polymers through Nanopores
- Effect of Solvent Viscosity on the Driven Translocation of Charged Polymers through Nanopores
- Chinese Journal of Polymer Science 2022年40卷第5期页码：532-540
- Affiliations：
  
  a.Department of Physics, Zhejiang University, Hangzhou 310027, China
  b.Department of Physics, Taizhou University, Taizhou 318000, China
- Author bio：
  
  luomengbo@zju.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 11974305).
- DOI：10.1007/s10118-022-2696-2
  中图分类号：
- 收稿：2021-12-06，
  
  修回：2022-1-6，
  
  录用：2022-1-14，
  
  网络首发：2022-03-17，
  
  纸质出版：2022-05-01
- Accepted：
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Hu, H. X.; Wu, F.; Yang, X.; Wang, C.; Luo, M. B. Effect of solvent viscosity on the driven translocation of charged polymers through nanopores. Chinese J. Polym. Sci. 2022, 40, 532–540

Han-Xian Hu, Fan Wu, Xiao Yang, et al. Effect of Solvent Viscosity on the Driven Translocation of Charged Polymers through Nanopores[J]. Chinese Journal of Polymer Science, 2022, 40(5): 532-540.
Hu, H. X.; Wu, F.; Yang, X.; Wang, C.; Luo, M. B. Effect of solvent viscosity on the driven translocation of charged polymers through nanopores. Chinese J. Polym. Sci. 2022, 40, 532–540 DOI： 10.1007/s10118-022-2696-2.

Han-Xian Hu, Fan Wu, Xiao Yang, et al. Effect of Solvent Viscosity on the Driven Translocation of Charged Polymers through Nanopores[J]. Chinese Journal of Polymer Science, 2022, 40(5): 532-540. DOI： 10.1007/s10118-022-2696-2.

摘要

Abstract

The effect of viscosity of non-translocated (

cis

) side

cis

on the driven translocation of charged polymers through nanopores is investigated using Langevin dynamics simulation. Results show that the translocation of polymer chains can be regulated by changing

cis

. As

cis

decreases

the translocation time

decreases

and the exponent

in the scaling relation with driving force

−

increases whereas

in the scaling relation with chain length

decreases. Simultaneously

the conformation of the polymer chain at the

cis

side gravitates towards an equilibrium state. The results imply a relationship between the translocation and the conformation of polymer chains. To verify this hypothesis

we change the conformation of polymer by artificially relaxing the translocating polymer

via

adding an additional relaxation time in the simulation. A sufficient large additional relaxation time for the translocating polymer chain at the

cis

side only or at both

cis

and

trans

sides results in exponents

and

both close to 1

in contrast to

=1.36 and

=0.8 for the translocation without the additional relaxation. The additional relaxation for the polymer chain at the

cis

side accelerates the translocation and plays a more important role than that for polymer chain at the

trans

side.

关键词

Keywords

references

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